Solvothermal synthesis of 1D and 2D cobalt(II) and nickel(II) coordination polymers with 2,5-dihydroxy-p-benzenediacetic acid

Peng Ren; Na Xu; Chen Chen; Hai Bin Song; Wei Shi; Peng Cheng

doi:10.1016/j.inoche.2008.03.024

Solvothermal synthesis of 1D and 2D cobalt(II) and nickel(II) coordination polymers with 2,5-dihydroxy-p-benzenediacetic acid

Peng Ren
, Na Xu
, Chen Chen
, Hai Bin Song
, Wei Shi^*
, Peng Cheng

^*Corresponding author for this work

Nankai University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

1D cobalt(II) and nickel(II) coordination polymers {[Co(dba)(H₂O)₄] · H₂O}_n (1) and {[Ni(dba)(H₂O)₄] · H₂O}_n (2) (H₂dba = 2,5-dihydroxy-p-benzenediacetic acid) were synthesized under low temperature solvothermal condition. When 4,4′-bipyridine (bpy) was introduced to the synthetic systems of 1 and 2, respectively, two novel 2D coordination polymers {[Co(dba)(bpy)] · 0.5H₂O}_n (3) and [Ni(dba)(bpy)(H₂O)₂]_n (4) with different structures were obtained. All of the compounds were characterized by elemental analysis, FT-IR, UV-Vis spectra and single crystal X-ray diffraction.

Original language	English
Pages (from-to)	730-732
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2008.03.024
State	Published - Jul 2008
Externally published	Yes

Keywords

2,5-Dihydroxy-p-benzenediacetic acid
Cobalt(II)
Coordination polymer
Mixed ligands
Nickel(II)

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10.1016/j.inoche.2008.03.024

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@article{821974604f274216b9a7e607a7c960c5,

title = "Solvothermal synthesis of 1D and 2D cobalt(II) and nickel(II) coordination polymers with 2,5-dihydroxy-p-benzenediacetic acid",

abstract = "1D cobalt(II) and nickel(II) coordination polymers \{[Co(dba)(H2O)4] · H2O\}n (1) and \{[Ni(dba)(H2O)4] · H2O\}n (2) (H2dba = 2,5-dihydroxy-p-benzenediacetic acid) were synthesized under low temperature solvothermal condition. When 4,4′-bipyridine (bpy) was introduced to the synthetic systems of 1 and 2, respectively, two novel 2D coordination polymers \{[Co(dba)(bpy)] · 0.5H2O\}n (3) and [Ni(dba)(bpy)(H2O)2]n (4) with different structures were obtained. All of the compounds were characterized by elemental analysis, FT-IR, UV-Vis spectra and single crystal X-ray diffraction.",

keywords = "2,5-Dihydroxy-p-benzenediacetic acid, Cobalt(II), Coordination polymer, Mixed ligands, Nickel(II)",

author = "Peng Ren and Na Xu and Chen Chen and Song, \{Hai Bin\} and Wei Shi and Peng Cheng",

year = "2008",

month = jul,

doi = "10.1016/j.inoche.2008.03.024",

language = "英语",

volume = "11",

pages = "730--732",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "7",

}

TY - JOUR

T1 - Solvothermal synthesis of 1D and 2D cobalt(II) and nickel(II) coordination polymers with 2,5-dihydroxy-p-benzenediacetic acid

AU - Ren, Peng

AU - Xu, Na

AU - Chen, Chen

AU - Song, Hai Bin

AU - Shi, Wei

AU - Cheng, Peng

PY - 2008/7

Y1 - 2008/7

N2 - 1D cobalt(II) and nickel(II) coordination polymers {[Co(dba)(H2O)4] · H2O}n (1) and {[Ni(dba)(H2O)4] · H2O}n (2) (H2dba = 2,5-dihydroxy-p-benzenediacetic acid) were synthesized under low temperature solvothermal condition. When 4,4′-bipyridine (bpy) was introduced to the synthetic systems of 1 and 2, respectively, two novel 2D coordination polymers {[Co(dba)(bpy)] · 0.5H2O}n (3) and [Ni(dba)(bpy)(H2O)2]n (4) with different structures were obtained. All of the compounds were characterized by elemental analysis, FT-IR, UV-Vis spectra and single crystal X-ray diffraction.

AB - 1D cobalt(II) and nickel(II) coordination polymers {[Co(dba)(H2O)4] · H2O}n (1) and {[Ni(dba)(H2O)4] · H2O}n (2) (H2dba = 2,5-dihydroxy-p-benzenediacetic acid) were synthesized under low temperature solvothermal condition. When 4,4′-bipyridine (bpy) was introduced to the synthetic systems of 1 and 2, respectively, two novel 2D coordination polymers {[Co(dba)(bpy)] · 0.5H2O}n (3) and [Ni(dba)(bpy)(H2O)2]n (4) with different structures were obtained. All of the compounds were characterized by elemental analysis, FT-IR, UV-Vis spectra and single crystal X-ray diffraction.

KW - 2,5-Dihydroxy-p-benzenediacetic acid

KW - Cobalt(II)

KW - Coordination polymer

KW - Mixed ligands

KW - Nickel(II)

UR - https://www.scopus.com/pages/publications/44749091092

U2 - 10.1016/j.inoche.2008.03.024

DO - 10.1016/j.inoche.2008.03.024

M3 - 文章

AN - SCOPUS:44749091092

SN - 1387-7003

VL - 11

SP - 730

EP - 732

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Solvothermal synthesis of 1D and 2D cobalt(II) and nickel(II) coordination polymers with 2,5-dihydroxy-p-benzenediacetic acid

Abstract

Keywords

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