Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability

Peng Ren; Wei Shi; Peng Cheng

doi:10.1021/cg700740m

Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability

Peng Ren
, Wei Shi
, Peng Cheng^*

^*Corresponding author for this work

Nankai University

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Using 1,2-bis(4-pyridyl)ethane (bpe) and benzene- 1,3-biscarboxylic acid (H₂bba) as ligands, two novel heterometallic three-dimensional coordination polymers {[Zn₃Mn_1.5(bpe)(bba) ₄(Hbba)]-bpe}., (Mn-Zn) and {[Zn₂Pr(bpe)(bba) ₃(Hbba)]·H₂O}_n(Pr-Zn) were isolated under hydrothermal conditions. Both complexes are constructed via 3d-3d and 3d-4f clusters as secondary building units, respectively, which represent the first template synthesis for 3D heterometallic MOFs.

Original language	English
Pages (from-to)	1097-1099
Number of pages	3
Journal	Crystal Growth and Design
Volume	8
Issue number	4
DOIs	https://doi.org/10.1021/cg700740m
State	Published - Apr 2008
Externally published	Yes

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title = "Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability",

abstract = "Using 1,2-bis(4-pyridyl)ethane (bpe) and benzene- 1,3-biscarboxylic acid (H2bba) as ligands, two novel heterometallic three-dimensional coordination polymers \{[Zn3Mn1.5(bpe)(bba) 4(Hbba)]-bpe\}., (Mn-Zn) and \{[Zn2Pr(bpe)(bba) 3(Hbba)]·H2O\}n(Pr-Zn) were isolated under hydrothermal conditions. Both complexes are constructed via 3d-3d and 3d-4f clusters as secondary building units, respectively, which represent the first template synthesis for 3D heterometallic MOFs.",

author = "Peng Ren and Wei Shi and Peng Cheng",

year = "2008",

month = apr,

doi = "10.1021/cg700740m",

language = "英语",

volume = "8",

pages = "1097--1099",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability

AU - Ren, Peng

AU - Shi, Wei

AU - Cheng, Peng

PY - 2008/4

Y1 - 2008/4

N2 - Using 1,2-bis(4-pyridyl)ethane (bpe) and benzene- 1,3-biscarboxylic acid (H2bba) as ligands, two novel heterometallic three-dimensional coordination polymers {[Zn3Mn1.5(bpe)(bba) 4(Hbba)]-bpe}., (Mn-Zn) and {[Zn2Pr(bpe)(bba) 3(Hbba)]·H2O}n(Pr-Zn) were isolated under hydrothermal conditions. Both complexes are constructed via 3d-3d and 3d-4f clusters as secondary building units, respectively, which represent the first template synthesis for 3D heterometallic MOFs.

AB - Using 1,2-bis(4-pyridyl)ethane (bpe) and benzene- 1,3-biscarboxylic acid (H2bba) as ligands, two novel heterometallic three-dimensional coordination polymers {[Zn3Mn1.5(bpe)(bba) 4(Hbba)]-bpe}., (Mn-Zn) and {[Zn2Pr(bpe)(bba) 3(Hbba)]·H2O}n(Pr-Zn) were isolated under hydrothermal conditions. Both complexes are constructed via 3d-3d and 3d-4f clusters as secondary building units, respectively, which represent the first template synthesis for 3D heterometallic MOFs.

UR - https://www.scopus.com/pages/publications/49149120350

U2 - 10.1021/cg700740m

DO - 10.1021/cg700740m

M3 - 文章

AN - SCOPUS:49149120350

SN - 1528-7483

VL - 8

SP - 1097

EP - 1099

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 4

ER -

Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability

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