Synthesis and hypergolic properties of flammable ionic liquids based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion

Zhi Wang; Yunhe Jin; Wenquan Zhang; Binshen Wang; Tianlin Liu; Jiaheng Zhang; Qinghua Zhang

doi:10.1039/c9dt00958b

Synthesis and hypergolic properties of flammable ionic liquids based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion

Zhi Wang
, Yunhe Jin
, Wenquan Zhang^*
, Binshen Wang
, Tianlin Liu
, Jiaheng Zhang
, Qinghua Zhang

^*Corresponding author for this work

China Academy of Engineering Physics
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A series of hypergolic ionic liquids (HILs) based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion were synthesized by introducing the {BH₂-CN} moiety into the 1,2,3-triazole anion. This introduction allowed us to improve the self-ignition property and decrease the viscosity of ionic fuels. The synthesized series of HILs exhibited wide liquid operating ranges (>220 °C), high densities (>1 g cm^-3), low viscosities (as low as 22.48 cP), and ignition delay (ID) times as short as 5 ms by using white fuming nitric acid (WFNA) as the oxidizer. Furthermore, these HILs can be ignited upon contact with a 90 wt% H₂O₂ oxidizer in the presence of iodine.

Original language	English
Pages (from-to)	6198-6204
Number of pages	7
Journal	Dalton Transactions
Volume	48
Issue number	18
DOIs	https://doi.org/10.1039/c9dt00958b
State	Published - 2019
Externally published	Yes

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title = "Synthesis and hypergolic properties of flammable ionic liquids based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion",

abstract = "A series of hypergolic ionic liquids (HILs) based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion were synthesized by introducing the \{BH2-CN\} moiety into the 1,2,3-triazole anion. This introduction allowed us to improve the self-ignition property and decrease the viscosity of ionic fuels. The synthesized series of HILs exhibited wide liquid operating ranges (>220 °C), high densities (>1 g cm-3), low viscosities (as low as 22.48 cP), and ignition delay (ID) times as short as 5 ms by using white fuming nitric acid (WFNA) as the oxidizer. Furthermore, these HILs can be ignited upon contact with a 90 wt\% H2O2 oxidizer in the presence of iodine.",

author = "Zhi Wang and Yunhe Jin and Wenquan Zhang and Binshen Wang and Tianlin Liu and Jiaheng Zhang and Qinghua Zhang",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2019.",

year = "2019",

doi = "10.1039/c9dt00958b",

language = "英语",

volume = "48",

pages = "6198--6204",

journal = "Dalton Transactions",

issn = "1477-9226",

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TY - JOUR

T1 - Synthesis and hypergolic properties of flammable ionic liquids based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion

AU - Wang, Zhi

AU - Jin, Yunhe

AU - Zhang, Wenquan

AU - Wang, Binshen

AU - Liu, Tianlin

AU - Zhang, Jiaheng

AU - Zhang, Qinghua

N1 - Publisher Copyright: © The Royal Society of Chemistry 2019.

PY - 2019

Y1 - 2019

N2 - A series of hypergolic ionic liquids (HILs) based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion were synthesized by introducing the {BH2-CN} moiety into the 1,2,3-triazole anion. This introduction allowed us to improve the self-ignition property and decrease the viscosity of ionic fuels. The synthesized series of HILs exhibited wide liquid operating ranges (>220 °C), high densities (>1 g cm-3), low viscosities (as low as 22.48 cP), and ignition delay (ID) times as short as 5 ms by using white fuming nitric acid (WFNA) as the oxidizer. Furthermore, these HILs can be ignited upon contact with a 90 wt% H2O2 oxidizer in the presence of iodine.

AB - A series of hypergolic ionic liquids (HILs) based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion were synthesized by introducing the {BH2-CN} moiety into the 1,2,3-triazole anion. This introduction allowed us to improve the self-ignition property and decrease the viscosity of ionic fuels. The synthesized series of HILs exhibited wide liquid operating ranges (>220 °C), high densities (>1 g cm-3), low viscosities (as low as 22.48 cP), and ignition delay (ID) times as short as 5 ms by using white fuming nitric acid (WFNA) as the oxidizer. Furthermore, these HILs can be ignited upon contact with a 90 wt% H2O2 oxidizer in the presence of iodine.

UR - https://www.scopus.com/pages/publications/85065465174

U2 - 10.1039/c9dt00958b

DO - 10.1039/c9dt00958b

M3 - 文章

C2 - 30977494

AN - SCOPUS:85065465174

SN - 1477-9226

VL - 48

SP - 6198

EP - 6204

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

Synthesis and hypergolic properties of flammable ionic liquids based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion

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