Synthesis, crystal structure and non-linear optical properties of a new cyanide-containing compound

Hai Ying Bie; Jing Lu; Jie Hui Yu; Ying Hua Sun; Xiao Zhang; Ji Qing Xu; Ling Yun Pan; Qing Xin Yang

doi:10.1080/00958970412331310536

Synthesis, crystal structure and non-linear optical properties of a new cyanide-containing compound

Hai Ying Bie
, Jing Lu
, Jie Hui Yu
, Ying Hua Sun
, Xiao Zhang
, Ji Qing Xu^*
, Ling Yun Pan
, Qing Xin Yang

^*Corresponding author for this work

College of Chemistry
College of Physics

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Reaction of K₃[Fe(CN)₆], NiCl₂ and diethylenetriamine (dien) resulted in the formation of a cyanide-containing heterometallic compound [Ni(dien)₂]₂[Fe(CN) ₆]·4H₂O 1. The structure consists of two octahedral [Ni(dien)₂]²⁺ cations, one octahedral [Fe(CN) ₆]^4- anion and four crystallization water molecules, which are held together by hydrogen-bonding interactions. Its TG curve exhibits two stages of mass loss. Compound 1 in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with an absorption coefficient and refractive index α₂ = 1.10 × 10^-11 m w^-1, n₂ = -3.05 × 10^-19 m² w^-1, respectively, and third-order NLO susceptibility χ⁽³⁾ 4.34 × 10^-13 esu.

Original language	English
Pages (from-to)	1603-1609
Number of pages	7
Journal	Journal of Coordination Chemistry
Volume	57
Issue number	17-18
DOIs	https://doi.org/10.1080/00958970412331310536
State	Published - 15 Dec 2004
Externally published	Yes

Keywords

Crystal structure
Cyanide complexes
Third-order NLO properties

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@article{f50b14d99f6e48f097df23fc5cd7ffde,

title = "Synthesis, crystal structure and non-linear optical properties of a new cyanide-containing compound",

abstract = "Reaction of K3[Fe(CN)6], NiCl2 and diethylenetriamine (dien) resulted in the formation of a cyanide-containing heterometallic compound [Ni(dien)2]2[Fe(CN) 6]·4H2O 1. The structure consists of two octahedral [Ni(dien)2]2+ cations, one octahedral [Fe(CN) 6]4- anion and four crystallization water molecules, which are held together by hydrogen-bonding interactions. Its TG curve exhibits two stages of mass loss. Compound 1 in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with an absorption coefficient and refractive index α2 = 1.10 × 10-11 m w-1, n2 = -3.05 × 10-19 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 4.34 × 10-13 esu.",

keywords = "Crystal structure, Cyanide complexes, Third-order NLO properties",

author = "Bie, \{Hai Ying\} and Jing Lu and Yu, \{Jie Hui\} and Sun, \{Ying Hua\} and Xiao Zhang and Xu, \{Ji Qing\} and Pan, \{Ling Yun\} and Yang, \{Qing Xin\}",

year = "2004",

month = dec,

day = "15",

doi = "10.1080/00958970412331310536",

language = "英语",

volume = "57",

pages = "1603--1609",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "17-18",

}

TY - JOUR

T1 - Synthesis, crystal structure and non-linear optical properties of a new cyanide-containing compound

AU - Bie, Hai Ying

AU - Lu, Jing

AU - Yu, Jie Hui

AU - Sun, Ying Hua

AU - Zhang, Xiao

AU - Xu, Ji Qing

AU - Pan, Ling Yun

AU - Yang, Qing Xin

PY - 2004/12/15

Y1 - 2004/12/15

N2 - Reaction of K3[Fe(CN)6], NiCl2 and diethylenetriamine (dien) resulted in the formation of a cyanide-containing heterometallic compound [Ni(dien)2]2[Fe(CN) 6]·4H2O 1. The structure consists of two octahedral [Ni(dien)2]2+ cations, one octahedral [Fe(CN) 6]4- anion and four crystallization water molecules, which are held together by hydrogen-bonding interactions. Its TG curve exhibits two stages of mass loss. Compound 1 in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with an absorption coefficient and refractive index α2 = 1.10 × 10-11 m w-1, n2 = -3.05 × 10-19 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 4.34 × 10-13 esu.

AB - Reaction of K3[Fe(CN)6], NiCl2 and diethylenetriamine (dien) resulted in the formation of a cyanide-containing heterometallic compound [Ni(dien)2]2[Fe(CN) 6]·4H2O 1. The structure consists of two octahedral [Ni(dien)2]2+ cations, one octahedral [Fe(CN) 6]4- anion and four crystallization water molecules, which are held together by hydrogen-bonding interactions. Its TG curve exhibits two stages of mass loss. Compound 1 in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with an absorption coefficient and refractive index α2 = 1.10 × 10-11 m w-1, n2 = -3.05 × 10-19 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 4.34 × 10-13 esu.

KW - Crystal structure

KW - Cyanide complexes

KW - Third-order NLO properties

UR - https://www.scopus.com/pages/publications/11444251176

U2 - 10.1080/00958970412331310536

DO - 10.1080/00958970412331310536

M3 - 文章

AN - SCOPUS:11444251176

SN - 0095-8972

VL - 57

SP - 1603

EP - 1609

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 17-18

ER -

Synthesis, crystal structure and non-linear optical properties of a new cyanide-containing compound

Abstract

Keywords

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