Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

Jia Zhang; Bryan J. Foley; Nattamai Bhuvanesh; Jia Zhou; Daron E. Janzen; Matthew T. Whited; Oleg V. Ozerov

doi:10.1021/acs.organomet.8b00594

Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

Jia Zhang
, Bryan J. Foley
, Nattamai Bhuvanesh
, Jia Zhou
, Daron E. Janzen
, Matthew T. Whited^*
, Oleg V. Ozerov

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Preparation and characterization of a series of pincer-type [P₂Si]Co complexes are reported, including a crystal structure of the first base-free cobalt silylene complex. The cationic silylene complex is strongly Lewis acidic and oxophilic, readily coordinating Lewis bases such as triflate and pyridine and heterolytically cleaving the O-H bonds in ethanol and water.

Original language	English
Pages (from-to)	3956-3962
Number of pages	7
Journal	Organometallics
Volume	37
Issue number	21
DOIs	https://doi.org/10.1021/acs.organomet.8b00594
State	Published - 12 Nov 2018
Externally published	Yes

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title = "Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes",

abstract = "Preparation and characterization of a series of pincer-type [P2Si]Co complexes are reported, including a crystal structure of the first base-free cobalt silylene complex. The cationic silylene complex is strongly Lewis acidic and oxophilic, readily coordinating Lewis bases such as triflate and pyridine and heterolytically cleaving the O-H bonds in ethanol and water.",

author = "Jia Zhang and Foley, \{Bryan J.\} and Nattamai Bhuvanesh and Jia Zhou and Janzen, \{Daron E.\} and Whited, \{Matthew T.\} and Ozerov, \{Oleg V.\}",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = nov,

day = "12",

doi = "10.1021/acs.organomet.8b00594",

language = "英语",

volume = "37",

pages = "3956--3962",

journal = "Organometallics",

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publisher = "American Chemical Society",

number = "21",

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TY - JOUR

T1 - Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

AU - Zhang, Jia

AU - Foley, Bryan J.

AU - Bhuvanesh, Nattamai

AU - Zhou, Jia

AU - Janzen, Daron E.

AU - Whited, Matthew T.

AU - Ozerov, Oleg V.

PY - 2018/11/12

Y1 - 2018/11/12

N2 - Preparation and characterization of a series of pincer-type [P2Si]Co complexes are reported, including a crystal structure of the first base-free cobalt silylene complex. The cationic silylene complex is strongly Lewis acidic and oxophilic, readily coordinating Lewis bases such as triflate and pyridine and heterolytically cleaving the O-H bonds in ethanol and water.

AB - Preparation and characterization of a series of pincer-type [P2Si]Co complexes are reported, including a crystal structure of the first base-free cobalt silylene complex. The cationic silylene complex is strongly Lewis acidic and oxophilic, readily coordinating Lewis bases such as triflate and pyridine and heterolytically cleaving the O-H bonds in ethanol and water.

UR - https://www.scopus.com/pages/publications/85055038557

U2 - 10.1021/acs.organomet.8b00594

DO - 10.1021/acs.organomet.8b00594

M3 - 文章

AN - SCOPUS:85055038557

SN - 0276-7333

VL - 37

SP - 3956

EP - 3962

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

Abstract

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