Self-assembled multilayer films containing 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper: Preparation, and third order nonlinear optical properties

Chunying He; Jingze Fan; Zhongguo Li; Yachen Gao; Zhimin Chen; Yinglin Song; Yiqun Wu; Bin Wang

doi:10.1016/j.optmat.2013.11.016

Self-assembled multilayer films containing 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper: Preparation, and third order nonlinear optical properties

Chunying He^*
, Jingze Fan
, Zhongguo Li
, Yachen Gao
, Zhimin Chen
, Yinglin Song
, Yiqun Wu
, Bin Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Composite film with alternating layers containing anionic 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper and cationic polydiallydimethylammonium chloride was fabricated by electrostatic self-assembled layer-by-layer (LBL) technique. The microstructure of the film was characterized by a series of techniques. The third-order nonlinear optical properties of the film were measured using 4f coherent imaging system with phase object (NIT-PO) with laser duration of 20 ps at the wavelength of 532 nm. The film exhibited excellent nonlinear absorption and self-focusing effect. The second-order molecular hyperpolarizability γ value of the film reaches as high as 1.54 × 10^-29 esu.

Original language	English
Pages (from-to)	746-752
Number of pages	7
Journal	Optical Materials
Volume	36
Issue number	4
DOIs	https://doi.org/10.1016/j.optmat.2013.11.016
State	Published - Feb 2014
Externally published	Yes

Keywords

4f Coherent imaging system
Electronic self-assembly
Phthalocyanine
Thin film
Third-order optical nonlinearity

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10.1016/j.optmat.2013.11.016

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@article{005e88e53fc6496089672a2d977c327c,

title = "Self-assembled multilayer films containing 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper: Preparation, and third order nonlinear optical properties",

abstract = "Composite film with alternating layers containing anionic 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper and cationic polydiallydimethylammonium chloride was fabricated by electrostatic self-assembled layer-by-layer (LBL) technique. The microstructure of the film was characterized by a series of techniques. The third-order nonlinear optical properties of the film were measured using 4f coherent imaging system with phase object (NIT-PO) with laser duration of 20 ps at the wavelength of 532 nm. The film exhibited excellent nonlinear absorption and self-focusing effect. The second-order molecular hyperpolarizability γ value of the film reaches as high as 1.54 × 10-29 esu.",

keywords = "4f Coherent imaging system, Electronic self-assembly, Phthalocyanine, Thin film, Third-order optical nonlinearity",

author = "Chunying He and Jingze Fan and Zhongguo Li and Yachen Gao and Zhimin Chen and Yinglin Song and Yiqun Wu and Bin Wang",

year = "2014",

month = feb,

doi = "10.1016/j.optmat.2013.11.016",

language = "英语",

volume = "36",

pages = "746--752",

journal = "Optical Materials",

issn = "0925-3467",

publisher = "Elsevier B.V.",

number = "4",

}

TY - JOUR

T1 - Self-assembled multilayer films containing 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper

T2 - Preparation, and third order nonlinear optical properties

AU - He, Chunying

AU - Fan, Jingze

AU - Li, Zhongguo

AU - Gao, Yachen

AU - Chen, Zhimin

AU - Song, Yinglin

AU - Wu, Yiqun

AU - Wang, Bin

PY - 2014/2

Y1 - 2014/2

N2 - Composite film with alternating layers containing anionic 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper and cationic polydiallydimethylammonium chloride was fabricated by electrostatic self-assembled layer-by-layer (LBL) technique. The microstructure of the film was characterized by a series of techniques. The third-order nonlinear optical properties of the film were measured using 4f coherent imaging system with phase object (NIT-PO) with laser duration of 20 ps at the wavelength of 532 nm. The film exhibited excellent nonlinear absorption and self-focusing effect. The second-order molecular hyperpolarizability γ value of the film reaches as high as 1.54 × 10-29 esu.

AB - Composite film with alternating layers containing anionic 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper and cationic polydiallydimethylammonium chloride was fabricated by electrostatic self-assembled layer-by-layer (LBL) technique. The microstructure of the film was characterized by a series of techniques. The third-order nonlinear optical properties of the film were measured using 4f coherent imaging system with phase object (NIT-PO) with laser duration of 20 ps at the wavelength of 532 nm. The film exhibited excellent nonlinear absorption and self-focusing effect. The second-order molecular hyperpolarizability γ value of the film reaches as high as 1.54 × 10-29 esu.

KW - 4f Coherent imaging system

KW - Electronic self-assembly

KW - Phthalocyanine

KW - Thin film

KW - Third-order optical nonlinearity

UR - https://www.scopus.com/pages/publications/84892368074

U2 - 10.1016/j.optmat.2013.11.016

DO - 10.1016/j.optmat.2013.11.016

M3 - 文章

AN - SCOPUS:84892368074

SN - 0925-3467

VL - 36

SP - 746

EP - 752

JO - Optical Materials

JF - Optical Materials

IS - 4

ER -

Self-assembled multilayer films containing 1,8,15,22-tetrakis (8-quinolineoxy-5-sulfonic acid)-phthalocyanine copper: Preparation, and third order nonlinear optical properties

Abstract

Keywords

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