Stereoisomerism in polyoxometalates: Structural and spectroscopic studies of bis(malate)-functionalized cluster systems

Xikui Fang; Travis M. Anderson; Yu Hou; Craig L. Hill

doi:10.1039/b508468g

Stereoisomerism in polyoxometalates: Structural and spectroscopic studies of bis(malate)-functionalized cluster systems

Xikui Fang
, Travis M. Anderson
, Yu Hou
, Craig L. Hill^*

^*Corresponding author for this work

Emory University

Research output: Contribution to journal › Article › peer-review

109 Scopus citations

Abstract

Pure enantiomers of a polytungstate cluster [(α-P₂W ₁₆O₅₉)Zr₂(μ₃-O)(mal)] ₂^18- (mal = malate) have been obtained and their conversion to meso diastereomers was observed by ³¹P NMR.

Original language	English
Pages (from-to)	5044-5046
Number of pages	3
Journal	Chemical Communications
Issue number	40
DOIs	https://doi.org/10.1039/b508468g
State	Published - 28 Oct 2005
Externally published	Yes

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@article{837fb75214c444d395d30199f867405a,

title = "Stereoisomerism in polyoxometalates: Structural and spectroscopic studies of bis(malate)-functionalized cluster systems",

abstract = "Pure enantiomers of a polytungstate cluster [(α-P2W 16O59)Zr2(μ3-O)(mal)] 218- (mal = malate) have been obtained and their conversion to meso diastereomers was observed by 31P NMR.",

author = "Xikui Fang and Anderson, \{Travis M.\} and Yu Hou and Hill, \{Craig L.\}",

year = "2005",

month = oct,

day = "28",

doi = "10.1039/b508468g",

language = "英语",

pages = "5044--5046",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "40",

}

TY - JOUR

T1 - Stereoisomerism in polyoxometalates

T2 - Structural and spectroscopic studies of bis(malate)-functionalized cluster systems

AU - Fang, Xikui

AU - Anderson, Travis M.

AU - Hou, Yu

AU - Hill, Craig L.

PY - 2005/10/28

Y1 - 2005/10/28

N2 - Pure enantiomers of a polytungstate cluster [(α-P2W 16O59)Zr2(μ3-O)(mal)] 218- (mal = malate) have been obtained and their conversion to meso diastereomers was observed by 31P NMR.

AB - Pure enantiomers of a polytungstate cluster [(α-P2W 16O59)Zr2(μ3-O)(mal)] 218- (mal = malate) have been obtained and their conversion to meso diastereomers was observed by 31P NMR.

UR - https://www.scopus.com/pages/publications/27644563109

U2 - 10.1039/b508468g

DO - 10.1039/b508468g

M3 - 文章

C2 - 16220165

AN - SCOPUS:27644563109

SN - 1359-7345

SP - 5044

EP - 5046

JO - Chemical Communications

JF - Chemical Communications

IS - 40

ER -

Stereoisomerism in polyoxometalates: Structural and spectroscopic studies of bis(malate)-functionalized cluster systems

Abstract

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