Abstract
The cubic sodium tungsten bronzes, NaxWO3 (x = 0.854 and 0.814) were prepared by rare earths gaseous permeation method. Structural analysis was carried out by Rietveld method from powder X-ray diffraction data. The X-ray diffraction profile calculated with cubic P32 models are in good agreement with the observed X-ray diffraction patterns. There is only a little difference in W-0 bond and Na-0 bond between Na0.854WO3 and Na0.814 WO3. Conductivity measurements indicate that NaxWO3 show anomalous semiconducting behavior and percolation model was used to interpret it.
| Original language | English |
|---|---|
| Pages (from-to) | 749-751 |
| Number of pages | 3 |
| Journal | Journal of Rare Earths |
| Volume | 22 |
| Issue number | 6 |
| State | Published - Dec 2004 |
Keywords
- Conductivity
- Rare earths
- Rare earths gaseous permeation
- Sodium tungsten bronze
- Structural analysis
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