Sulfated zirconia supported in mesoporous materials

Yinyong Sun; Lei Zhu; Huijuan Lu; Runwei Wang; Sen Lin; Dazheng Jiang; Feng Shou Xiao

doi:10.1016/S0926-860X(02)00133-3

Sulfated zirconia supported in mesoporous materials

Yinyong Sun
, Lei Zhu
, Huijuan Lu
, Runwei Wang
, Sen Lin
, Dazheng Jiang
, Feng Shou Xiao^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

77 Scopus citations

Abstract

SO₄^2-/ZrO₂ (SZ) supported on ordered mesoporous hexagonal materials were prepared by dispersion of ZrOCl₂·8H₂O into the mesopores, followed by the hydrolysis and sulfation. These materials have been characterized by X-ray diffraction, nitrogen adsorption isotherms, infrared spectroscopy, and catalytic cracking of n-hexane, cumene and 1,3,5-triisopropylbenzene. The results show that SZ was successfully loaded into the inner pores of MCM-41; the as-synthesized catalyst showed favorable catalytic properties. The factors in the preparative process that affected the final activity were discussed.

Original language	English
Pages (from-to)	21-31
Number of pages	11
Journal	Applied Catalysis A: General
Volume	237
Issue number	1-2
DOIs	https://doi.org/10.1016/S0926-860X(02)00133-3
State	Published - Nov 2002
Externally published	Yes

Keywords

1,3,5-triisopropylbenzene
Cracking
Cumene
Dispersion
MCM-41
Sulfated zirconia
n-Hexane

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10.1016/S0926-860X(02)00133-3

Cite this

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title = "Sulfated zirconia supported in mesoporous materials",

abstract = "SO42-/ZrO2 (SZ) supported on ordered mesoporous hexagonal materials were prepared by dispersion of ZrOCl2·8H2O into the mesopores, followed by the hydrolysis and sulfation. These materials have been characterized by X-ray diffraction, nitrogen adsorption isotherms, infrared spectroscopy, and catalytic cracking of n-hexane, cumene and 1,3,5-triisopropylbenzene. The results show that SZ was successfully loaded into the inner pores of MCM-41; the as-synthesized catalyst showed favorable catalytic properties. The factors in the preparative process that affected the final activity were discussed.",

keywords = "1,3,5-triisopropylbenzene, Cracking, Cumene, Dispersion, MCM-41, Sulfated zirconia, n-Hexane",

author = "Yinyong Sun and Lei Zhu and Huijuan Lu and Runwei Wang and Sen Lin and Dazheng Jiang and Xiao, \{Feng Shou\}",

year = "2002",

month = nov,

doi = "10.1016/S0926-860X(02)00133-3",

language = "英语",

volume = "237",

pages = "21--31",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Sulfated zirconia supported in mesoporous materials

AU - Sun, Yinyong

AU - Zhu, Lei

AU - Lu, Huijuan

AU - Wang, Runwei

AU - Lin, Sen

AU - Jiang, Dazheng

AU - Xiao, Feng Shou

PY - 2002/11

Y1 - 2002/11

N2 - SO42-/ZrO2 (SZ) supported on ordered mesoporous hexagonal materials were prepared by dispersion of ZrOCl2·8H2O into the mesopores, followed by the hydrolysis and sulfation. These materials have been characterized by X-ray diffraction, nitrogen adsorption isotherms, infrared spectroscopy, and catalytic cracking of n-hexane, cumene and 1,3,5-triisopropylbenzene. The results show that SZ was successfully loaded into the inner pores of MCM-41; the as-synthesized catalyst showed favorable catalytic properties. The factors in the preparative process that affected the final activity were discussed.

AB - SO42-/ZrO2 (SZ) supported on ordered mesoporous hexagonal materials were prepared by dispersion of ZrOCl2·8H2O into the mesopores, followed by the hydrolysis and sulfation. These materials have been characterized by X-ray diffraction, nitrogen adsorption isotherms, infrared spectroscopy, and catalytic cracking of n-hexane, cumene and 1,3,5-triisopropylbenzene. The results show that SZ was successfully loaded into the inner pores of MCM-41; the as-synthesized catalyst showed favorable catalytic properties. The factors in the preparative process that affected the final activity were discussed.

KW - 1,3,5-triisopropylbenzene

KW - Cracking

KW - Cumene

KW - Dispersion

KW - MCM-41

KW - Sulfated zirconia

KW - n-Hexane

UR - https://www.scopus.com/pages/publications/0036836726

U2 - 10.1016/S0926-860X(02)00133-3

DO - 10.1016/S0926-860X(02)00133-3

M3 - 文章

AN - SCOPUS:0036836726

SN - 0926-860X

VL - 237

SP - 21

EP - 31

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

IS - 1-2

ER -

Sulfated zirconia supported in mesoporous materials

Abstract

Keywords

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