Superior energy storage properties of (1-x)Ba0.85Ca0.15Zr0.1Ti0.9O3-xBi(Mg2/3Ta1/3)O3 lead-free ceramics

Dandan Han; Bin Zhang; Deqiang Zhao; Jianwei Zhao; Yuhang Liu; Shunri Zheng; Li Fan; Changhao Wang; Dawei Wang; Fanling Meng

doi:10.1016/j.jallcom.2023.169300

Superior energy storage properties of (1-x)Ba_0.85Ca_0.15Zr_0.1Ti_0.9O₃-xBi(Mg_2/3Ta_1/3)O₃ lead-free ceramics

Dandan Han
, Bin Zhang
, Deqiang Zhao
, Jianwei Zhao
, Yuhang Liu
, Shunri Zheng
, Li Fan
, Changhao Wang^*
, Dawei Wang^*
, Fanling Meng

^*Corresponding author for this work

Jilin University
Jilin Institute of Chemical Technology
Shenzhen Institute of Advanced Technology
Chongqing Jiaotong University
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

In this work, lead-free (1-x)Ba_0.85Ca_0.15Zr_0.1Ti_0.9O₃-xBi(Mg_2/3Ta_1/3)O₃ (BCZT-BMTx) relaxor ferroelectrics (RFEs) were prepared via a traditional solid-state reaction. BMT was introduced into ferroelectric (FE) BCZT ceramics by a strategy of composition modification, which remarkably inhibited the grain growth and triggered a FE-to-RFE phase transition. The breakdown strength (E_b) of BCZT ceramics was greatly improved by enhancing the band gap with Ta₂O₅ (∼4 eV) doping into B-site. BCZT-BMT8 ceramic possesses both high energy efficiency (η) of 93.87% and recoverable energy density (W_rec) of 3.4 J/cm³ at a relatively high E_b of 440 kV/cm, which are superior to most of other BaTiO₃-based energy storage ceramics. Especially, excellent energy storage stability with respect to frequency (2–500 Hz, a variation of W_rec<4.27% and η < 2.65%) and temperature (30–130 °C, W_rec<13.5% and η < 2.4%) was obtained for BCZT-BMT8 ceramic. In brief, the enhanced W_rec and E_b with significantly high η indicated that BCZT-BMT8 ceramic is a promising candidate for energy storage capacitors.

Original language	English
Article number	169300
Journal	Journal of Alloys and Compounds
Volume	946
DOIs	https://doi.org/10.1016/j.jallcom.2023.169300
State	Published - 15 Jun 2023
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

BaTiO-based
Capacitors
Energy storage
Relaxor ferroelectric

Access to Document

10.1016/j.jallcom.2023.169300

Cite this

@article{b6e9e09c12c3434daf7ad0b0d7ace88d,

title = "Superior energy storage properties of (1-x)Ba0.85Ca0.15Zr0.1Ti0.9O3-xBi(Mg2/3Ta1/3)O3 lead-free ceramics",

abstract = "In this work, lead-free (1-x)Ba0.85Ca0.15Zr0.1Ti0.9O3-xBi(Mg2/3Ta1/3)O3 (BCZT-BMTx) relaxor ferroelectrics (RFEs) were prepared via a traditional solid-state reaction. BMT was introduced into ferroelectric (FE) BCZT ceramics by a strategy of composition modification, which remarkably inhibited the grain growth and triggered a FE-to-RFE phase transition. The breakdown strength (Eb) of BCZT ceramics was greatly improved by enhancing the band gap with Ta2O5 (∼4 eV) doping into B-site. BCZT-BMT8 ceramic possesses both high energy efficiency (η) of 93.87\% and recoverable energy density (Wrec) of 3.4 J/cm3 at a relatively high Eb of 440 kV/cm, which are superior to most of other BaTiO3-based energy storage ceramics. Especially, excellent energy storage stability with respect to frequency (2–500 Hz, a variation of Wrec<4.27\% and η < 2.65\%) and temperature (30–130 °C, Wrec<13.5\% and η < 2.4\%) was obtained for BCZT-BMT8 ceramic. In brief, the enhanced Wrec and Eb with significantly high η indicated that BCZT-BMT8 ceramic is a promising candidate for energy storage capacitors.",

keywords = "BaTiO-based, Capacitors, Energy storage, Relaxor ferroelectric",

author = "Dandan Han and Bin Zhang and Deqiang Zhao and Jianwei Zhao and Yuhang Liu and Shunri Zheng and Li Fan and Changhao Wang and Dawei Wang and Fanling Meng",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier B.V.",

year = "2023",

month = jun,

day = "15",

doi = "10.1016/j.jallcom.2023.169300",

language = "英语",

volume = "946",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Superior energy storage properties of (1-x)Ba0.85Ca0.15Zr0.1Ti0.9O3-xBi(Mg2/3Ta1/3)O3 lead-free ceramics

AU - Han, Dandan

AU - Zhang, Bin

AU - Zhao, Deqiang

AU - Zhao, Jianwei

AU - Liu, Yuhang

AU - Zheng, Shunri

AU - Fan, Li

AU - Wang, Changhao

AU - Wang, Dawei

AU - Meng, Fanling

PY - 2023/6/15

Y1 - 2023/6/15

N2 - In this work, lead-free (1-x)Ba0.85Ca0.15Zr0.1Ti0.9O3-xBi(Mg2/3Ta1/3)O3 (BCZT-BMTx) relaxor ferroelectrics (RFEs) were prepared via a traditional solid-state reaction. BMT was introduced into ferroelectric (FE) BCZT ceramics by a strategy of composition modification, which remarkably inhibited the grain growth and triggered a FE-to-RFE phase transition. The breakdown strength (Eb) of BCZT ceramics was greatly improved by enhancing the band gap with Ta2O5 (∼4 eV) doping into B-site. BCZT-BMT8 ceramic possesses both high energy efficiency (η) of 93.87% and recoverable energy density (Wrec) of 3.4 J/cm3 at a relatively high Eb of 440 kV/cm, which are superior to most of other BaTiO3-based energy storage ceramics. Especially, excellent energy storage stability with respect to frequency (2–500 Hz, a variation of Wrec<4.27% and η < 2.65%) and temperature (30–130 °C, Wrec<13.5% and η < 2.4%) was obtained for BCZT-BMT8 ceramic. In brief, the enhanced Wrec and Eb with significantly high η indicated that BCZT-BMT8 ceramic is a promising candidate for energy storage capacitors.

AB - In this work, lead-free (1-x)Ba0.85Ca0.15Zr0.1Ti0.9O3-xBi(Mg2/3Ta1/3)O3 (BCZT-BMTx) relaxor ferroelectrics (RFEs) were prepared via a traditional solid-state reaction. BMT was introduced into ferroelectric (FE) BCZT ceramics by a strategy of composition modification, which remarkably inhibited the grain growth and triggered a FE-to-RFE phase transition. The breakdown strength (Eb) of BCZT ceramics was greatly improved by enhancing the band gap with Ta2O5 (∼4 eV) doping into B-site. BCZT-BMT8 ceramic possesses both high energy efficiency (η) of 93.87% and recoverable energy density (Wrec) of 3.4 J/cm3 at a relatively high Eb of 440 kV/cm, which are superior to most of other BaTiO3-based energy storage ceramics. Especially, excellent energy storage stability with respect to frequency (2–500 Hz, a variation of Wrec<4.27% and η < 2.65%) and temperature (30–130 °C, Wrec<13.5% and η < 2.4%) was obtained for BCZT-BMT8 ceramic. In brief, the enhanced Wrec and Eb with significantly high η indicated that BCZT-BMT8 ceramic is a promising candidate for energy storage capacitors.

KW - BaTiO-based

KW - Capacitors

KW - Energy storage

KW - Relaxor ferroelectric

UR - https://www.scopus.com/pages/publications/85148745776

U2 - 10.1016/j.jallcom.2023.169300

DO - 10.1016/j.jallcom.2023.169300

M3 - 文章

AN - SCOPUS:85148745776

SN - 0925-8388

VL - 946

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

M1 - 169300

ER -