Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

A. N. Gusev; V. F. Shul'gin; E. V. Braga; I. Nemec; B. F. Minaev; G. V. Baryshnikov; Z. Trávníček; H. Ågren; I. L. Eremenko; K. A. Lyssenko; W. Linert

doi:10.1016/j.poly.2018.08.019

Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

A. N. Gusev^*
, V. F. Shul'gin
, E. V. Braga
, I. Nemec
, B. F. Minaev
, G. V. Baryshnikov
, Z. Trávníček
, H. Ågren
, I. L. Eremenko
, K. A. Lyssenko
, W. Linert

^*Corresponding author for this work

Russian Academy of Sciences
Palacký University Olomouc
KTH Royal Institute of Technology
Uppsala University
A.N. Nesmeyanov Institute of Organoelement Compounds
TU Wien

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The present article reports on the syntheses, crystal structures and luminescence properties of three solvate forms of a zinc(II) complex containing 4-{(E)-[(2-fluorophenyl)imino]methyl}-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one (HL). The reaction of zinc(II)acetate with the HL ligand in ethanol and acetonitrile led to the formation of two solvate analogues [Zn(L)₂]·Solv (Solv – ethanol (1) and acetonitrile (2)). The properties of the [Zn(L)₂]·Solv complexes were investigated by UV–Vis absorption and fluorescence emission spectroscopy, and the density functional theory calculations. Bader's topological analysis was performed to investigate the electronic peculiarities of Zn(II) polyhedra and non-covalent interactions within crystal packing of studied solvates.

Original language	English
Pages (from-to)	202-208
Number of pages	7
Journal	Polyhedron
Volume	155
DOIs	https://doi.org/10.1016/j.poly.2018.08.019
State	Published - 15 Nov 2018
Externally published	Yes

Keywords

Crystal structures
Density functional theory
Photophysical properties
Schiff base
Zinc(II) complex

Access to Document

10.1016/j.poly.2018.08.019

Cite this

Gusev, A. N., Shul'gin, V. F., Braga, E. V., Nemec, I., Minaev, B. F., Baryshnikov, G. V., Trávníček, Z., Ågren, H., Eremenko, I. L., Lyssenko, K. A., & Linert, W. (2018). Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence. Polyhedron, 155, 202-208. https://doi.org/10.1016/j.poly.2018.08.019

@article{faab4d9ab5bb4be6ac60760ddeac228a,

title = "Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence",

abstract = "The present article reports on the syntheses, crystal structures and luminescence properties of three solvate forms of a zinc(II) complex containing 4-\{(E)-[(2-fluorophenyl)imino]methyl\}-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one (HL). The reaction of zinc(II)acetate with the HL ligand in ethanol and acetonitrile led to the formation of two solvate analogues [Zn(L)2]·Solv (Solv – ethanol (1) and acetonitrile (2)). The properties of the [Zn(L)2]·Solv complexes were investigated by UV–Vis absorption and fluorescence emission spectroscopy, and the density functional theory calculations. Bader's topological analysis was performed to investigate the electronic peculiarities of Zn(II) polyhedra and non-covalent interactions within crystal packing of studied solvates.",

keywords = "Crystal structures, Density functional theory, Photophysical properties, Schiff base, Zinc(II) complex",

author = "Gusev, \{A. N.\} and Shul'gin, \{V. F.\} and Braga, \{E. V.\} and I. Nemec and Minaev, \{B. F.\} and Baryshnikov, \{G. V.\} and Z. Tr{\'a}vn{\'i}{\v c}ek and H. {\AA}gren and Eremenko, \{I. L.\} and Lyssenko, \{K. A.\} and W. Linert",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",

year = "2018",

month = nov,

day = "15",

doi = "10.1016/j.poly.2018.08.019",

language = "英语",

volume = "155",

pages = "202--208",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

AU - Gusev, A. N.

AU - Shul'gin, V. F.

AU - Braga, E. V.

AU - Nemec, I.

AU - Minaev, B. F.

AU - Baryshnikov, G. V.

AU - Trávníček, Z.

AU - Ågren, H.

AU - Eremenko, I. L.

AU - Lyssenko, K. A.

AU - Linert, W.

PY - 2018/11/15

Y1 - 2018/11/15

N2 - The present article reports on the syntheses, crystal structures and luminescence properties of three solvate forms of a zinc(II) complex containing 4-{(E)-[(2-fluorophenyl)imino]methyl}-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one (HL). The reaction of zinc(II)acetate with the HL ligand in ethanol and acetonitrile led to the formation of two solvate analogues [Zn(L)2]·Solv (Solv – ethanol (1) and acetonitrile (2)). The properties of the [Zn(L)2]·Solv complexes were investigated by UV–Vis absorption and fluorescence emission spectroscopy, and the density functional theory calculations. Bader's topological analysis was performed to investigate the electronic peculiarities of Zn(II) polyhedra and non-covalent interactions within crystal packing of studied solvates.

AB - The present article reports on the syntheses, crystal structures and luminescence properties of three solvate forms of a zinc(II) complex containing 4-{(E)-[(2-fluorophenyl)imino]methyl}-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one (HL). The reaction of zinc(II)acetate with the HL ligand in ethanol and acetonitrile led to the formation of two solvate analogues [Zn(L)2]·Solv (Solv – ethanol (1) and acetonitrile (2)). The properties of the [Zn(L)2]·Solv complexes were investigated by UV–Vis absorption and fluorescence emission spectroscopy, and the density functional theory calculations. Bader's topological analysis was performed to investigate the electronic peculiarities of Zn(II) polyhedra and non-covalent interactions within crystal packing of studied solvates.

KW - Crystal structures

KW - Density functional theory

KW - Photophysical properties

KW - Schiff base

KW - Zinc(II) complex

UR - https://www.scopus.com/pages/publications/85052641720

U2 - 10.1016/j.poly.2018.08.019

DO - 10.1016/j.poly.2018.08.019

M3 - 文章

AN - SCOPUS:85052641720

SN - 0277-5387

VL - 155

SP - 202

EP - 208

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this