Synthesis and characterization of L-glutamic acid bridged porphyrin and its CD spectrum

Xi Ming Guo; Lian Jiang Su; Lian Xiang Yu; Tong Shun Shi

Synthesis and characterization of L-glutamic acid bridged porphyrin and its CD spectrum

Xi Ming Guo^*
, Lian Jiang Su
, Lian Xiang Yu
, Tong Shun Shi

^*Corresponding author for this work

College of Chemistry
Daqing Teachers College

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The L-glutamicacyl dichloride was prepared by the reaction of L-glutamic acid (NH₂ was protected by using acetyl group) with SOCl₂, then reacted with 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin, to give L-glutamic acid bridged diporphyrins. The compound was confirmed by using IR, ¹H NMR, UV-Vis and elemental analysis. The chiral characteristics of the dimmer was studied by the circular dichroism (CD) spectrum.

Original language	English
Pages (from-to)	410-413
Number of pages	4
Journal	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume	27
Issue number	3
State	Published - Mar 2006
Externally published	Yes

Keywords

5-(4-Hydroxylphenyl)-10,15,20-triphenylporphyrin (MHTPP)
Circula dichroism spectrum
Dimers
L-Glutamic acid

Cite this

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title = "Synthesis and characterization of L-glutamic acid bridged porphyrin and its CD spectrum",

abstract = "The L-glutamicacyl dichloride was prepared by the reaction of L-glutamic acid (NH2 was protected by using acetyl group) with SOCl2, then reacted with 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin, to give L-glutamic acid bridged diporphyrins. The compound was confirmed by using IR, 1H NMR, UV-Vis and elemental analysis. The chiral characteristics of the dimmer was studied by the circular dichroism (CD) spectrum.",

keywords = "5-(4-Hydroxylphenyl)-10,15,20-triphenylporphyrin (MHTPP), Circula dichroism spectrum, Dimers, L-Glutamic acid",

author = "Guo, \{Xi Ming\} and Su, \{Lian Jiang\} and Yu, \{Lian Xiang\} and Shi, \{Tong Shun\}",

year = "2006",

month = mar,

language = "英语",

volume = "27",

pages = "410--413",

journal = "Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities",

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TY - JOUR

T1 - Synthesis and characterization of L-glutamic acid bridged porphyrin and its CD spectrum

AU - Guo, Xi Ming

AU - Su, Lian Jiang

AU - Yu, Lian Xiang

AU - Shi, Tong Shun

PY - 2006/3

Y1 - 2006/3

N2 - The L-glutamicacyl dichloride was prepared by the reaction of L-glutamic acid (NH2 was protected by using acetyl group) with SOCl2, then reacted with 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin, to give L-glutamic acid bridged diporphyrins. The compound was confirmed by using IR, 1H NMR, UV-Vis and elemental analysis. The chiral characteristics of the dimmer was studied by the circular dichroism (CD) spectrum.

AB - The L-glutamicacyl dichloride was prepared by the reaction of L-glutamic acid (NH2 was protected by using acetyl group) with SOCl2, then reacted with 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin, to give L-glutamic acid bridged diporphyrins. The compound was confirmed by using IR, 1H NMR, UV-Vis and elemental analysis. The chiral characteristics of the dimmer was studied by the circular dichroism (CD) spectrum.

KW - 5-(4-Hydroxylphenyl)-10,15,20-triphenylporphyrin (MHTPP)

KW - Circula dichroism spectrum

KW - Dimers

KW - L-Glutamic acid

UR - https://www.scopus.com/pages/publications/33645919020

M3 - 文章

AN - SCOPUS:33645919020

SN - 0251-0790

VL - 27

SP - 410

EP - 413

JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

IS - 3

ER -

Synthesis and characterization of L-glutamic acid bridged porphyrin and its CD spectrum

Abstract

Keywords

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