Switching slow relaxation in a MnIII3MnIV cluster: An example of grafting single-molecule magnets onto polyoxometalates

Xikui Fang; Manfred Speldrich; Helmut Schilder; Rui Cao; Kevin P. O'Halloran; Craig L. Hill; Paul Kögerler

doi:10.1039/b925947c

Switching slow relaxation in a Mn^III₃Mn^IV cluster: An example of grafting single-molecule magnets onto polyoxometalates

Xikui Fang^*
, Manfred Speldrich
, Helmut Schilder
, Rui Cao
, Kevin P. O'Halloran
, Craig L. Hill
, Paul Kögerler

^*Corresponding author for this work

Ames Laboratory
RWTH Aachen University
Emory University

Research output: Contribution to journal › Article › peer-review

92 Scopus citations

Abstract

Binding an established single-molecule magnet cluster of distorted cubane type [Mn^III₃Mn^IVO₄] to the lacunary site of an {α-P₂W₁₅} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.

Original language	English
Pages (from-to)	2760-2762
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	16
DOIs	https://doi.org/10.1039/b925947c
State	Published - 2010
Externally published	Yes

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title = "Switching slow relaxation in a MnIII3MnIV cluster: An example of grafting single-molecule magnets onto polyoxometalates",

abstract = "Binding an established single-molecule magnet cluster of distorted cubane type [MnIII3MnIVO4] to the lacunary site of an \{α-P2W15\} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.",

author = "Xikui Fang and Manfred Speldrich and Helmut Schilder and Rui Cao and O'Halloran, \{Kevin P.\} and Hill, \{Craig L.\} and Paul K{\"o}gerler",

year = "2010",

doi = "10.1039/b925947c",

language = "英语",

volume = "46",

pages = "2760--2762",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T2 - An example of grafting single-molecule magnets onto polyoxometalates

AU - Fang, Xikui

AU - Speldrich, Manfred

AU - Schilder, Helmut

AU - Cao, Rui

AU - O'Halloran, Kevin P.

AU - Hill, Craig L.

AU - Kögerler, Paul

PY - 2010

Y1 - 2010

N2 - Binding an established single-molecule magnet cluster of distorted cubane type [MnIII3MnIVO4] to the lacunary site of an {α-P2W15} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.

AB - Binding an established single-molecule magnet cluster of distorted cubane type [MnIII3MnIVO4] to the lacunary site of an {α-P2W15} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.

UR - https://www.scopus.com/pages/publications/77950505816

U2 - 10.1039/b925947c

DO - 10.1039/b925947c

M3 - 文章

AN - SCOPUS:77950505816

SN - 1359-7345

VL - 46

SP - 2760

EP - 2762

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Switching slow relaxation in a Mn^III₃Mn^IV cluster: An example of grafting single-molecule magnets onto polyoxometalates

Abstract

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