Synthesis and structural characterization of amorphous nano-sized SiBONC ceramic powders via polymer pyrolysis

F. Li; G. Wen; H. W. Bai; L. Song

doi:10.1016/j.jnoncrysol.2006.12.018

Synthesis and structural characterization of amorphous nano-sized SiBONC ceramic powders via polymer pyrolysis

F. Li
, G. Wen^*
, H. W. Bai
, L. Song

^*Corresponding author for this work

Faculty of Computing

Harbin Institute of Technology
Harbin Institute of Technology Weihai

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

SiBONC ceramic powders have been prepared via a polymer pyrolysis route using silicon tetrachloride (SiCl₄), benzaldehyde (PhCHO), boron trichloride (BCl₃) and aniline (PhNH₂) as starting materials. Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and transmission electron microscopy (TEM) were performed to investigate the structural characteristics of the polymer precursor and the ceramic powders. The SiBONC ceramic powders in spherical shape with a mean diameter of 50 nm are amorphous and composed of B-N, Si-O, Si-C, and SiON_x groups. The SiBONC ceramic powders were sintered at 1700 °C to a dense material which still remained amorphous.

Original language	English
Pages (from-to)	379-383
Number of pages	5
Journal	Journal of Non-Crystalline Solids
Volume	353
Issue number	4
DOIs	https://doi.org/10.1016/j.jnoncrysol.2006.12.018
State	Published - 15 Mar 2007

Keywords

Composition
FT-IR measurements
Nanoparticles
Powders
STEM/TEM
TEM/STEM
UPS/XPS
X-ray diffraction
XPS

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10.1016/j.jnoncrysol.2006.12.018

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title = "Synthesis and structural characterization of amorphous nano-sized SiBONC ceramic powders via polymer pyrolysis",

abstract = "SiBONC ceramic powders have been prepared via a polymer pyrolysis route using silicon tetrachloride (SiCl4), benzaldehyde (PhCHO), boron trichloride (BCl3) and aniline (PhNH2) as starting materials. Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and transmission electron microscopy (TEM) were performed to investigate the structural characteristics of the polymer precursor and the ceramic powders. The SiBONC ceramic powders in spherical shape with a mean diameter of 50 nm are amorphous and composed of B-N, Si-O, Si-C, and SiONx groups. The SiBONC ceramic powders were sintered at 1700 °C to a dense material which still remained amorphous.",

keywords = "Composition, FT-IR measurements, Nanoparticles, Powders, STEM/TEM, TEM/STEM, UPS/XPS, X-ray diffraction, XPS",

author = "F. Li and G. Wen and Bai, \{H. W.\} and L. Song",

year = "2007",

month = mar,

day = "15",

doi = "10.1016/j.jnoncrysol.2006.12.018",

language = "英语",

volume = "353",

pages = "379--383",

journal = "Journal of Non-Crystalline Solids",

issn = "0022-3093",

publisher = "Elsevier B.V.",

number = "4",

}

TY - JOUR

T1 - Synthesis and structural characterization of amorphous nano-sized SiBONC ceramic powders via polymer pyrolysis

AU - Li, F.

AU - Wen, G.

AU - Bai, H. W.

AU - Song, L.

PY - 2007/3/15

Y1 - 2007/3/15

N2 - SiBONC ceramic powders have been prepared via a polymer pyrolysis route using silicon tetrachloride (SiCl4), benzaldehyde (PhCHO), boron trichloride (BCl3) and aniline (PhNH2) as starting materials. Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and transmission electron microscopy (TEM) were performed to investigate the structural characteristics of the polymer precursor and the ceramic powders. The SiBONC ceramic powders in spherical shape with a mean diameter of 50 nm are amorphous and composed of B-N, Si-O, Si-C, and SiONx groups. The SiBONC ceramic powders were sintered at 1700 °C to a dense material which still remained amorphous.

AB - SiBONC ceramic powders have been prepared via a polymer pyrolysis route using silicon tetrachloride (SiCl4), benzaldehyde (PhCHO), boron trichloride (BCl3) and aniline (PhNH2) as starting materials. Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and transmission electron microscopy (TEM) were performed to investigate the structural characteristics of the polymer precursor and the ceramic powders. The SiBONC ceramic powders in spherical shape with a mean diameter of 50 nm are amorphous and composed of B-N, Si-O, Si-C, and SiONx groups. The SiBONC ceramic powders were sintered at 1700 °C to a dense material which still remained amorphous.

KW - Composition

KW - FT-IR measurements

KW - Nanoparticles

KW - Powders

KW - STEM/TEM

KW - TEM/STEM

KW - UPS/XPS

KW - X-ray diffraction

KW - XPS

UR - https://www.scopus.com/pages/publications/33846909481

U2 - 10.1016/j.jnoncrysol.2006.12.018

DO - 10.1016/j.jnoncrysol.2006.12.018

M3 - 文章

AN - SCOPUS:33846909481

SN - 0022-3093

VL - 353

SP - 379

EP - 383

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 4

ER -

Synthesis and structural characterization of amorphous nano-sized SiBONC ceramic powders via polymer pyrolysis

Abstract

Keywords

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