Synthesis and characterization of monosubstituted TTF and its solvent dependent mono- and dication charge-transfer salts

Yu Wang; Shuxin Cui; Bo Li; Jingping Zhang; Yan Zhang

doi:10.1021/cg900635f

Synthesis and characterization of monosubstituted TTF and its solvent dependent mono- and dication charge-transfer salts

Yu Wang
, Shuxin Cui
, Bo Li
, Jingping Zhang^*
, Yan Zhang

^*Corresponding author for this work

Northeast Normal University
Peking University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The synthesis and characterization of the novel asymmetric l-(4-(tetrathiafulvaleneyl)phenyl)ethanone (TTF-PEO) toward the precursor for multifunctional material are described. The tuning of the charge-transfer of TTF-PEO by solvent was-realized forming the mono- and dication complexes (TTF-PEO)₂CuBr₄ and (TTF-PEO)₂(CuBr ₄)₂ • CH₂Cl₂ • CH ₃CN in the triclinic Pl and the orthorhombic Pbca space group, respectively. The antiferromagnetic behavior for the monocation radical TTF-PEO⁺ salt with CuBr₄^2- displayed obvious phase transition at 110-120 K.

Original language	English
Pages (from-to)	3855-3858
Number of pages	4
Journal	Crystal Growth and Design
Volume	9
Issue number	9
DOIs	https://doi.org/10.1021/cg900635f
State	Published - 2 Sep 2009
Externally published	Yes

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title = "Synthesis and characterization of monosubstituted TTF and its solvent dependent mono- and dication charge-transfer salts",

abstract = "The synthesis and characterization of the novel asymmetric l-(4-(tetrathiafulvaleneyl)phenyl)ethanone (TTF-PEO) toward the precursor for multifunctional material are described. The tuning of the charge-transfer of TTF-PEO by solvent was-realized forming the mono- and dication complexes (TTF-PEO)2CuBr4 and (TTF-PEO)2(CuBr 4)2 • CH2Cl2 • CH 3CN in the triclinic Pl and the orthorhombic Pbca space group, respectively. The antiferromagnetic behavior for the monocation radical TTF-PEO+ salt with CuBr42- displayed obvious phase transition at 110-120 K.",

author = "Yu Wang and Shuxin Cui and Bo Li and Jingping Zhang and Yan Zhang",

year = "2009",

month = sep,

day = "2",

doi = "10.1021/cg900635f",

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journal = "Crystal Growth and Design",

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TY - JOUR

T1 - Synthesis and characterization of monosubstituted TTF and its solvent dependent mono- and dication charge-transfer salts

AU - Wang, Yu

AU - Cui, Shuxin

AU - Li, Bo

AU - Zhang, Jingping

AU - Zhang, Yan

PY - 2009/9/2

Y1 - 2009/9/2

N2 - The synthesis and characterization of the novel asymmetric l-(4-(tetrathiafulvaleneyl)phenyl)ethanone (TTF-PEO) toward the precursor for multifunctional material are described. The tuning of the charge-transfer of TTF-PEO by solvent was-realized forming the mono- and dication complexes (TTF-PEO)2CuBr4 and (TTF-PEO)2(CuBr 4)2 • CH2Cl2 • CH 3CN in the triclinic Pl and the orthorhombic Pbca space group, respectively. The antiferromagnetic behavior for the monocation radical TTF-PEO+ salt with CuBr42- displayed obvious phase transition at 110-120 K.

AB - The synthesis and characterization of the novel asymmetric l-(4-(tetrathiafulvaleneyl)phenyl)ethanone (TTF-PEO) toward the precursor for multifunctional material are described. The tuning of the charge-transfer of TTF-PEO by solvent was-realized forming the mono- and dication complexes (TTF-PEO)2CuBr4 and (TTF-PEO)2(CuBr 4)2 • CH2Cl2 • CH 3CN in the triclinic Pl and the orthorhombic Pbca space group, respectively. The antiferromagnetic behavior for the monocation radical TTF-PEO+ salt with CuBr42- displayed obvious phase transition at 110-120 K.

UR - https://www.scopus.com/pages/publications/70049090840

U2 - 10.1021/cg900635f

DO - 10.1021/cg900635f

M3 - 文章

AN - SCOPUS:70049090840

SN - 1528-7483

VL - 9

SP - 3855

EP - 3858

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 9

ER -

Synthesis and characterization of monosubstituted TTF and its solvent dependent mono- and dication charge-transfer salts

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