Abstract
Single-photon core-valence double ionization of molecular oxygen has been studied using a magnetic bottle time-of-flight electron coincidence spectrometer. The K-1 V-1 double ionization electron spectrum of O2 is reported and is assigned with the aid of ab initio calculations. A direct comparison of the core-valence double ionization electron spectra with the conventional valence band photoelectron spectrum is made. The lowest core-valence double ionization energy is found to be 571.6 eV and is associated with a Π3 dicationic state.
| Original language | English |
|---|---|
| Article number | 023409 |
| Journal | Physical Review A - Atomic, Molecular, and Optical Physics |
| Volume | 78 |
| Issue number | 2 |
| DOIs | |
| State | Published - 18 Aug 2008 |
| Externally published | Yes |
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