Structural coloration of non-metallic surfaces using ductile-regime vibration-assisted ultraprecision texturing

Structural coloration stemming from microstructure-induced light interference has been recognized as a promising surface colorizing technology, based on its potential in a wide array of applications, including high-definition displays, anti-counterfeiting, refractive index sensing, and photonic gas and vapor sensing. Vibration-assisted ultraprecision texturing using diamond tools has emerged as a high-efficiency and cost-effective machining method for colorizing metallic and ductile surfaces by creating near-wavelength microstructures. Although theoretically possible, it is extremely challenging to apply the vibration-assisted texturing technique directly to colorize non-metallic and brittle materials (e.g., silicon and acrylic polymers) with high-quality, crack-free microstructures owing to the intrinsic brittleness of these materials. This study demonstrates the feasibility of direct texturing near-wavelength-scale gratings on brittle surfaces in the ductile regime to fabricate crack-free micro/nanostructures. The effects of tool vibration trajectories on the ductile-to-brittle transition phenomena were investigated to reveal the cutting mechanism of ductile-regime texturing and optimize the processing windows. Structural coloration on silicon and acrylic surfaces was successfully demonstrated by creating programmable and pixelated diffraction gratings with spacing values ranging from 0.75 to 4 μm.