Self-assembly and third-order nonlinear optical property (NLO) of one-dimensional silver(I) aggregation bridged by iodide

Yongli Wei; Yinglin Song; Hongwei Hou; Yu Zhu; Yaoting Fan

doi:10.1080/00958970412331295255

Self-assembly and third-order nonlinear optical property (NLO) of one-dimensional silver(I) aggregation bridged by iodide

Yongli Wei
, Yinglin Song
, Hongwei Hou^*
, Yu Zhu
, Yaoting Fan

^*Corresponding author for this work

School of Physics

Zhengzhou University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A new synthetic method was employed to prepare the silver(I) iodide polymer {[NEt₄]₃[Ag₆I₉]}_n with a one-dimensional double-chain. A mixture of solid Et₄NI, AgI and [NH₄]₂[MoO₂S₂] was heated gently and the reaction residue was extracted with MeCN. Orange-red monoclinic crystals were obtained at room temperature. The infinite chains of [Ag₆I ₉]_n^- consist of edge-shared square pyramids, in which iodides bridge silver atoms such that the geometry around the silver atoms is tetrahedral. A detailed study of its third-order nonlinear optical property via Z-scan is reported. The polymer {[NEt₄] ₃[Ag₆I₉]}_n shows a very strong self-focusing refractive effect with efficient third-order NLO susceptibility χ⁽³⁾ of 6.0 × 10^-11 esu.

Original language	English
Pages (from-to)	1329-1337
Number of pages	9
Journal	Journal of Coordination Chemistry
Volume	57
Issue number	15
DOIs	https://doi.org/10.1080/00958970412331295255
State	Published - 15 Oct 2004

Keywords

One-dimensional double chains
Silver iodide
Tetragonal pyramid
Third-order NLO property

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title = "Self-assembly and third-order nonlinear optical property (NLO) of one-dimensional silver(I) aggregation bridged by iodide",

abstract = "A new synthetic method was employed to prepare the silver(I) iodide polymer \{[NEt4]3[Ag6I9]\}n with a one-dimensional double-chain. A mixture of solid Et4NI, AgI and [NH4]2[MoO2S2] was heated gently and the reaction residue was extracted with MeCN. Orange-red monoclinic crystals were obtained at room temperature. The infinite chains of [Ag6I 9]n- consist of edge-shared square pyramids, in which iodides bridge silver atoms such that the geometry around the silver atoms is tetrahedral. A detailed study of its third-order nonlinear optical property via Z-scan is reported. The polymer \{[NEt4] 3[Ag6I9]\}n shows a very strong self-focusing refractive effect with efficient third-order NLO susceptibility χ(3) of 6.0 × 10-11 esu.",

keywords = "One-dimensional double chains, Silver iodide, Tetragonal pyramid, Third-order NLO property",

author = "Yongli Wei and Yinglin Song and Hongwei Hou and Yu Zhu and Yaoting Fan",

year = "2004",

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day = "15",

doi = "10.1080/00958970412331295255",

language = "英语",

volume = "57",

pages = "1329--1337",

journal = "Journal of Coordination Chemistry",

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T1 - Self-assembly and third-order nonlinear optical property (NLO) of one-dimensional silver(I) aggregation bridged by iodide

AU - Wei, Yongli

AU - Song, Yinglin

AU - Hou, Hongwei

AU - Zhu, Yu

AU - Fan, Yaoting

PY - 2004/10/15

Y1 - 2004/10/15

N2 - A new synthetic method was employed to prepare the silver(I) iodide polymer {[NEt4]3[Ag6I9]}n with a one-dimensional double-chain. A mixture of solid Et4NI, AgI and [NH4]2[MoO2S2] was heated gently and the reaction residue was extracted with MeCN. Orange-red monoclinic crystals were obtained at room temperature. The infinite chains of [Ag6I 9]n- consist of edge-shared square pyramids, in which iodides bridge silver atoms such that the geometry around the silver atoms is tetrahedral. A detailed study of its third-order nonlinear optical property via Z-scan is reported. The polymer {[NEt4] 3[Ag6I9]}n shows a very strong self-focusing refractive effect with efficient third-order NLO susceptibility χ(3) of 6.0 × 10-11 esu.

AB - A new synthetic method was employed to prepare the silver(I) iodide polymer {[NEt4]3[Ag6I9]}n with a one-dimensional double-chain. A mixture of solid Et4NI, AgI and [NH4]2[MoO2S2] was heated gently and the reaction residue was extracted with MeCN. Orange-red monoclinic crystals were obtained at room temperature. The infinite chains of [Ag6I 9]n- consist of edge-shared square pyramids, in which iodides bridge silver atoms such that the geometry around the silver atoms is tetrahedral. A detailed study of its third-order nonlinear optical property via Z-scan is reported. The polymer {[NEt4] 3[Ag6I9]}n shows a very strong self-focusing refractive effect with efficient third-order NLO susceptibility χ(3) of 6.0 × 10-11 esu.

KW - One-dimensional double chains

KW - Silver iodide

KW - Tetragonal pyramid

KW - Third-order NLO property

UR - https://www.scopus.com/pages/publications/8444221618

U2 - 10.1080/00958970412331295255

DO - 10.1080/00958970412331295255

M3 - 文章

AN - SCOPUS:8444221618

SN - 0095-8972

VL - 57

SP - 1329

EP - 1337

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 15

ER -

Self-assembly and third-order nonlinear optical property (NLO) of one-dimensional silver(I) aggregation bridged by iodide

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Keywords

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