Synthesis and characterization of a water-soluble nylon copolyamide

Yongping Bai; Lei Huang; Tong Huang; Jun Long; Yongfeng Zhou

doi:10.1016/j.polymer.2013.05.070

Synthesis and characterization of a water-soluble nylon copolyamide

Yongping Bai
, Lei Huang
, Tong Huang
, Jun Long^*
, Yongfeng Zhou

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Shanghai Jiao Tong University

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A novel water-soluble copolyamide based on Nylon 66 was synthesized via solution-melt polycondensation of hexanedioic acid and sodium 5-sulfoisophthalate with 1,6-diaminohexane. The chemical structures of the products were ascertained by various spectroscopic techniques (FT-IR, Raman, and ¹H NMR). The thermal properties of the polyamides under consideration were measured by TGA and DSC. According to the temperature dependence of FTIR spectra, it was found that the average strength of the intermolecular hydrogen bond of the water-soluble copolyamides becomes weak with increasing the temperature. It was found that the obtained random copolyamides could self-assemble into spherical micelles in aqueous solution with the size dependent on the hydrophilic fraction according to the DLS and TEM measurements.

Original language	English
Pages (from-to)	4171-4176
Number of pages	6
Journal	Polymer
Volume	54
Issue number	16
DOIs	https://doi.org/10.1016/j.polymer.2013.05.070
State	Published - 19 Jul 2013
Externally published	Yes

Keywords

Micelles
Self-assembly
Water-soluble polyamides

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10.1016/j.polymer.2013.05.070

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title = "Synthesis and characterization of a water-soluble nylon copolyamide",

abstract = "A novel water-soluble copolyamide based on Nylon 66 was synthesized via solution-melt polycondensation of hexanedioic acid and sodium 5-sulfoisophthalate with 1,6-diaminohexane. The chemical structures of the products were ascertained by various spectroscopic techniques (FT-IR, Raman, and 1H NMR). The thermal properties of the polyamides under consideration were measured by TGA and DSC. According to the temperature dependence of FTIR spectra, it was found that the average strength of the intermolecular hydrogen bond of the water-soluble copolyamides becomes weak with increasing the temperature. It was found that the obtained random copolyamides could self-assemble into spherical micelles in aqueous solution with the size dependent on the hydrophilic fraction according to the DLS and TEM measurements.",

keywords = "Micelles, Self-assembly, Water-soluble polyamides",

author = "Yongping Bai and Lei Huang and Tong Huang and Jun Long and Yongfeng Zhou",

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doi = "10.1016/j.polymer.2013.05.070",

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TY - JOUR

T1 - Synthesis and characterization of a water-soluble nylon copolyamide

AU - Bai, Yongping

AU - Huang, Lei

AU - Huang, Tong

AU - Long, Jun

AU - Zhou, Yongfeng

PY - 2013/7/19

Y1 - 2013/7/19

N2 - A novel water-soluble copolyamide based on Nylon 66 was synthesized via solution-melt polycondensation of hexanedioic acid and sodium 5-sulfoisophthalate with 1,6-diaminohexane. The chemical structures of the products were ascertained by various spectroscopic techniques (FT-IR, Raman, and 1H NMR). The thermal properties of the polyamides under consideration were measured by TGA and DSC. According to the temperature dependence of FTIR spectra, it was found that the average strength of the intermolecular hydrogen bond of the water-soluble copolyamides becomes weak with increasing the temperature. It was found that the obtained random copolyamides could self-assemble into spherical micelles in aqueous solution with the size dependent on the hydrophilic fraction according to the DLS and TEM measurements.

AB - A novel water-soluble copolyamide based on Nylon 66 was synthesized via solution-melt polycondensation of hexanedioic acid and sodium 5-sulfoisophthalate with 1,6-diaminohexane. The chemical structures of the products were ascertained by various spectroscopic techniques (FT-IR, Raman, and 1H NMR). The thermal properties of the polyamides under consideration were measured by TGA and DSC. According to the temperature dependence of FTIR spectra, it was found that the average strength of the intermolecular hydrogen bond of the water-soluble copolyamides becomes weak with increasing the temperature. It was found that the obtained random copolyamides could self-assemble into spherical micelles in aqueous solution with the size dependent on the hydrophilic fraction according to the DLS and TEM measurements.

KW - Micelles

KW - Self-assembly

KW - Water-soluble polyamides

UR - https://www.scopus.com/pages/publications/84880038066

U2 - 10.1016/j.polymer.2013.05.070

DO - 10.1016/j.polymer.2013.05.070

M3 - 文章

AN - SCOPUS:84880038066

SN - 0032-3861

VL - 54

SP - 4171

EP - 4176

JO - Polymer

JF - Polymer

IS - 16

ER -

Synthesis and characterization of a water-soluble nylon copolyamide

Abstract

Keywords

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