Synthesis, characterization and optical property of a new two-dimensional (2-D) copper halide coordination polymer [Cu 4 II(OH) 4(1,10-phen) 4][Cu 8 IBr 12] (phen = phenanthroline)

Jie Hui Yu; Hai Ying Bie; Ji Qing Xu; Jing Lu; Xiao Zhang

doi:10.1016/j.inoche.2004.09.013

Synthesis, characterization and optical property of a new two-dimensional (2-D) copper halide coordination polymer [Cu ₄ ^II(OH) ₄(1,10-phen) ₄][Cu ₈ ^IBr ₁₂] (phen = phenanthroline)

Jie Hui Yu
, Hai Ying Bie
, Ji Qing Xu
, Jing Lu
, Xiao Zhang

College of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A horse-like picture drawn by hydrothermal reactions, and formed through the linkage of [Cu8IBr12]4- chains by the tetranuclear copper-hydroxo clusters [Cu ₄(OH) ₄(phen) ₄] ⁴⁺ as the bridges. The hydrothermal reaction of CuBr ₂, CuBr and 1,10-phen gives birth to a 2-D coordination polymer [Cu ₄ ^II(OH) ₄(1,10- phen) ₄][Cu ₈ ^IBr ₁₂] (1), consisting of the unique [Cu8IBr12]4- chains linked by the stepped-cubane copper(II)-hydroxo clusters [Cu ₄ ^II(OH) ₄(phen) ₄] ⁴⁺ as the bridges. Compound 1 possesses high thermal stable. The non-linear optical property of 1 was studied, and the compound exhibits the reverse saturable absorption (α ₂ = 0.80 × 10 ^-11 m W ^-1) and self-defocusing performance (n ₂ = -1.55 × 10 ^-18 m ² W ^-1).

Original language	English
Pages (from-to)	1205-1208
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	11
DOIs	https://doi.org/10.1016/j.inoche.2004.09.013
State	Published - Nov 2004
Externally published	Yes

Keywords

Copper halide
Hydrothermal synthesis
Non-linear optics
Stepped cubane

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10.1016/j.inoche.2004.09.013

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@article{c4d6e4c793414078ad4714df189dbeda,

title = "Synthesis, characterization and optical property of a new two-dimensional (2-D) copper halide coordination polymer [Cu 4 II(OH) 4(1,10-phen) 4][Cu 8 IBr 12] (phen = phenanthroline)",

abstract = "A horse-like picture drawn by hydrothermal reactions, and formed through the linkage of [Cu8IBr12]4- chains by the tetranuclear copper-hydroxo clusters [Cu 4(OH) 4(phen) 4] 4+ as the bridges. The hydrothermal reaction of CuBr 2, CuBr and 1,10-phen gives birth to a 2-D coordination polymer [Cu 4 II(OH) 4(1,10- phen) 4][Cu 8 IBr 12] (1), consisting of the unique [Cu8IBr12]4- chains linked by the stepped-cubane copper(II)-hydroxo clusters [Cu 4 II(OH) 4(phen) 4] 4+ as the bridges. Compound 1 possesses high thermal stable. The non-linear optical property of 1 was studied, and the compound exhibits the reverse saturable absorption (α 2 = 0.80 × 10 -11 m W -1) and self-defocusing performance (n 2 = -1.55 × 10 -18 m 2 W -1).",

keywords = "Copper halide, Hydrothermal synthesis, Non-linear optics, Stepped cubane",

author = "Yu, \{Jie Hui\} and Bie, \{Hai Ying\} and Xu, \{Ji Qing\} and Jing Lu and Xiao Zhang",

year = "2004",

month = nov,

doi = "10.1016/j.inoche.2004.09.013",

language = "英语",

volume = "7",

pages = "1205--1208",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "11",

}

Synthesis, characterization and optical property of a new two-dimensional (2-D) copper halide coordination polymer [Cu ₄ ^II(OH) ₄(1,10-phen) ₄][Cu ₈ ^IBr ₁₂] (phen = phenanthroline). / Yu, Jie Hui; Bie, Hai Ying; Xu, Ji Qing et al.
In: Inorganic Chemistry Communications, Vol. 7, No. 11, 11.2004, p. 1205-1208.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, characterization and optical property of a new two-dimensional (2-D) copper halide coordination polymer [Cu 4 II(OH) 4(1,10-phen) 4][Cu 8 IBr 12] (phen = phenanthroline)

AU - Yu, Jie Hui

AU - Bie, Hai Ying

AU - Xu, Ji Qing

AU - Lu, Jing

AU - Zhang, Xiao

PY - 2004/11

Y1 - 2004/11

N2 - A horse-like picture drawn by hydrothermal reactions, and formed through the linkage of [Cu8IBr12]4- chains by the tetranuclear copper-hydroxo clusters [Cu 4(OH) 4(phen) 4] 4+ as the bridges. The hydrothermal reaction of CuBr 2, CuBr and 1,10-phen gives birth to a 2-D coordination polymer [Cu 4 II(OH) 4(1,10- phen) 4][Cu 8 IBr 12] (1), consisting of the unique [Cu8IBr12]4- chains linked by the stepped-cubane copper(II)-hydroxo clusters [Cu 4 II(OH) 4(phen) 4] 4+ as the bridges. Compound 1 possesses high thermal stable. The non-linear optical property of 1 was studied, and the compound exhibits the reverse saturable absorption (α 2 = 0.80 × 10 -11 m W -1) and self-defocusing performance (n 2 = -1.55 × 10 -18 m 2 W -1).

AB - A horse-like picture drawn by hydrothermal reactions, and formed through the linkage of [Cu8IBr12]4- chains by the tetranuclear copper-hydroxo clusters [Cu 4(OH) 4(phen) 4] 4+ as the bridges. The hydrothermal reaction of CuBr 2, CuBr and 1,10-phen gives birth to a 2-D coordination polymer [Cu 4 II(OH) 4(1,10- phen) 4][Cu 8 IBr 12] (1), consisting of the unique [Cu8IBr12]4- chains linked by the stepped-cubane copper(II)-hydroxo clusters [Cu 4 II(OH) 4(phen) 4] 4+ as the bridges. Compound 1 possesses high thermal stable. The non-linear optical property of 1 was studied, and the compound exhibits the reverse saturable absorption (α 2 = 0.80 × 10 -11 m W -1) and self-defocusing performance (n 2 = -1.55 × 10 -18 m 2 W -1).

KW - Copper halide

KW - Hydrothermal synthesis

KW - Non-linear optics

KW - Stepped cubane

UR - https://www.scopus.com/pages/publications/7044270698

U2 - 10.1016/j.inoche.2004.09.013

DO - 10.1016/j.inoche.2004.09.013

M3 - 文章

AN - SCOPUS:7044270698

SN - 1387-7003

VL - 7

SP - 1205

EP - 1208

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

ER -

Synthesis, characterization and optical property of a new two-dimensional (2-D) copper halide coordination polymer [Cu ₄ ^II(OH) ₄(1,10-phen) ₄][Cu ₈ ^IBr ₁₂] (phen = phenanthroline)

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