Synthesis, Crystal Structure, and Catalytic Performance of 2,6-Bis [ 1-(2,4,6-trimethylphenylirnino)ethyl] pyridine Nickel(I1) Complex

Rui Qing Fan; Yu Lin Yang; Zhi Wei Lü

doi:10.1016/S1005-9040(08)60002-1

Synthesis, Crystal Structure, and Catalytic Performance of 2,6-Bis [ 1-(2,4,6-trimethylphenylirnino)ethyl] pyridine Nickel(I1) Complex

Rui Qing Fan^*
, Yu Lin Yang
, Zhi Wei Lü

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Institute of Opto-Electronics
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A novel nickel(II) complex Ni[L]Cl₂ CH3CN(1) containing the tridentate ligand 2,6-bis[1-(2,4,6-trimethylphenylimino)ethyl]pyridine(L) has been synthesized. The crystal structure of complex 1 was determined by single crystal X-ray diffraction analysis. The catalytic activity of complex 1 for the polymerization of ethylene was studied under activation with methylaluminoxane(MA0).

Original language	English
Pages (from-to)	4-7
Number of pages	4
Journal	Chemical Research in Chinese Universities
Volume	24
Issue number	1
DOIs	https://doi.org/10.1016/S1005-9040(08)60002-1
State	Published - Jan 2008

Keywords

Bis(imino)pyridyl nickel complex
Crystal structure
Ethylene polymerization

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10.1016/S1005-9040(08)60002-1

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title = "Synthesis, Crystal Structure, and Catalytic Performance of 2,6-Bis [ 1-(2,4,6-trimethylphenylirnino)ethyl] pyridine Nickel(I1) Complex",

abstract = "A novel nickel(II) complex Ni[L]Cl2 CH3CN(1) containing the tridentate ligand 2,6-bis[1-(2,4,6-trimethylphenylimino)ethyl]pyridine(L) has been synthesized. The crystal structure of complex 1 was determined by single crystal X-ray diffraction analysis. The catalytic activity of complex 1 for the polymerization of ethylene was studied under activation with methylaluminoxane(MA0).",

keywords = "Bis(imino)pyridyl nickel complex, Crystal structure, Ethylene polymerization",

author = "Fan, \{Rui Qing\} and Yang, \{Yu Lin\} and L{\"u}, \{Zhi Wei\}",

year = "2008",

month = jan,

doi = "10.1016/S1005-9040(08)60002-1",

language = "英语",

volume = "24",

pages = "4--7",

journal = "Chemical Research in Chinese Universities",

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TY - JOUR

T1 - Synthesis, Crystal Structure, and Catalytic Performance of 2,6-Bis [ 1-(2,4,6-trimethylphenylirnino)ethyl] pyridine Nickel(I1) Complex

AU - Fan, Rui Qing

AU - Yang, Yu Lin

AU - Lü, Zhi Wei

PY - 2008/1

Y1 - 2008/1

N2 - A novel nickel(II) complex Ni[L]Cl2 CH3CN(1) containing the tridentate ligand 2,6-bis[1-(2,4,6-trimethylphenylimino)ethyl]pyridine(L) has been synthesized. The crystal structure of complex 1 was determined by single crystal X-ray diffraction analysis. The catalytic activity of complex 1 for the polymerization of ethylene was studied under activation with methylaluminoxane(MA0).

AB - A novel nickel(II) complex Ni[L]Cl2 CH3CN(1) containing the tridentate ligand 2,6-bis[1-(2,4,6-trimethylphenylimino)ethyl]pyridine(L) has been synthesized. The crystal structure of complex 1 was determined by single crystal X-ray diffraction analysis. The catalytic activity of complex 1 for the polymerization of ethylene was studied under activation with methylaluminoxane(MA0).

KW - Bis(imino)pyridyl nickel complex

KW - Crystal structure

KW - Ethylene polymerization

UR - https://www.scopus.com/pages/publications/56449128690

U2 - 10.1016/S1005-9040(08)60002-1

DO - 10.1016/S1005-9040(08)60002-1

M3 - 文章

AN - SCOPUS:56449128690

SN - 1005-9040

VL - 24

SP - 4

EP - 7

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 1

ER -

Synthesis, Crystal Structure, and Catalytic Performance of 2,6-Bis [ 1-(2,4,6-trimethylphenylirnino)ethyl] pyridine Nickel(I1) Complex

Abstract

Keywords

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