Synthesis and structure of a new layered zinc phosphate [C 6N2H16]3.5[Zn14(PO 4)7(HPO4)7] in the presence of trans-1,4-diaminocyclohexane

Yan Xing; Guanghua Li; He Meng; Zhan Shi; Yunling Liu; Xinghui Wei; Yulin Yang; Wenqin Pang

doi:10.1016/j.inoche.2003.12.036

Synthesis and structure of a new layered zinc phosphate [C ₆N₂H₁₆]_3.5[Zn₁₄(PO ₄)₇(HPO₄)₇] in the presence of trans-1,4-diaminocyclohexane

Yan Xing
, Guanghua Li
, He Meng
, Zhan Shi
, Yunling Liu
, Xinghui Wei
, Yulin Yang
, Wenqin Pang^*

^*Corresponding author for this work

College of Chemistry
Northeast Normal University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A novel two-dimensional layered zinc phosphate [C₆N ₂H₁₆]_3.5[Zn₁₄(PO₄) ₇(HPO₄)₇], I, has been synthesized hydrothermally using trans-1,4-diaminocyclohexane(trans -1,4-DACH) as the structure-directing agent. The structure of I comprises a network of ZnO ₄, PO₄, and PO₃(OH) tetrahedral forming one-dimensional tubes. The tubes, in turn, are linked via oxygen atoms forming macroanionic inorganic layers.

Original language	English
Pages (from-to)	475-477
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2003.12.036
State	Published - Apr 2004
Externally published	Yes

Keywords

Hydrothermal synthesis
Layer structure
Trans-1,4- diaminocyclohexane
Zinc phosphate

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10.1016/j.inoche.2003.12.036

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title = "Synthesis and structure of a new layered zinc phosphate [C 6N2H16]3.5[Zn14(PO 4)7(HPO4)7] in the presence of trans-1,4-diaminocyclohexane",

abstract = "A novel two-dimensional layered zinc phosphate [C6N 2H16]3.5[Zn14(PO4) 7(HPO4)7], I, has been synthesized hydrothermally using trans-1,4-diaminocyclohexane(trans -1,4-DACH) as the structure-directing agent. The structure of I comprises a network of ZnO 4, PO4, and PO3(OH) tetrahedral forming one-dimensional tubes. The tubes, in turn, are linked via oxygen atoms forming macroanionic inorganic layers.",

keywords = "Hydrothermal synthesis, Layer structure, Trans-1,4- diaminocyclohexane, Zinc phosphate",

author = "Yan Xing and Guanghua Li and He Meng and Zhan Shi and Yunling Liu and Xinghui Wei and Yulin Yang and Wenqin Pang",

year = "2004",

month = apr,

doi = "10.1016/j.inoche.2003.12.036",

language = "英语",

volume = "7",

pages = "475--477",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "4",

}

TY - JOUR

T1 - Synthesis and structure of a new layered zinc phosphate [C 6N2H16]3.5[Zn14(PO 4)7(HPO4)7] in the presence of trans-1,4-diaminocyclohexane

AU - Xing, Yan

AU - Li, Guanghua

AU - Meng, He

AU - Shi, Zhan

AU - Liu, Yunling

AU - Wei, Xinghui

AU - Yang, Yulin

AU - Pang, Wenqin

PY - 2004/4

Y1 - 2004/4

N2 - A novel two-dimensional layered zinc phosphate [C6N 2H16]3.5[Zn14(PO4) 7(HPO4)7], I, has been synthesized hydrothermally using trans-1,4-diaminocyclohexane(trans -1,4-DACH) as the structure-directing agent. The structure of I comprises a network of ZnO 4, PO4, and PO3(OH) tetrahedral forming one-dimensional tubes. The tubes, in turn, are linked via oxygen atoms forming macroanionic inorganic layers.

AB - A novel two-dimensional layered zinc phosphate [C6N 2H16]3.5[Zn14(PO4) 7(HPO4)7], I, has been synthesized hydrothermally using trans-1,4-diaminocyclohexane(trans -1,4-DACH) as the structure-directing agent. The structure of I comprises a network of ZnO 4, PO4, and PO3(OH) tetrahedral forming one-dimensional tubes. The tubes, in turn, are linked via oxygen atoms forming macroanionic inorganic layers.

KW - Hydrothermal synthesis

KW - Layer structure

KW - Trans-1,4- diaminocyclohexane

KW - Zinc phosphate

UR - https://www.scopus.com/pages/publications/1642281017

U2 - 10.1016/j.inoche.2003.12.036

DO - 10.1016/j.inoche.2003.12.036

M3 - 文章

AN - SCOPUS:1642281017

SN - 1387-7003

VL - 7

SP - 475

EP - 477

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 4

ER -

Synthesis and structure of a new layered zinc phosphate [C ₆N₂H₁₆]_3.5[Zn₁₄(PO ₄)₇(HPO₄)₇] in the presence of trans-1,4-diaminocyclohexane

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