Surface confined synthesis of porphyrin containing two-dimensional polymers: The effect of rigidity and preferential adsorption of building blocks

Xiuling Sun; Lixia Fan; Xin Zhou; Wei Quan Tian; Zongxia Guo; Zhibo Li; Xiaokang Li; Shengbin Lei

doi:10.1039/c5cc00659g

Surface confined synthesis of porphyrin containing two-dimensional polymers: The effect of rigidity and preferential adsorption of building blocks

Xiuling Sun
, Lixia Fan
, Xin Zhou^*
, Wei Quan Tian
, Zongxia Guo
, Zhibo Li
, Xiaokang Li
, Shengbin Lei

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

We have designed and synthesized two porphyrin containing two-dimensional (2D) polymers based on the imine linkage. Both the 2D polymers are revealed to be 2D organic semiconductors with band gaps of around 1 eV. STM characterization reveals that the rigidity and affinity of building blocks to the surface has essential effects on the topology of the 2D polymers.

Original language	English
Pages (from-to)	5864-5867
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	27
DOIs	https://doi.org/10.1039/c5cc00659g
State	Published - 7 Apr 2015

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10.1039/c5cc00659g

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title = "Surface confined synthesis of porphyrin containing two-dimensional polymers: The effect of rigidity and preferential adsorption of building blocks",

abstract = "We have designed and synthesized two porphyrin containing two-dimensional (2D) polymers based on the imine linkage. Both the 2D polymers are revealed to be 2D organic semiconductors with band gaps of around 1 eV. STM characterization reveals that the rigidity and affinity of building blocks to the surface has essential effects on the topology of the 2D polymers.",

author = "Xiuling Sun and Lixia Fan and Xin Zhou and Tian, \{Wei Quan\} and Zongxia Guo and Zhibo Li and Xiaokang Li and Shengbin Lei",

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T1 - Surface confined synthesis of porphyrin containing two-dimensional polymers

T2 - The effect of rigidity and preferential adsorption of building blocks

AU - Sun, Xiuling

AU - Fan, Lixia

AU - Zhou, Xin

AU - Tian, Wei Quan

AU - Guo, Zongxia

AU - Li, Zhibo

AU - Li, Xiaokang

AU - Lei, Shengbin

PY - 2015/4/7

Y1 - 2015/4/7

N2 - We have designed and synthesized two porphyrin containing two-dimensional (2D) polymers based on the imine linkage. Both the 2D polymers are revealed to be 2D organic semiconductors with band gaps of around 1 eV. STM characterization reveals that the rigidity and affinity of building blocks to the surface has essential effects on the topology of the 2D polymers.

AB - We have designed and synthesized two porphyrin containing two-dimensional (2D) polymers based on the imine linkage. Both the 2D polymers are revealed to be 2D organic semiconductors with band gaps of around 1 eV. STM characterization reveals that the rigidity and affinity of building blocks to the surface has essential effects on the topology of the 2D polymers.

UR - https://www.scopus.com/pages/publications/84925353390

U2 - 10.1039/c5cc00659g

DO - 10.1039/c5cc00659g

M3 - 文章

AN - SCOPUS:84925353390

SN - 1359-7345

VL - 51

SP - 5864

EP - 5867

JO - Chemical Communications

JF - Chemical Communications

IS - 27

ER -

Surface confined synthesis of porphyrin containing two-dimensional polymers: The effect of rigidity and preferential adsorption of building blocks

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