Synthesis and characterization of a luminescent Ni(II)-compound based on tpt and m-H2bdc detecting picric acid and chromate anions in aqueous

Jinxue Li; Xinrui Zhuang; Nanxi Zhang; Liyan Zhao; Qingfeng Yang; Xiao Zhang

doi:10.1016/j.ica.2019.119096

Synthesis and characterization of a luminescent Ni(II)-compound based on tpt and m-H₂bdc detecting picric acid and chromate anions in aqueous

Jinxue Li
, Xinrui Zhuang
, Nanxi Zhang
, Liyan Zhao
, Qingfeng Yang
, Xiao Zhang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
School of Life Science and Technology, Harbin Institute of Technology
Ningxia University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A new luminescent compound Ni₄(tpt)₄(m-bdc)₄·H₂O (1) (tpt = tris(4-pyridyl)triazine, m-H₂bdc = m-benzenedicarboxylic acid) was successfully synthesized by hydrothermal method, and characterized using single-crystal X-ray diffraction, PXRD, TG analysis and IR. 1 possesses a four-connected three-dimensional (3D) topological network with the Schläfli symbols of {6⁵⋅8}. 1 not only has excellent thermal and chemical stability, but also is a dual-functional luminescent sensor with high selectivity and sensitivity for detection of picric acid (PA) and chromate (CrO₄²⁻) anions in water via the luminescent quenching. And the sensing mechanism for the quenching process was discussed in detail. Moreover, 1 can be regenerated by a fast and simple method in detecting PA and CrO₄²⁻, showing excellent recyclability after the sensing experiment.

Original language	English
Article number	119096
Journal	Inorganica Chimica Acta
Volume	497
DOIs	https://doi.org/10.1016/j.ica.2019.119096
State	Published - 1 Nov 2019
Externally published	Yes

Keywords

Chromate (CrO) anions
Dual-functional luminescent sensor
Hydrothermal synthesis
Metal organic framework
Nitroaromatic compounds

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@article{06b26c85513440f58190a7253b775243,

title = "Synthesis and characterization of a luminescent Ni(II)-compound based on tpt and m-H2bdc detecting picric acid and chromate anions in aqueous",

abstract = "A new luminescent compound Ni4(tpt)4(m-bdc)4·H2O (1) (tpt = tris(4-pyridyl)triazine, m-H2bdc = m-benzenedicarboxylic acid) was successfully synthesized by hydrothermal method, and characterized using single-crystal X-ray diffraction, PXRD, TG analysis and IR. 1 possesses a four-connected three-dimensional (3D) topological network with the Schl{\"a}fli symbols of \{65⋅8\}. 1 not only has excellent thermal and chemical stability, but also is a dual-functional luminescent sensor with high selectivity and sensitivity for detection of picric acid (PA) and chromate (CrO42−) anions in water via the luminescent quenching. And the sensing mechanism for the quenching process was discussed in detail. Moreover, 1 can be regenerated by a fast and simple method in detecting PA and CrO42−, showing excellent recyclability after the sensing experiment.",

keywords = "Chromate (CrO) anions, Dual-functional luminescent sensor, Hydrothermal synthesis, Metal organic framework, Nitroaromatic compounds",

author = "Jinxue Li and Xinrui Zhuang and Nanxi Zhang and Liyan Zhao and Qingfeng Yang and Xiao Zhang",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = nov,

day = "1",

doi = "10.1016/j.ica.2019.119096",

language = "英语",

volume = "497",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis and characterization of a luminescent Ni(II)-compound based on tpt and m-H2bdc detecting picric acid and chromate anions in aqueous

AU - Li, Jinxue

AU - Zhuang, Xinrui

AU - Zhang, Nanxi

AU - Zhao, Liyan

AU - Yang, Qingfeng

AU - Zhang, Xiao

PY - 2019/11/1

Y1 - 2019/11/1

N2 - A new luminescent compound Ni4(tpt)4(m-bdc)4·H2O (1) (tpt = tris(4-pyridyl)triazine, m-H2bdc = m-benzenedicarboxylic acid) was successfully synthesized by hydrothermal method, and characterized using single-crystal X-ray diffraction, PXRD, TG analysis and IR. 1 possesses a four-connected three-dimensional (3D) topological network with the Schläfli symbols of {65⋅8}. 1 not only has excellent thermal and chemical stability, but also is a dual-functional luminescent sensor with high selectivity and sensitivity for detection of picric acid (PA) and chromate (CrO42−) anions in water via the luminescent quenching. And the sensing mechanism for the quenching process was discussed in detail. Moreover, 1 can be regenerated by a fast and simple method in detecting PA and CrO42−, showing excellent recyclability after the sensing experiment.

AB - A new luminescent compound Ni4(tpt)4(m-bdc)4·H2O (1) (tpt = tris(4-pyridyl)triazine, m-H2bdc = m-benzenedicarboxylic acid) was successfully synthesized by hydrothermal method, and characterized using single-crystal X-ray diffraction, PXRD, TG analysis and IR. 1 possesses a four-connected three-dimensional (3D) topological network with the Schläfli symbols of {65⋅8}. 1 not only has excellent thermal and chemical stability, but also is a dual-functional luminescent sensor with high selectivity and sensitivity for detection of picric acid (PA) and chromate (CrO42−) anions in water via the luminescent quenching. And the sensing mechanism for the quenching process was discussed in detail. Moreover, 1 can be regenerated by a fast and simple method in detecting PA and CrO42−, showing excellent recyclability after the sensing experiment.

KW - Chromate (CrO) anions

KW - Dual-functional luminescent sensor

KW - Hydrothermal synthesis

KW - Metal organic framework

KW - Nitroaromatic compounds

UR - https://www.scopus.com/pages/publications/85071643718

U2 - 10.1016/j.ica.2019.119096

DO - 10.1016/j.ica.2019.119096

M3 - 文章

AN - SCOPUS:85071643718

SN - 0020-1693

VL - 497

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

M1 - 119096

ER -

Synthesis and characterization of a luminescent Ni(II)-compound based on tpt and m-H₂bdc detecting picric acid and chromate anions in aqueous

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Keywords

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