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Single-photon core-valence double ionization of molecular oxygen

  • E. Andersson*
  • , M. Stenrup
  • , J. H.D. Eland
  • , L. Hedin
  • , M. Berglund
  • , L. Karlsson
  • , A. Larson
  • , H. Agren
  • , J. E. Rubensson
  • , R. Feifel
  • *Corresponding author for this work
  • Uppsala University
  • KTH Royal Institute of Technology
  • University of Oxford
  • Stockholm University
  • Helmholtz Centre Berlin for Materials and Energy

Research output: Contribution to journalArticlepeer-review

Abstract

Single-photon core-valence double ionization of molecular oxygen has been studied using a magnetic bottle time-of-flight electron coincidence spectrometer. The K-1 V-1 double ionization electron spectrum of O2 is reported and is assigned with the aid of ab initio calculations. A direct comparison of the core-valence double ionization electron spectra with the conventional valence band photoelectron spectrum is made. The lowest core-valence double ionization energy is found to be 571.6 eV and is associated with a Π3 dicationic state.

Original languageEnglish
Article number023409
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume78
Issue number2
DOIs
StatePublished - 18 Aug 2008
Externally publishedYes

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