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Spin-orbit coupling in molecular auger spectra: Propensity rules tested for water

  • Linköping University

Research output: Contribution to journalArticlepeer-review

Abstract

Electronic spectra of dicadonic molecules comprise a high density of singlet and triplet states. By virtue of simple propensity rules only the singlet states are selected by core-valence (CW) Auger spectroscopy. We use second-order response theory to explore the role of spin-orbit interaction in the manifold of low-lying dicadonic states and its implications on the intensity analysis of the Auger spectrum of water.

Original languageEnglish
Pages (from-to)913-919
Number of pages7
JournalJournal of Physics B: Atomic, Molecular and Optical Physics
Volume26
Issue number5
DOIs
StatePublished - 14 Mar 1993
Externally publishedYes

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