Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands

Gao Feng Wang; Xiao Zhang; Shu Wen Sun; Hong Sun; Wen Chan Zhang; Xia Yang; Ying Lian Qin; Hui Xuan Ma

doi:10.1134/S1063774517060268

Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands

Gao Feng Wang^*
, Xiao Zhang
, Shu Wen Sun
, Hong Sun
, Wen Chan Zhang
, Xia Yang
, Ying Lian Qin
, Hui Xuan Ma

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A copper complex with V-shaped ligands, [(L¹)Cu₂Cl₂]_n (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/_c with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R₁ = 0.0681, and wR₂ = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.

Original language	English
Pages (from-to)	881-884
Number of pages	4
Journal	Crystallography Reports
Volume	62
Issue number	6
DOIs	https://doi.org/10.1134/S1063774517060268
State	Published - 1 Nov 2017
Externally published	Yes

Access to Document

10.1134/S1063774517060268

Cite this

@article{fe07bd1ab40a4590989ee13f0944be98,

title = "Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands",

abstract = "A copper complex with V-shaped ligands, [(L1)Cu2Cl2]n (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/c with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) {\AA}, and β = 112.875(6)°, Z = 4, R1 = 0.0681, and wR2 = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.",

author = "Wang, \{Gao Feng\} and Xiao Zhang and Sun, \{Shu Wen\} and Hong Sun and Zhang, \{Wen Chan\} and Xia Yang and Qin, \{Ying Lian\} and Ma, \{Hui Xuan\}",

note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Inc.",

year = "2017",

month = nov,

day = "1",

doi = "10.1134/S1063774517060268",

language = "英语",

volume = "62",

pages = "881--884",

journal = "Crystallography Reports",

issn = "1063-7745",

publisher = "Pleiades Publishing",

number = "6",

}

TY - JOUR

T1 - Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands

AU - Wang, Gao Feng

AU - Zhang, Xiao

AU - Sun, Shu Wen

AU - Sun, Hong

AU - Zhang, Wen Chan

AU - Yang, Xia

AU - Qin, Ying Lian

AU - Ma, Hui Xuan

PY - 2017/11/1

Y1 - 2017/11/1

N2 - A copper complex with V-shaped ligands, [(L1)Cu2Cl2]n (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/c with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R1 = 0.0681, and wR2 = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.

AB - A copper complex with V-shaped ligands, [(L1)Cu2Cl2]n (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/c with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R1 = 0.0681, and wR2 = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.

UR - https://www.scopus.com/pages/publications/85034596487

U2 - 10.1134/S1063774517060268

DO - 10.1134/S1063774517060268

M3 - 文章

AN - SCOPUS:85034596487

SN - 1063-7745

VL - 62

SP - 881

EP - 884

JO - Crystallography Reports

JF - Crystallography Reports

IS - 6

ER -

Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands

Abstract

Access to Document

Other files and links

Fingerprint

Cite this