Synthesis, crystal structure and nonlinear optical properties of an oxomolybdate-copper cluster [Cu4(PPh3)6] [Mo8O2O26]

Ying Gui Zhu; Xue Hai Ju; Ying Lin Song; Ke Xuan Huang; Yi Zhi Li; He Gen Zheng

Synthesis, crystal structure and nonlinear optical properties of an oxomolybdate-copper cluster [Cu₄(PPh₃)₆] [Mo₈O₂O₂₆]

Ying Gui Zhu^*
, Xue Hai Ju
, Ying Lin Song
, Ke Xuan Huang
, Yi Zhi Li
, He Gen Zheng

^*Corresponding author for this work

Anhui Normal University
Nanjing University of Science and Technology
Soochow University
Nanjing University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

In this article, an oxomolybdate-copper cluster, [Cu₄(PPh ₃)₆][Mo₈O₂₆] (1), has been synthesized and characterized by single-crystal X-ray diffraction structure analysis, IR spectrum and XRD analysis. The crystal structure shows that the centrosymmetric [Mo₈O₂₆]^4- anion is built with eight MoO₆ edge-shared octahedra, which belongs to the typical β-octamolybdate arrangement. The title cluster exhibits nonlinear optical properties (NLO) with effective third-order NLO absorptive index α₂ and refractive index n₂ value 12.9×10 ^-11 MKS and 3.13×10^-11 esu, respectively. CCDC: 632477.

Original language	English
Pages (from-to)	2029-2034
Number of pages	6
Journal	Chinese Journal of Inorganic Chemistry
Volume	24
Issue number	12
State	Published - Dec 2008
Externally published	Yes

Keywords

Cluster
Crystal structure
Nonlinear optics
Oxomolybdate-copper

Cite this

@article{4d0bdc4f82fe438394a8097bcb806d63,

title = "Synthesis, crystal structure and nonlinear optical properties of an oxomolybdate-copper cluster [Cu4(PPh3)6] [Mo8O2O26]",

abstract = "In this article, an oxomolybdate-copper cluster, [Cu4(PPh 3)6][Mo8O26] (1), has been synthesized and characterized by single-crystal X-ray diffraction structure analysis, IR spectrum and XRD analysis. The crystal structure shows that the centrosymmetric [Mo8O26]4- anion is built with eight MoO6 edge-shared octahedra, which belongs to the typical β-octamolybdate arrangement. The title cluster exhibits nonlinear optical properties (NLO) with effective third-order NLO absorptive index α2 and refractive index n2 value 12.9×10 -11 MKS and 3.13×10-11 esu, respectively. CCDC: 632477.",

keywords = "Cluster, Crystal structure, Nonlinear optics, Oxomolybdate-copper",

author = "Zhu, \{Ying Gui\} and Ju, \{Xue Hai\} and Song, \{Ying Lin\} and Huang, \{Ke Xuan\} and Li, \{Yi Zhi\} and Zheng, \{He Gen\}",

year = "2008",

month = dec,

language = "英语",

volume = "24",

pages = "2029--2034",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "12",

}

TY - JOUR

T1 - Synthesis, crystal structure and nonlinear optical properties of an oxomolybdate-copper cluster [Cu4(PPh3)6] [Mo8O2O26]

AU - Zhu, Ying Gui

AU - Ju, Xue Hai

AU - Song, Ying Lin

AU - Huang, Ke Xuan

AU - Li, Yi Zhi

AU - Zheng, He Gen

PY - 2008/12

Y1 - 2008/12

N2 - In this article, an oxomolybdate-copper cluster, [Cu4(PPh 3)6][Mo8O26] (1), has been synthesized and characterized by single-crystal X-ray diffraction structure analysis, IR spectrum and XRD analysis. The crystal structure shows that the centrosymmetric [Mo8O26]4- anion is built with eight MoO6 edge-shared octahedra, which belongs to the typical β-octamolybdate arrangement. The title cluster exhibits nonlinear optical properties (NLO) with effective third-order NLO absorptive index α2 and refractive index n2 value 12.9×10 -11 MKS and 3.13×10-11 esu, respectively. CCDC: 632477.

AB - In this article, an oxomolybdate-copper cluster, [Cu4(PPh 3)6][Mo8O26] (1), has been synthesized and characterized by single-crystal X-ray diffraction structure analysis, IR spectrum and XRD analysis. The crystal structure shows that the centrosymmetric [Mo8O26]4- anion is built with eight MoO6 edge-shared octahedra, which belongs to the typical β-octamolybdate arrangement. The title cluster exhibits nonlinear optical properties (NLO) with effective third-order NLO absorptive index α2 and refractive index n2 value 12.9×10 -11 MKS and 3.13×10-11 esu, respectively. CCDC: 632477.

KW - Cluster

KW - Crystal structure

KW - Nonlinear optics

KW - Oxomolybdate-copper

UR - https://www.scopus.com/pages/publications/58149171922

M3 - 文章

AN - SCOPUS:58149171922

SN - 1001-4861

VL - 24

SP - 2029

EP - 2034

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 12

ER -

Synthesis, crystal structure and nonlinear optical properties of an oxomolybdate-copper cluster [Cu₄(PPh₃)₆] [Mo₈O₂O₂₆]

Abstract

Keywords

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