Syntheses and properties of the PET-co-PEA copolyester

Lipeng Wang; Yu Wang; Fuchen Zhang; Yongping Bai; Liping Ding

doi:10.1002/app.44967

Syntheses and properties of the PET-co-PEA copolyester

Lipeng Wang
, Yu Wang
, Fuchen Zhang
, Yongping Bai^*
, Liping Ding

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Nantong University

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

An aliphatic-aromatic random-block copolyester of poly(ethylene terephthalate) (PET), and poly(enthylene adipate) (PEA), PET-co-PEA, was synthesized via melt polycondensation. The chemical structure of the products were characterized by two kinds of spectroscopic techniques (Fourier transform infrared and ¹H-NMR). The thermal properties of the copolyester were characterized by thermogravimetry analysis, differential scanning calorimetry, wide-angle X-ray diffraction, and polarized optical microscopy. It was found that the crystallization ability, melting point, glass transition temperature of the random-block coplyester decreased apparently. Meanwhile, the tensile strength and hydrolysis performance were measured as well. The result showed that the random-block copolyesters PET-co-PEA displayed excellent properties in elasticity and strength. In addition, the potential degradability was found in hydrolysis measurement.

Original language	English
Article number	44967
Journal	Journal of Applied Polymer Science
Volume	134
Issue number	36
DOIs	https://doi.org/10.1002/app.44967
State	Published - 20 Sep 2017
Externally published	Yes

Keywords

degradability
elasticity and properties
random-block copolyester

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10.1002/app.44967

Cite this

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title = "Syntheses and properties of the PET-co-PEA copolyester",

abstract = "An aliphatic-aromatic random-block copolyester of poly(ethylene terephthalate) (PET), and poly(enthylene adipate) (PEA), PET-co-PEA, was synthesized via melt polycondensation. The chemical structure of the products were characterized by two kinds of spectroscopic techniques (Fourier transform infrared and 1H-NMR). The thermal properties of the copolyester were characterized by thermogravimetry analysis, differential scanning calorimetry, wide-angle X-ray diffraction, and polarized optical microscopy. It was found that the crystallization ability, melting point, glass transition temperature of the random-block coplyester decreased apparently. Meanwhile, the tensile strength and hydrolysis performance were measured as well. The result showed that the random-block copolyesters PET-co-PEA displayed excellent properties in elasticity and strength. In addition, the potential degradability was found in hydrolysis measurement.",

keywords = "degradability, elasticity and properties, random-block copolyester",

author = "Lipeng Wang and Yu Wang and Fuchen Zhang and Yongping Bai and Liping Ding",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley Periodicals, Inc.",

year = "2017",

month = sep,

day = "20",

doi = "10.1002/app.44967",

language = "英语",

volume = "134",

journal = "Journal of Applied Polymer Science",

issn = "0021-8995",

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T1 - Syntheses and properties of the PET-co-PEA copolyester

AU - Wang, Lipeng

AU - Wang, Yu

AU - Zhang, Fuchen

AU - Bai, Yongping

AU - Ding, Liping

PY - 2017/9/20

Y1 - 2017/9/20

N2 - An aliphatic-aromatic random-block copolyester of poly(ethylene terephthalate) (PET), and poly(enthylene adipate) (PEA), PET-co-PEA, was synthesized via melt polycondensation. The chemical structure of the products were characterized by two kinds of spectroscopic techniques (Fourier transform infrared and 1H-NMR). The thermal properties of the copolyester were characterized by thermogravimetry analysis, differential scanning calorimetry, wide-angle X-ray diffraction, and polarized optical microscopy. It was found that the crystallization ability, melting point, glass transition temperature of the random-block coplyester decreased apparently. Meanwhile, the tensile strength and hydrolysis performance were measured as well. The result showed that the random-block copolyesters PET-co-PEA displayed excellent properties in elasticity and strength. In addition, the potential degradability was found in hydrolysis measurement.

AB - An aliphatic-aromatic random-block copolyester of poly(ethylene terephthalate) (PET), and poly(enthylene adipate) (PEA), PET-co-PEA, was synthesized via melt polycondensation. The chemical structure of the products were characterized by two kinds of spectroscopic techniques (Fourier transform infrared and 1H-NMR). The thermal properties of the copolyester were characterized by thermogravimetry analysis, differential scanning calorimetry, wide-angle X-ray diffraction, and polarized optical microscopy. It was found that the crystallization ability, melting point, glass transition temperature of the random-block coplyester decreased apparently. Meanwhile, the tensile strength and hydrolysis performance were measured as well. The result showed that the random-block copolyesters PET-co-PEA displayed excellent properties in elasticity and strength. In addition, the potential degradability was found in hydrolysis measurement.

KW - degradability

KW - elasticity and properties

KW - random-block copolyester

UR - https://www.scopus.com/pages/publications/85020894467

U2 - 10.1002/app.44967

DO - 10.1002/app.44967

M3 - 文章

AN - SCOPUS:85020894467

SN - 0021-8995

VL - 134

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 36

M1 - 44967

ER -

Syntheses and properties of the PET-co-PEA copolyester

Abstract

Keywords

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