Syntheses, crystal structures, third-order nonlinear optical properties and thermal properties of two infinite (6, 3) net complexes

Wan Zhou; Xiangru Meng; Yanan Ding; Weiqiang Li; Hongwei Hou; Yinglin Song; Yaoting Fan

doi:10.1016/j.molstruc.2009.08.022

Syntheses, crystal structures, third-order nonlinear optical properties and thermal properties of two infinite (6, 3) net complexes

Wan Zhou
, Xiangru Meng
, Yanan Ding
, Weiqiang Li
, Hongwei Hou^*
, Yinglin Song
, Yaoting Fan

^*Corresponding author for this work

Zhengzhou University
Soochow University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Two new complexes {[Co(bbbm)_1.5(NO₃)₂]·H₂O}_n (1) and [Cd(bbbm)_1.5(NO₃)₂]_n (2) (bbbm = 1,1'-(1,4-butanediyl)bis-1H-benzimidazole) have been synthesized and structurally characterized. Both complexes are built up by two-dimensional coordination networks with (6, 3) nets. The third-order nonlinear optical (NLO) properties of the two complexes are determined and the results show that they not only possess large third-order NLO absorptive effects, but also display strong refractive behaviors. The hyperpolarizability |γ| values are 2.2 × 10^-29 esu for complex 1, and 1.6 × 10^-30 esu for complex 2. The NLO effective of complex 1 is stronger than that of 2 due to the decreased π back-donation capacity from Co(II) to Cd(II). Thermal analysis studies show that complex 1 is less stable and begins to decompose at 131 °C. While complex 2 is stable up to 257 °C.

Original language	English
Pages (from-to)	100-106
Number of pages	7
Journal	Journal of Molecular Structure
Volume	937
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2009.08.022
State	Published - 26 Nov 2009
Externally published	Yes

Keywords

Complex
Crystal structure
NLO property
Thermal analysis

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10.1016/j.molstruc.2009.08.022

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@article{ce1a0be323144b91901a2190379856c9,

title = "Syntheses, crystal structures, third-order nonlinear optical properties and thermal properties of two infinite (6, 3) net complexes",

abstract = "Two new complexes \{[Co(bbbm)1.5(NO3)2]·H2O\}n (1) and [Cd(bbbm)1.5(NO3)2]n (2) (bbbm = 1,1'-(1,4-butanediyl)bis-1H-benzimidazole) have been synthesized and structurally characterized. Both complexes are built up by two-dimensional coordination networks with (6, 3) nets. The third-order nonlinear optical (NLO) properties of the two complexes are determined and the results show that they not only possess large third-order NLO absorptive effects, but also display strong refractive behaviors. The hyperpolarizability |γ| values are 2.2 × 10-29 esu for complex 1, and 1.6 × 10-30 esu for complex 2. The NLO effective of complex 1 is stronger than that of 2 due to the decreased π back-donation capacity from Co(II) to Cd(II). Thermal analysis studies show that complex 1 is less stable and begins to decompose at 131 °C. While complex 2 is stable up to 257 °C.",

keywords = "Complex, Crystal structure, NLO property, Thermal analysis",

author = "Wan Zhou and Xiangru Meng and Yanan Ding and Weiqiang Li and Hongwei Hou and Yinglin Song and Yaoting Fan",

year = "2009",

month = nov,

day = "26",

doi = "10.1016/j.molstruc.2009.08.022",

language = "英语",

volume = "937",

pages = "100--106",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Syntheses, crystal structures, third-order nonlinear optical properties and thermal properties of two infinite (6, 3) net complexes

AU - Zhou, Wan

AU - Meng, Xiangru

AU - Ding, Yanan

AU - Li, Weiqiang

AU - Hou, Hongwei

AU - Song, Yinglin

AU - Fan, Yaoting

PY - 2009/11/26

Y1 - 2009/11/26

N2 - Two new complexes {[Co(bbbm)1.5(NO3)2]·H2O}n (1) and [Cd(bbbm)1.5(NO3)2]n (2) (bbbm = 1,1'-(1,4-butanediyl)bis-1H-benzimidazole) have been synthesized and structurally characterized. Both complexes are built up by two-dimensional coordination networks with (6, 3) nets. The third-order nonlinear optical (NLO) properties of the two complexes are determined and the results show that they not only possess large third-order NLO absorptive effects, but also display strong refractive behaviors. The hyperpolarizability |γ| values are 2.2 × 10-29 esu for complex 1, and 1.6 × 10-30 esu for complex 2. The NLO effective of complex 1 is stronger than that of 2 due to the decreased π back-donation capacity from Co(II) to Cd(II). Thermal analysis studies show that complex 1 is less stable and begins to decompose at 131 °C. While complex 2 is stable up to 257 °C.

AB - Two new complexes {[Co(bbbm)1.5(NO3)2]·H2O}n (1) and [Cd(bbbm)1.5(NO3)2]n (2) (bbbm = 1,1'-(1,4-butanediyl)bis-1H-benzimidazole) have been synthesized and structurally characterized. Both complexes are built up by two-dimensional coordination networks with (6, 3) nets. The third-order nonlinear optical (NLO) properties of the two complexes are determined and the results show that they not only possess large third-order NLO absorptive effects, but also display strong refractive behaviors. The hyperpolarizability |γ| values are 2.2 × 10-29 esu for complex 1, and 1.6 × 10-30 esu for complex 2. The NLO effective of complex 1 is stronger than that of 2 due to the decreased π back-donation capacity from Co(II) to Cd(II). Thermal analysis studies show that complex 1 is less stable and begins to decompose at 131 °C. While complex 2 is stable up to 257 °C.

KW - Complex

KW - Crystal structure

KW - NLO property

KW - Thermal analysis

UR - https://www.scopus.com/pages/publications/70349786512

U2 - 10.1016/j.molstruc.2009.08.022

DO - 10.1016/j.molstruc.2009.08.022

M3 - 文章

AN - SCOPUS:70349786512

SN - 0022-2860

VL - 937

SP - 100

EP - 106

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Syntheses, crystal structures, third-order nonlinear optical properties and thermal properties of two infinite (6, 3) net complexes

Abstract

Keywords

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