Structure and characterization of DBSA doped PAN

Da Shu Yu; Nai Qing Zhang; Li Qun Wang; Li Jiang Hu

Structure and characterization of DBSA doped PAN

Da Shu Yu^*
, Nai Qing Zhang
, Li Qun Wang
, Li Jiang Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A conducting polyaniline (PANI) was prepared by emulsification through H₂O-toluene-dodecybenzene sulphonic acid (DBSA) system. Molar ratio of DBSA/AN(Aniline), (NH₄)₂S₂O₈/AN, and drop wise time of (NH₄)₂S₂O₈ were studied in this process. Considering the post-treatment and improving the emulsifying process, product yield was greatly raised and after-treatment procedure was simplified via the multiple emulsion technology. FTIR, XRD, XPS were used to identify the composition of final products, and the wave absorbing property for product was measured. The experimental results indicated that the product was doped very well by DBSA; the products had a part of crystallization phenomena and it presents thermal stability. PANI/DBSA showed good wave absorption with 9.31 dB, and the width of frequency band attenuation over 9 dB is about 1 GHz.

Original language	English
Pages (from-to)	615-618
Number of pages	4
Journal	Gongneng Cailiao/Journal of Functional Materials
Volume	37
Issue number	SUPPL.
State	Published - Sep 2006

Keywords

Absorbing properties
Microstructure characteristics
Polyaniline

Cite this

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title = "Structure and characterization of DBSA doped PAN",

abstract = "A conducting polyaniline (PANI) was prepared by emulsification through H2O-toluene-dodecybenzene sulphonic acid (DBSA) system. Molar ratio of DBSA/AN(Aniline), (NH4)2S2O8/AN, and drop wise time of (NH4)2S2O8 were studied in this process. Considering the post-treatment and improving the emulsifying process, product yield was greatly raised and after-treatment procedure was simplified via the multiple emulsion technology. FTIR, XRD, XPS were used to identify the composition of final products, and the wave absorbing property for product was measured. The experimental results indicated that the product was doped very well by DBSA; the products had a part of crystallization phenomena and it presents thermal stability. PANI/DBSA showed good wave absorption with 9.31 dB, and the width of frequency band attenuation over 9 dB is about 1 GHz.",

keywords = "Absorbing properties, Microstructure characteristics, Polyaniline",

author = "Yu, \{Da Shu\} and Zhang, \{Nai Qing\} and Wang, \{Li Qun\} and Hu, \{Li Jiang\}",

year = "2006",

month = sep,

language = "英语",

volume = "37",

pages = "615--618",

journal = "Gongneng Cailiao/Journal of Functional Materials",

issn = "1001-9731",

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}

TY - JOUR

T1 - Structure and characterization of DBSA doped PAN

AU - Yu, Da Shu

AU - Zhang, Nai Qing

AU - Wang, Li Qun

AU - Hu, Li Jiang

PY - 2006/9

Y1 - 2006/9

N2 - A conducting polyaniline (PANI) was prepared by emulsification through H2O-toluene-dodecybenzene sulphonic acid (DBSA) system. Molar ratio of DBSA/AN(Aniline), (NH4)2S2O8/AN, and drop wise time of (NH4)2S2O8 were studied in this process. Considering the post-treatment and improving the emulsifying process, product yield was greatly raised and after-treatment procedure was simplified via the multiple emulsion technology. FTIR, XRD, XPS were used to identify the composition of final products, and the wave absorbing property for product was measured. The experimental results indicated that the product was doped very well by DBSA; the products had a part of crystallization phenomena and it presents thermal stability. PANI/DBSA showed good wave absorption with 9.31 dB, and the width of frequency band attenuation over 9 dB is about 1 GHz.

AB - A conducting polyaniline (PANI) was prepared by emulsification through H2O-toluene-dodecybenzene sulphonic acid (DBSA) system. Molar ratio of DBSA/AN(Aniline), (NH4)2S2O8/AN, and drop wise time of (NH4)2S2O8 were studied in this process. Considering the post-treatment and improving the emulsifying process, product yield was greatly raised and after-treatment procedure was simplified via the multiple emulsion technology. FTIR, XRD, XPS were used to identify the composition of final products, and the wave absorbing property for product was measured. The experimental results indicated that the product was doped very well by DBSA; the products had a part of crystallization phenomena and it presents thermal stability. PANI/DBSA showed good wave absorption with 9.31 dB, and the width of frequency band attenuation over 9 dB is about 1 GHz.

KW - Absorbing properties

KW - Microstructure characteristics

KW - Polyaniline

UR - https://www.scopus.com/pages/publications/33751084620

M3 - 文章

AN - SCOPUS:33751084620

SN - 1001-9731

VL - 37

SP - 615

EP - 618

JO - Gongneng Cailiao/Journal of Functional Materials

JF - Gongneng Cailiao/Journal of Functional Materials

IS - SUPPL.

ER -

Structure and characterization of DBSA doped PAN

Abstract

Keywords

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