Surface modification of polymeric materials by plasma immersion ion implantation

Ricky K.Y. Fu; I. T.L. Cheung; Y. F. Mei; C. H. Shek; G. G. Siu; Paul K. Chu; W. M. Yang; Y. X. Leng; Y. X. Huang; X. B. Tian; S. Q. Yang

doi:10.1016/j.nimb.2005.05.029

Surface modification of polymeric materials by plasma immersion ion implantation

Ricky K.Y. Fu
, I. T.L. Cheung
, Y. F. Mei
, C. H. Shek
, G. G. Siu
, Paul K. Chu^*
, W. M. Yang
, Y. X. Leng
, Y. X. Huang
, X. B. Tian
, S. Q. Yang

^*Corresponding author for this work

School of Materials Science and Engineering

City University of Hong Kong
Southwest Jiaotong University
Harbin Institute of Technology

Research output: Contribution to journal › Conference article › peer-review

55 Scopus citations

Abstract

Polymer surfaces typically have low surface tension and high chemical inertness and so they usually have poor wetting and adhesion properties. The surface properties can be altered by modifying the molecular structure using plasma immersion ion implantation (PIII). In this work, Nylon-6 was treated using oxygen/nitrogen PIII. The observed improvement in the wettability is due to the oxygenated and nitrogen (amine) functional groups created on the polymer surface by the plasma treatment. X-ray photoelectron spectroscopy (XPS) results show that nitrogen and oxygen plasma implantation result in C-C bond breaking to form the imine and amine groups as well as alcohol and/or carbonyl groups on the surface. The water contact angle results reveal that the surface wetting properties depend on the functional groups, which can be adjusted by the ratio of oxygen-nitrogen mixtures.

Original language	English
Pages (from-to)	417-421
Number of pages	5
Journal	Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
Volume	237
Issue number	1-2
DOIs	https://doi.org/10.1016/j.nimb.2005.05.029
State	Published - Aug 2005
Event	Ion Implantation Technology Proceedings of the 15th International Conference on Ion Implantation Technology ITT 2004 - Duration: 25 Oct 2004 → 27 Oct 2004

Keywords

Functional groups
Ion implantation
Nylon-6
Wettability
X-ray photoelectron spectroscopy

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10.1016/j.nimb.2005.05.029

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Fu, R. K. Y., Cheung, I. T. L., Mei, Y. F., Shek, C. H., Siu, G. G., Chu, P. K., Yang, W. M., Leng, Y. X., Huang, Y. X., Tian, X. B., & Yang, S. Q. (2005). Surface modification of polymeric materials by plasma immersion ion implantation. Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, 237(1-2), 417-421. https://doi.org/10.1016/j.nimb.2005.05.029

@article{6fa8532e36a14912bd0f1c41bc2c2aad,

title = "Surface modification of polymeric materials by plasma immersion ion implantation",

abstract = "Polymer surfaces typically have low surface tension and high chemical inertness and so they usually have poor wetting and adhesion properties. The surface properties can be altered by modifying the molecular structure using plasma immersion ion implantation (PIII). In this work, Nylon-6 was treated using oxygen/nitrogen PIII. The observed improvement in the wettability is due to the oxygenated and nitrogen (amine) functional groups created on the polymer surface by the plasma treatment. X-ray photoelectron spectroscopy (XPS) results show that nitrogen and oxygen plasma implantation result in C-C bond breaking to form the imine and amine groups as well as alcohol and/or carbonyl groups on the surface. The water contact angle results reveal that the surface wetting properties depend on the functional groups, which can be adjusted by the ratio of oxygen-nitrogen mixtures.",

keywords = "Functional groups, Ion implantation, Nylon-6, Wettability, X-ray photoelectron spectroscopy",

author = "Fu, \{Ricky K.Y.\} and Cheung, \{I. T.L.\} and Mei, \{Y. F.\} and Shek, \{C. H.\} and Siu, \{G. G.\} and Chu, \{Paul K.\} and Yang, \{W. M.\} and Leng, \{Y. X.\} and Huang, \{Y. X.\} and Tian, \{X. B.\} and Yang, \{S. Q.\}",

year = "2005",

month = aug,

doi = "10.1016/j.nimb.2005.05.029",

language = "英语",

volume = "237",

pages = "417--421",

journal = "Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms",

issn = "0168-583X",

publisher = "Elsevier B.V.",

number = "1-2",

note = "Ion Implantation Technology Proceedings of the 15th International Conference on Ion Implantation Technology ITT 2004 ; Conference date: 25-10-2004 Through 27-10-2004",

}

Fu, RKY, Cheung, ITL, Mei, YF, Shek, CH, Siu, GG, Chu, PK, Yang, WM, Leng, YX, Huang, YX , Tian, XB & Yang, SQ 2005, 'Surface modification of polymeric materials by plasma immersion ion implantation', Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, vol. 237, no. 1-2, pp. 417-421. https://doi.org/10.1016/j.nimb.2005.05.029

TY - JOUR

T1 - Surface modification of polymeric materials by plasma immersion ion implantation

AU - Fu, Ricky K.Y.

AU - Cheung, I. T.L.

AU - Mei, Y. F.

AU - Shek, C. H.

AU - Siu, G. G.

AU - Chu, Paul K.

AU - Yang, W. M.

AU - Leng, Y. X.

AU - Huang, Y. X.

AU - Tian, X. B.

AU - Yang, S. Q.

PY - 2005/8

Y1 - 2005/8

N2 - Polymer surfaces typically have low surface tension and high chemical inertness and so they usually have poor wetting and adhesion properties. The surface properties can be altered by modifying the molecular structure using plasma immersion ion implantation (PIII). In this work, Nylon-6 was treated using oxygen/nitrogen PIII. The observed improvement in the wettability is due to the oxygenated and nitrogen (amine) functional groups created on the polymer surface by the plasma treatment. X-ray photoelectron spectroscopy (XPS) results show that nitrogen and oxygen plasma implantation result in C-C bond breaking to form the imine and amine groups as well as alcohol and/or carbonyl groups on the surface. The water contact angle results reveal that the surface wetting properties depend on the functional groups, which can be adjusted by the ratio of oxygen-nitrogen mixtures.

AB - Polymer surfaces typically have low surface tension and high chemical inertness and so they usually have poor wetting and adhesion properties. The surface properties can be altered by modifying the molecular structure using plasma immersion ion implantation (PIII). In this work, Nylon-6 was treated using oxygen/nitrogen PIII. The observed improvement in the wettability is due to the oxygenated and nitrogen (amine) functional groups created on the polymer surface by the plasma treatment. X-ray photoelectron spectroscopy (XPS) results show that nitrogen and oxygen plasma implantation result in C-C bond breaking to form the imine and amine groups as well as alcohol and/or carbonyl groups on the surface. The water contact angle results reveal that the surface wetting properties depend on the functional groups, which can be adjusted by the ratio of oxygen-nitrogen mixtures.

KW - Functional groups

KW - Ion implantation

KW - Nylon-6

KW - Wettability

KW - X-ray photoelectron spectroscopy

UR - https://www.scopus.com/pages/publications/23444445210

U2 - 10.1016/j.nimb.2005.05.029

DO - 10.1016/j.nimb.2005.05.029

M3 - 会议文章

AN - SCOPUS:23444445210

SN - 0168-583X

VL - 237

SP - 417

EP - 421

JO - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

JF - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

IS - 1-2

T2 - Ion Implantation Technology Proceedings of the 15th International Conference on Ion Implantation Technology ITT 2004

Y2 - 25 October 2004 through 27 October 2004

ER -

Surface modification of polymeric materials by plasma immersion ion implantation

Abstract

Keywords

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