Syntheses and characterization of ferrocenylthiocarboxylate-containing coordination compounds for nonlinear optics

Haiyan Yang; Linke Li; Yinglin Song; Hongwei Hou; Yaoting Fan

doi:10.1016/j.jorganchem.2008.05.017

Syntheses and characterization of ferrocenylthiocarboxylate-containing coordination compounds for nonlinear optics

Haiyan Yang
, Linke Li
, Yinglin Song
, Hongwei Hou^*
, Yaoting Fan

^*Corresponding author for this work

Zhengzhou University
Soochow University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Four metal-organic coordination compounds containing ferrocenylthiocarboxylate components, [Cd₂(η²-SOCFc)₂(η¹-μ₂-SOCFc)₂(4,4′-bpy)]_n (1), [Cd(SOCFc)₂(tmp)]_n (tmp = 4,4′-trimethylene-dipyridine) (2) [Zn(SOCFc)₂(2,2′-bpy)] (3), and {[Hg(SOCFc)₂(phen)] · (0.5CH₃OH)} (4) (Fc = (η⁵-C₅H₅)Fe(η⁵-C₅H₄)), have been prepared in search of good nonlinear optical (NLO) materials. Investigation of the NLO properties shows that Hg-containing compound 4 exhibits very strong third-order NLO absorptive and refractive effects. The NLO absorptive coefficient α₂ value (2.11 × 10^-10 m W^-1) is larger than those of all the reported ferrocenylcarboxylate-containing coordination compounds and comparable to the well-performing Hg-containing complexes. Additionally, we further analyzed their NLO behaviors through studying electrochemical properties of the four compounds.

Original language	English
Pages (from-to)	2624-2630
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	15
DOIs	https://doi.org/10.1016/j.jorganchem.2008.05.017
State	Published - 15 Jul 2008
Externally published	Yes

Keywords

Coordination compounds
Electrochemical properties
Ferrocenylthiocarboxylate
Nonlinear optical properties

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10.1016/j.jorganchem.2008.05.017

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@article{226512f9fee34c9dbabb3421beef41e4,

title = "Syntheses and characterization of ferrocenylthiocarboxylate-containing coordination compounds for nonlinear optics",

abstract = "Four metal-organic coordination compounds containing ferrocenylthiocarboxylate components, [Cd2(η2-SOCFc)2(η1-μ2-SOCFc)2(4,4′-bpy)]n (1), [Cd(SOCFc)2(tmp)]n (tmp = 4,4′-trimethylene-dipyridine) (2) [Zn(SOCFc)2(2,2′-bpy)] (3), and \{[Hg(SOCFc)2(phen)] · (0.5CH3OH)\} (4) (Fc = (η5-C5H5)Fe(η5-C5H4)), have been prepared in search of good nonlinear optical (NLO) materials. Investigation of the NLO properties shows that Hg-containing compound 4 exhibits very strong third-order NLO absorptive and refractive effects. The NLO absorptive coefficient α2 value (2.11 × 10-10 m W-1) is larger than those of all the reported ferrocenylcarboxylate-containing coordination compounds and comparable to the well-performing Hg-containing complexes. Additionally, we further analyzed their NLO behaviors through studying electrochemical properties of the four compounds.",

keywords = "Coordination compounds, Electrochemical properties, Ferrocenylthiocarboxylate, Nonlinear optical properties",

author = "Haiyan Yang and Linke Li and Yinglin Song and Hongwei Hou and Yaoting Fan",

year = "2008",

month = jul,

day = "15",

doi = "10.1016/j.jorganchem.2008.05.017",

language = "英语",

volume = "693",

pages = "2624--2630",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Syntheses and characterization of ferrocenylthiocarboxylate-containing coordination compounds for nonlinear optics

AU - Yang, Haiyan

AU - Li, Linke

AU - Song, Yinglin

AU - Hou, Hongwei

AU - Fan, Yaoting

PY - 2008/7/15

Y1 - 2008/7/15

N2 - Four metal-organic coordination compounds containing ferrocenylthiocarboxylate components, [Cd2(η2-SOCFc)2(η1-μ2-SOCFc)2(4,4′-bpy)]n (1), [Cd(SOCFc)2(tmp)]n (tmp = 4,4′-trimethylene-dipyridine) (2) [Zn(SOCFc)2(2,2′-bpy)] (3), and {[Hg(SOCFc)2(phen)] · (0.5CH3OH)} (4) (Fc = (η5-C5H5)Fe(η5-C5H4)), have been prepared in search of good nonlinear optical (NLO) materials. Investigation of the NLO properties shows that Hg-containing compound 4 exhibits very strong third-order NLO absorptive and refractive effects. The NLO absorptive coefficient α2 value (2.11 × 10-10 m W-1) is larger than those of all the reported ferrocenylcarboxylate-containing coordination compounds and comparable to the well-performing Hg-containing complexes. Additionally, we further analyzed their NLO behaviors through studying electrochemical properties of the four compounds.

AB - Four metal-organic coordination compounds containing ferrocenylthiocarboxylate components, [Cd2(η2-SOCFc)2(η1-μ2-SOCFc)2(4,4′-bpy)]n (1), [Cd(SOCFc)2(tmp)]n (tmp = 4,4′-trimethylene-dipyridine) (2) [Zn(SOCFc)2(2,2′-bpy)] (3), and {[Hg(SOCFc)2(phen)] · (0.5CH3OH)} (4) (Fc = (η5-C5H5)Fe(η5-C5H4)), have been prepared in search of good nonlinear optical (NLO) materials. Investigation of the NLO properties shows that Hg-containing compound 4 exhibits very strong third-order NLO absorptive and refractive effects. The NLO absorptive coefficient α2 value (2.11 × 10-10 m W-1) is larger than those of all the reported ferrocenylcarboxylate-containing coordination compounds and comparable to the well-performing Hg-containing complexes. Additionally, we further analyzed their NLO behaviors through studying electrochemical properties of the four compounds.

KW - Coordination compounds

KW - Electrochemical properties

KW - Ferrocenylthiocarboxylate

KW - Nonlinear optical properties

UR - https://www.scopus.com/pages/publications/45849114722

U2 - 10.1016/j.jorganchem.2008.05.017

DO - 10.1016/j.jorganchem.2008.05.017

M3 - 文章

AN - SCOPUS:45849114722

SN - 0022-328X

VL - 693

SP - 2624

EP - 2630

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 15

ER -

Syntheses and characterization of ferrocenylthiocarboxylate-containing coordination compounds for nonlinear optics

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Keywords

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