Synthesis and structural characterization of a novel copper(II)/lead(II) heterometallic organic-inorganic hybrid

Gao Feng Wang; Xiao Zhang; Shu Wen Sun; Chen Zhong Yao; Zhao Rong Liu; Yu Chun Wang; Yuan Zhong Liu

doi:10.1515/znb-2015-0041

Synthesis and structural characterization of a novel copper(II)/lead(II) heterometallic organic-inorganic hybrid

Gao Feng Wang^*
, Xiao Zhang
, Shu Wen Sun
, Chen Zhong Yao
, Zhao Rong Liu
, Yu Chun Wang
, Yuan Zhong Liu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Yuncheng University
CAS - Suzhou Institute of Biomedical Engineering and Technology

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A new copper(II)/lead(II) complex [(terpy)₃CuPb₅Br₁₂] (1) (terpy = 2,2':6',2"-terpyridine) has been synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. The copper(II) and lead(II) ions in the title complex are in distorted six-(Cu(II), Pb(II)) and eight-fold (Pb(II)) coordination environments, in which the donor atoms are provided by bromide anions and nitrogen atoms of the 2,2':6',2"-terpyridine ligands. Complex 1 contains [(terpy)₄Pb₉Br₂₀]^2- building blocks. These bromoplumbate(II) clusters are connected by (terpy)₂Cu₂Br₄ units along the crystallographic b axis and by PbBr₆ units along the a axis, thereby forming an extended sheet structure.

Original language	English
Pages (from-to)	617-623
Number of pages	7
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	70
Issue number	9
DOIs	https://doi.org/10.1515/znb-2015-0041
State	Published - 1 Sep 2015

Keywords

Bromoplumbate
Cluster
Coordination polymer
Heterometallic complex
Organic-inorganic hybrids

Access to Document

10.1515/znb-2015-0041

Cite this

@article{85160d75e66646929419ea40829a02a0,

title = "Synthesis and structural characterization of a novel copper(II)/lead(II) heterometallic organic-inorganic hybrid",

abstract = "A new copper(II)/lead(II) complex [(terpy)3CuPb5Br12] (1) (terpy = 2,2':6',2{"}-terpyridine) has been synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. The copper(II) and lead(II) ions in the title complex are in distorted six-(Cu(II), Pb(II)) and eight-fold (Pb(II)) coordination environments, in which the donor atoms are provided by bromide anions and nitrogen atoms of the 2,2':6',2{"}-terpyridine ligands. Complex 1 contains [(terpy)4Pb9Br20]2- building blocks. These bromoplumbate(II) clusters are connected by (terpy)2Cu2Br4 units along the crystallographic b axis and by PbBr6 units along the a axis, thereby forming an extended sheet structure.",

keywords = "Bromoplumbate, Cluster, Coordination polymer, Heterometallic complex, Organic-inorganic hybrids",

author = "Wang, \{Gao Feng\} and Xiao Zhang and Sun, \{Shu Wen\} and Yao, \{Chen Zhong\} and Liu, \{Zhao Rong\} and Wang, \{Yu Chun\} and Liu, \{Yuan Zhong\}",

year = "2015",

month = sep,

day = "1",

doi = "10.1515/znb-2015-0041",

language = "英语",

volume = "70",

pages = "617--623",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "9",

}

TY - JOUR

T1 - Synthesis and structural characterization of a novel copper(II)/lead(II) heterometallic organic-inorganic hybrid

AU - Wang, Gao Feng

AU - Zhang, Xiao

AU - Sun, Shu Wen

AU - Yao, Chen Zhong

AU - Liu, Zhao Rong

AU - Wang, Yu Chun

AU - Liu, Yuan Zhong

PY - 2015/9/1

Y1 - 2015/9/1

N2 - A new copper(II)/lead(II) complex [(terpy)3CuPb5Br12] (1) (terpy = 2,2':6',2"-terpyridine) has been synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. The copper(II) and lead(II) ions in the title complex are in distorted six-(Cu(II), Pb(II)) and eight-fold (Pb(II)) coordination environments, in which the donor atoms are provided by bromide anions and nitrogen atoms of the 2,2':6',2"-terpyridine ligands. Complex 1 contains [(terpy)4Pb9Br20]2- building blocks. These bromoplumbate(II) clusters are connected by (terpy)2Cu2Br4 units along the crystallographic b axis and by PbBr6 units along the a axis, thereby forming an extended sheet structure.

AB - A new copper(II)/lead(II) complex [(terpy)3CuPb5Br12] (1) (terpy = 2,2':6',2"-terpyridine) has been synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. The copper(II) and lead(II) ions in the title complex are in distorted six-(Cu(II), Pb(II)) and eight-fold (Pb(II)) coordination environments, in which the donor atoms are provided by bromide anions and nitrogen atoms of the 2,2':6',2"-terpyridine ligands. Complex 1 contains [(terpy)4Pb9Br20]2- building blocks. These bromoplumbate(II) clusters are connected by (terpy)2Cu2Br4 units along the crystallographic b axis and by PbBr6 units along the a axis, thereby forming an extended sheet structure.

KW - Bromoplumbate

KW - Cluster

KW - Coordination polymer

KW - Heterometallic complex

KW - Organic-inorganic hybrids

UR - https://www.scopus.com/pages/publications/84957563833

U2 - 10.1515/znb-2015-0041

DO - 10.1515/znb-2015-0041

M3 - 文章

AN - SCOPUS:84957563833

SN - 0932-0776

VL - 70

SP - 617

EP - 623

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 9

ER -

Synthesis and structural characterization of a novel copper(II)/lead(II) heterometallic organic-inorganic hybrid

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this