Synthesis and characterization of AB-type diblock copolymer by enzymatic ring-opening polymerization and ATRP

Ke Sha; Dong Shuang Li; Ya Peng Li; Xiao Tian Liu; Peng Ai; Wei Wang; Jing Yuan Wang

Synthesis and characterization of AB-type diblock copolymer by enzymatic ring-opening polymerization and ATRP

Ke Sha^*
, Dong Shuang Li
, Ya Peng Li
, Xiao Tian Liu
, Peng Ai
, Wei Wang
, Jing Yuan Wang

^*Corresponding author for this work

College of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Mono-hydroxyl terminated polycaprolactone (PCL) was prepared by Novozyme 435 catalyzed ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) initiated by methanol, and subsequently converted to bromine ended PCL by the esterification of the resulting macromolecules with α-bromopropionyl bromide. The macroinitiators containing α-bromoester group were employed in the atom transfer radical polymerization (ATRP) of glycidyl methacrylate (GMA) with CuCl/2,2-bipyridine (bpy) as the catalyst system to obtain amphiphilic diblock copolymer PCL-b-PGMA.

Original language	English
Pages (from-to)	985-987
Number of pages	3
Journal	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume	27
Issue number	5
State	Published - May 2006
Externally published	Yes

Keywords

Atom transfer radical polymerization (ATRP)
Block copolymer
Enzyme-promoting ring-opening polymerization
Fixed enzyme Novozyme 435

Cite this

@article{1cb762c7dc8146bbb62ba1635e747568,

title = "Synthesis and characterization of AB-type diblock copolymer by enzymatic ring-opening polymerization and ATRP",

abstract = "Mono-hydroxyl terminated polycaprolactone (PCL) was prepared by Novozyme 435 catalyzed ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) initiated by methanol, and subsequently converted to bromine ended PCL by the esterification of the resulting macromolecules with α-bromopropionyl bromide. The macroinitiators containing α-bromoester group were employed in the atom transfer radical polymerization (ATRP) of glycidyl methacrylate (GMA) with CuCl/2,2-bipyridine (bpy) as the catalyst system to obtain amphiphilic diblock copolymer PCL-b-PGMA.",

keywords = "Atom transfer radical polymerization (ATRP), Block copolymer, Enzyme-promoting ring-opening polymerization, Fixed enzyme Novozyme 435",

author = "Ke Sha and Li, \{Dong Shuang\} and Li, \{Ya Peng\} and Liu, \{Xiao Tian\} and Peng Ai and Wei Wang and Wang, \{Jing Yuan\}",

year = "2006",

month = may,

language = "英语",

volume = "27",

pages = "985--987",

journal = "Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "5",

}

TY - JOUR

T1 - Synthesis and characterization of AB-type diblock copolymer by enzymatic ring-opening polymerization and ATRP

AU - Sha, Ke

AU - Li, Dong Shuang

AU - Li, Ya Peng

AU - Liu, Xiao Tian

AU - Ai, Peng

AU - Wang, Wei

AU - Wang, Jing Yuan

PY - 2006/5

Y1 - 2006/5

N2 - Mono-hydroxyl terminated polycaprolactone (PCL) was prepared by Novozyme 435 catalyzed ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) initiated by methanol, and subsequently converted to bromine ended PCL by the esterification of the resulting macromolecules with α-bromopropionyl bromide. The macroinitiators containing α-bromoester group were employed in the atom transfer radical polymerization (ATRP) of glycidyl methacrylate (GMA) with CuCl/2,2-bipyridine (bpy) as the catalyst system to obtain amphiphilic diblock copolymer PCL-b-PGMA.

AB - Mono-hydroxyl terminated polycaprolactone (PCL) was prepared by Novozyme 435 catalyzed ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) initiated by methanol, and subsequently converted to bromine ended PCL by the esterification of the resulting macromolecules with α-bromopropionyl bromide. The macroinitiators containing α-bromoester group were employed in the atom transfer radical polymerization (ATRP) of glycidyl methacrylate (GMA) with CuCl/2,2-bipyridine (bpy) as the catalyst system to obtain amphiphilic diblock copolymer PCL-b-PGMA.

KW - Atom transfer radical polymerization (ATRP)

KW - Block copolymer

KW - Enzyme-promoting ring-opening polymerization

KW - Fixed enzyme Novozyme 435

UR - https://www.scopus.com/pages/publications/33744949903

M3 - 文章

AN - SCOPUS:33744949903

SN - 0251-0790

VL - 27

SP - 985

EP - 987

JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

IS - 5

ER -

Synthesis and characterization of AB-type diblock copolymer by enzymatic ring-opening polymerization and ATRP

Abstract

Keywords

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