Structure and nonlinear optical property of the cluster compound V 2S6O2Cu6(3-MePy)6

Guo Dong Tang; Jin Fang Zhang; Ying Lin Song; Chi Zhang; Lu De Lu

Structure and nonlinear optical property of the cluster compound V ₂S₆O₂Cu₆(3-MePy)₆

Guo Dong Tang^*
, Jin Fang Zhang
, Ying Lin Song
, Chi Zhang
, Lu De Lu

^*Corresponding author for this work

Huaiyin Normal University
Nanjing University of Science and Technology
Jiangsu University
Soochow University

Research output: Contribution to journal › Article › peer-review

Abstract

A cluster compound V₂S₆O₂Cu ₆(3-MePy)₆ (3-MePy = 3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-ray diffraction: space group P1, Z = 1, a = 9.7278(4), b = 10.4180(5), c = 11.9230(6) Å, a = 108.240(3), β = 98.120(2), y = 99.500(2)°, R = 0.052 and wR = 0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability (α₂ = 1.7 × 10^-10 m·W^-1) and effective self-focusing performance (n₂ = 1.27×10- ¹⁸ m²·W^-1) in a 1.58 × 10 ^-4 mol·dm^-3 DMF solution.

Original language	English
Pages (from-to)	921-927
Number of pages	7
Journal	Jiegou Huaxue
Volume	33
Issue number	6
State	Published - 15 Jun 2014
Externally published	Yes

Keywords

Crystal structure
Nonlinear optics
Vanadium cluster

Cite this

@article{ec7708ee25e4440b99c70d55b41a350e,

title = "Structure and nonlinear optical property of the cluster compound V 2S6O2Cu6(3-MePy)6",

abstract = "A cluster compound V2S6O2Cu 6(3-MePy)6 (3-MePy = 3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-ray diffraction: space group P1, Z = 1, a = 9.7278(4), b = 10.4180(5), c = 11.9230(6) {\AA}, a = 108.240(3), β = 98.120(2), y = 99.500(2)°, R = 0.052 and wR = 0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability (α2 = 1.7 × 10-10 m·W-1) and effective self-focusing performance (n2 = 1.27×10- 18 m2·W-1) in a 1.58 × 10 -4 mol·dm-3 DMF solution.",

keywords = "Crystal structure, Nonlinear optics, Vanadium cluster",

author = "Tang, \{Guo Dong\} and Zhang, \{Jin Fang\} and Song, \{Ying Lin\} and Chi Zhang and Lu, \{Lu De\}",

year = "2014",

month = jun,

day = "15",

language = "英语",

volume = "33",

pages = "921--927",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "6",

}

TY - JOUR

T1 - Structure and nonlinear optical property of the cluster compound V 2S6O2Cu6(3-MePy)6

AU - Tang, Guo Dong

AU - Zhang, Jin Fang

AU - Song, Ying Lin

AU - Zhang, Chi

AU - Lu, Lu De

PY - 2014/6/15

Y1 - 2014/6/15

N2 - A cluster compound V2S6O2Cu 6(3-MePy)6 (3-MePy = 3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-ray diffraction: space group P1, Z = 1, a = 9.7278(4), b = 10.4180(5), c = 11.9230(6) Å, a = 108.240(3), β = 98.120(2), y = 99.500(2)°, R = 0.052 and wR = 0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability (α2 = 1.7 × 10-10 m·W-1) and effective self-focusing performance (n2 = 1.27×10- 18 m2·W-1) in a 1.58 × 10 -4 mol·dm-3 DMF solution.

AB - A cluster compound V2S6O2Cu 6(3-MePy)6 (3-MePy = 3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-ray diffraction: space group P1, Z = 1, a = 9.7278(4), b = 10.4180(5), c = 11.9230(6) Å, a = 108.240(3), β = 98.120(2), y = 99.500(2)°, R = 0.052 and wR = 0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability (α2 = 1.7 × 10-10 m·W-1) and effective self-focusing performance (n2 = 1.27×10- 18 m2·W-1) in a 1.58 × 10 -4 mol·dm-3 DMF solution.

KW - Crystal structure

KW - Nonlinear optics

KW - Vanadium cluster

UR - https://www.scopus.com/pages/publications/84903793756

M3 - 文章

AN - SCOPUS:84903793756

SN - 0254-5861

VL - 33

SP - 921

EP - 927

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 6

ER -

Structure and nonlinear optical property of the cluster compound V ₂S₆O₂Cu₆(3-MePy)₆

Abstract

Keywords

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