Synthesis and crystal structure of transition metal coordination compounds with triethylenediamine ligand and their florescence properties studies

Yan Ping Huang; Xiao Zhang; Lei Liu; Nan Xi Zhang; Xian Zhu Xu

doi:10.11862/CJIC.2014.186

Synthesis and crystal structure of transition metal coordination compounds with triethylenediamine ligand and their florescence properties studies

Yan Ping Huang
, Xiao Zhang^*
, Lei Liu
, Nan Xi Zhang
, Xian Zhu Xu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology
School of Life Science and Technology, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A series of transition metal coordination compounds based on the ligand, triethylenediamine (dabco), [CdCl₃H (dabco)₂] (1), [CoCl₃Hdabco] (2), [NiCl₂ (H₂O)₃Hdabco]Cl (3), [CuCl₃H (dabco)₂]Cl · H₂O (4) have been prepared and characterized by elemental analyses, IR spectra, thermogravimety and single crystal X-Ray diffraction structure analyses. Compound 1 displays an one-dimensional straight chain via the hydrogen bonding interactions. Compound 2 possesses the left helix molecular structure. Compound 3 possesses the right helix molecular structure and compound 4 exhibits a two-dimensional molecular sheet with grids. Compounds 1 to 4 show intensive photoluminescence. CCDC: 929375 for 1; 929376 for 2; 929377 for 3; 929378 for 4.

Original language	English
Pages (from-to)	1001-1008
Number of pages	8
Journal	Chinese Journal of Inorganic Chemistry
Volume	30
Issue number	5
DOIs	https://doi.org/10.11862/CJIC.2014.186
State	Published - 2014

Keywords

Crystal structure
Florescence properties
Transition-metal coordination compounds
Triethylenediamine

Access to Document

10.11862/CJIC.2014.186

Cite this

@article{c72cd52850aa449bb8a824ac90f1b5d8,

title = "Synthesis and crystal structure of transition metal coordination compounds with triethylenediamine ligand and their florescence properties studies",

abstract = "A series of transition metal coordination compounds based on the ligand, triethylenediamine (dabco), [CdCl3H (dabco)2] (1), [CoCl3Hdabco] (2), [NiCl2 (H2O)3Hdabco]Cl (3), [CuCl3H (dabco)2]Cl · H2O (4) have been prepared and characterized by elemental analyses, IR spectra, thermogravimety and single crystal X-Ray diffraction structure analyses. Compound 1 displays an one-dimensional straight chain via the hydrogen bonding interactions. Compound 2 possesses the left helix molecular structure. Compound 3 possesses the right helix molecular structure and compound 4 exhibits a two-dimensional molecular sheet with grids. Compounds 1 to 4 show intensive photoluminescence. CCDC: 929375 for 1; 929376 for 2; 929377 for 3; 929378 for 4.",

keywords = "Crystal structure, Florescence properties, Transition-metal coordination compounds, Triethylenediamine",

author = "Huang, \{Yan Ping\} and Xiao Zhang and Lei Liu and Zhang, \{Nan Xi\} and Xu, \{Xian Zhu\}",

year = "2014",

doi = "10.11862/CJIC.2014.186",

language = "英语",

volume = "30",

pages = "1001--1008",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "5",

}

TY - JOUR

T1 - Synthesis and crystal structure of transition metal coordination compounds with triethylenediamine ligand and their florescence properties studies

AU - Huang, Yan Ping

AU - Zhang, Xiao

AU - Liu, Lei

AU - Zhang, Nan Xi

AU - Xu, Xian Zhu

PY - 2014

Y1 - 2014

N2 - A series of transition metal coordination compounds based on the ligand, triethylenediamine (dabco), [CdCl3H (dabco)2] (1), [CoCl3Hdabco] (2), [NiCl2 (H2O)3Hdabco]Cl (3), [CuCl3H (dabco)2]Cl · H2O (4) have been prepared and characterized by elemental analyses, IR spectra, thermogravimety and single crystal X-Ray diffraction structure analyses. Compound 1 displays an one-dimensional straight chain via the hydrogen bonding interactions. Compound 2 possesses the left helix molecular structure. Compound 3 possesses the right helix molecular structure and compound 4 exhibits a two-dimensional molecular sheet with grids. Compounds 1 to 4 show intensive photoluminescence. CCDC: 929375 for 1; 929376 for 2; 929377 for 3; 929378 for 4.

AB - A series of transition metal coordination compounds based on the ligand, triethylenediamine (dabco), [CdCl3H (dabco)2] (1), [CoCl3Hdabco] (2), [NiCl2 (H2O)3Hdabco]Cl (3), [CuCl3H (dabco)2]Cl · H2O (4) have been prepared and characterized by elemental analyses, IR spectra, thermogravimety and single crystal X-Ray diffraction structure analyses. Compound 1 displays an one-dimensional straight chain via the hydrogen bonding interactions. Compound 2 possesses the left helix molecular structure. Compound 3 possesses the right helix molecular structure and compound 4 exhibits a two-dimensional molecular sheet with grids. Compounds 1 to 4 show intensive photoluminescence. CCDC: 929375 for 1; 929376 for 2; 929377 for 3; 929378 for 4.

KW - Crystal structure

KW - Florescence properties

KW - Transition-metal coordination compounds

KW - Triethylenediamine

UR - https://www.scopus.com/pages/publications/84902129240

U2 - 10.11862/CJIC.2014.186

DO - 10.11862/CJIC.2014.186

M3 - 文章

AN - SCOPUS:84902129240

SN - 1001-4861

VL - 30

SP - 1001

EP - 1008

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 5

ER -

Synthesis and crystal structure of transition metal coordination compounds with triethylenediamine ligand and their florescence properties studies

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this