Selective activation of peroxymonosulfate govern by B-site metal in delafossite for efficient pollutants degradation: Pivotal role of d orbital electronic configuration

Radical and non-radical oxidation pathways have been universally validated in transition metals (TMs) oxides activated peroxymonosulfate (PMS) processes. However, achieving high efficiency and selectivity of PMS activation remains challenging due to the ambiguous tuning mechanism of TMs sites on PMS activation in thermodynamic scope. Herein, we demonstrated that the exclusive PMS oxidation pathways were regulated by d orbital electronic configuration of B-sites in delafossites (CuBO₂) for Orange I degradation (Co^III 3d⁶ for reactive oxygen species (ROSs) vs. Cr^III 3d³ for electron transfer pathway). The d orbital electronic configuration was identified to affect the orbital overlap extent between 3d of B-sites and O 2p of PMS, which induced B-sites offering different types of hybrid orbital to coordinate with O 2p of PMS, thereby forming the high-spin complex (CuCoO₂@PMS) or the low-spin complex (CuCrO₂@PMS), on which basis PMS was selectively dissociated to form ROSs or achieve electron transfer pathway. As indicated by thermodynamic analysis, a general rule was proposed that B-sites of less than half-filled 3d orbital tended to act as electron shuttle, i.e., Cr^III (3d³), Mn^III (3d⁴), interacting with PMS to execute an electron transfer pathway for degrading Orange I, while B-sites of between half-filled and full-filled 3d orbital preferred to be electron donator, i.e., Co^III (3d⁶), Fe^III (3d⁵), activating PMS to generate ROSs. These findings lay a foundation for the oriented design of TMs-based catalysts from the atomic level according to d orbital electronic configuration optimization, as so to facilitate the achievement of PMS-AOPs with highly selective and efficient remediation of contaminants in water purification practice.