Self-Assembly Method for Synthesizing High-Dimensional EMOFs with High Stability and Laser Response

Jinhao Zhang; Zhiyuan Jin; Wenjia Hao; Liqiong Luo; Quancheng Liu; Hu Deng; Zhicheng Guo; Juan Shen; Rufang Peng; Bo Jin

doi:10.1021/acs.inorgchem.4c01161

Self-Assembly Method for Synthesizing High-Dimensional EMOFs with High Stability and Laser Response

Jinhao Zhang
, Zhiyuan Jin
, Wenjia Hao
, Liqiong Luo
, Quancheng Liu
, Hu Deng
, Zhicheng Guo
, Juan Shen^*
, Rufang Peng
, Bo Jin^*

^*Corresponding author for this work

Southwest University of Science and Technology

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Dimension and solvent molecules affect the performance of energetic metal-organic frameworks (EMOFs). High-dimensional EMOFs are usually characterized by high stability and low sensitivity due to their complex network structure. However, solvent molecules affect the detonation performance of EMOFs, and these molecules may be removed at low temperatures, resulting in structural collapse and affecting the stability of EMOFs. In this work, zero-dimensional (0D) Co(AFTO)₂·(H₂O)₂ (EMOF 1) and Ni(AFTO)₂·(H₂O)₂ (EMOF 2) with coordinated water molecules and [Co(AFTO)₂]_n·EtOH (EMOF 3) and [Ni(AFTO)₂]_n (EMOF 4) (AFTO = 5-(4-amino-furazan-3-yl)-1-hydroxytetrazole) with high-dimensional structure were synthesized using hydrothermal and self-assembly methods in ethanol, respectively. Structural and performance tests show that EMOF 3 and 4 exhibit remarkable thermal stability and low mechanical sensitivity. This method is a simple, effective, and green technique for synthesizing high-dimensional EMOFs with high stability through self-assembly in ethanol solution. In addition, EMOF 3 and 4 can be used as primary green laser explosives.

Original language	English
Pages (from-to)	12498-12505
Number of pages	8
Journal	Inorganic Chemistry
Volume	63
Issue number	27
DOIs	https://doi.org/10.1021/acs.inorgchem.4c01161
State	Published - 8 Jul 2024
Externally published	Yes

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@article{5ad397f1507f4865b09d2caa873da3f8,

title = "Self-Assembly Method for Synthesizing High-Dimensional EMOFs with High Stability and Laser Response",

abstract = "Dimension and solvent molecules affect the performance of energetic metal-organic frameworks (EMOFs). High-dimensional EMOFs are usually characterized by high stability and low sensitivity due to their complex network structure. However, solvent molecules affect the detonation performance of EMOFs, and these molecules may be removed at low temperatures, resulting in structural collapse and affecting the stability of EMOFs. In this work, zero-dimensional (0D) Co(AFTO)2·(H2O)2 (EMOF 1) and Ni(AFTO)2·(H2O)2 (EMOF 2) with coordinated water molecules and [Co(AFTO)2]n·EtOH (EMOF 3) and [Ni(AFTO)2]n (EMOF 4) (AFTO = 5-(4-amino-furazan-3-yl)-1-hydroxytetrazole) with high-dimensional structure were synthesized using hydrothermal and self-assembly methods in ethanol, respectively. Structural and performance tests show that EMOF 3 and 4 exhibit remarkable thermal stability and low mechanical sensitivity. This method is a simple, effective, and green technique for synthesizing high-dimensional EMOFs with high stability through self-assembly in ethanol solution. In addition, EMOF 3 and 4 can be used as primary green laser explosives.",

author = "Jinhao Zhang and Zhiyuan Jin and Wenjia Hao and Liqiong Luo and Quancheng Liu and Hu Deng and Zhicheng Guo and Juan Shen and Rufang Peng and Bo Jin",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society.",

year = "2024",

month = jul,

day = "8",

doi = "10.1021/acs.inorgchem.4c01161",

language = "英语",

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journal = "Inorganic Chemistry",

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TY - JOUR

T1 - Self-Assembly Method for Synthesizing High-Dimensional EMOFs with High Stability and Laser Response

AU - Zhang, Jinhao

AU - Jin, Zhiyuan

AU - Hao, Wenjia

AU - Luo, Liqiong

AU - Liu, Quancheng

AU - Deng, Hu

AU - Guo, Zhicheng

AU - Shen, Juan

AU - Peng, Rufang

AU - Jin, Bo

PY - 2024/7/8

Y1 - 2024/7/8

N2 - Dimension and solvent molecules affect the performance of energetic metal-organic frameworks (EMOFs). High-dimensional EMOFs are usually characterized by high stability and low sensitivity due to their complex network structure. However, solvent molecules affect the detonation performance of EMOFs, and these molecules may be removed at low temperatures, resulting in structural collapse and affecting the stability of EMOFs. In this work, zero-dimensional (0D) Co(AFTO)2·(H2O)2 (EMOF 1) and Ni(AFTO)2·(H2O)2 (EMOF 2) with coordinated water molecules and [Co(AFTO)2]n·EtOH (EMOF 3) and [Ni(AFTO)2]n (EMOF 4) (AFTO = 5-(4-amino-furazan-3-yl)-1-hydroxytetrazole) with high-dimensional structure were synthesized using hydrothermal and self-assembly methods in ethanol, respectively. Structural and performance tests show that EMOF 3 and 4 exhibit remarkable thermal stability and low mechanical sensitivity. This method is a simple, effective, and green technique for synthesizing high-dimensional EMOFs with high stability through self-assembly in ethanol solution. In addition, EMOF 3 and 4 can be used as primary green laser explosives.

AB - Dimension and solvent molecules affect the performance of energetic metal-organic frameworks (EMOFs). High-dimensional EMOFs are usually characterized by high stability and low sensitivity due to their complex network structure. However, solvent molecules affect the detonation performance of EMOFs, and these molecules may be removed at low temperatures, resulting in structural collapse and affecting the stability of EMOFs. In this work, zero-dimensional (0D) Co(AFTO)2·(H2O)2 (EMOF 1) and Ni(AFTO)2·(H2O)2 (EMOF 2) with coordinated water molecules and [Co(AFTO)2]n·EtOH (EMOF 3) and [Ni(AFTO)2]n (EMOF 4) (AFTO = 5-(4-amino-furazan-3-yl)-1-hydroxytetrazole) with high-dimensional structure were synthesized using hydrothermal and self-assembly methods in ethanol, respectively. Structural and performance tests show that EMOF 3 and 4 exhibit remarkable thermal stability and low mechanical sensitivity. This method is a simple, effective, and green technique for synthesizing high-dimensional EMOFs with high stability through self-assembly in ethanol solution. In addition, EMOF 3 and 4 can be used as primary green laser explosives.

UR - https://www.scopus.com/pages/publications/85196804025

U2 - 10.1021/acs.inorgchem.4c01161

DO - 10.1021/acs.inorgchem.4c01161

M3 - 文章

C2 - 38912702

AN - SCOPUS:85196804025

SN - 0020-1669

VL - 63

SP - 12498

EP - 12505

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 27

ER -

Self-Assembly Method for Synthesizing High-Dimensional EMOFs with High Stability and Laser Response

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