Scanning tunneling microscopy investigation of a supramolecular self-assembled three-dimensional chiral prism on a Au(111) surface

Qun Hui Yuan; Cun Ji Yan; Hui Juan Yan; Li Jun Wan; Brian H. Northrop; Hershel Jude; Peter J. Stang

doi:10.1021/ja801934w

Scanning tunneling microscopy investigation of a supramolecular self-assembled three-dimensional chiral prism on a Au(111) surface

Qun Hui Yuan
, Cun Ji Yan
, Hui Juan Yan
, Li Jun Wan^*
, Brian H. Northrop
, Hershel Jude
, Peter J. Stang

^*Corresponding author for this work

CAS - Institute of Chemistry
University of Utah

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Spontaneous symmetry-breaking of a racemic mixture of supramolecular triginal prisms into chiral domains on a Au(111) surface is observed by scanning tunneling microscopy (STM). High-resolution STM analysis enables the structural aspects of each enantiomeric domain to be elucidated. The ability to resolve chirality on achiral surfaces has potential applications in heterogeneous stereoselective synthesis and catalysis.

Original language	English
Pages (from-to)	8878-8879
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	28
DOIs	https://doi.org/10.1021/ja801934w
State	Published - 16 Jul 2008
Externally published	Yes

Access to Document

10.1021/ja801934w

Cite this

@article{99369e8dfbc34475a619c72bf3b150a2,

title = "Scanning tunneling microscopy investigation of a supramolecular self-assembled three-dimensional chiral prism on a Au(111) surface",

abstract = "Spontaneous symmetry-breaking of a racemic mixture of supramolecular triginal prisms into chiral domains on a Au(111) surface is observed by scanning tunneling microscopy (STM). High-resolution STM analysis enables the structural aspects of each enantiomeric domain to be elucidated. The ability to resolve chirality on achiral surfaces has potential applications in heterogeneous stereoselective synthesis and catalysis.",

author = "Yuan, \{Qun Hui\} and Yan, \{Cun Ji\} and Yan, \{Hui Juan\} and Wan, \{Li Jun\} and Northrop, \{Brian H.\} and Hershel Jude and Stang, \{Peter J.\}",

year = "2008",

month = jul,

day = "16",

doi = "10.1021/ja801934w",

language = "英语",

volume = "130",

pages = "8878--8879",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "28",

}

TY - JOUR

T1 - Scanning tunneling microscopy investigation of a supramolecular self-assembled three-dimensional chiral prism on a Au(111) surface

AU - Yuan, Qun Hui

AU - Yan, Cun Ji

AU - Yan, Hui Juan

AU - Wan, Li Jun

AU - Northrop, Brian H.

AU - Jude, Hershel

AU - Stang, Peter J.

PY - 2008/7/16

Y1 - 2008/7/16

N2 - Spontaneous symmetry-breaking of a racemic mixture of supramolecular triginal prisms into chiral domains on a Au(111) surface is observed by scanning tunneling microscopy (STM). High-resolution STM analysis enables the structural aspects of each enantiomeric domain to be elucidated. The ability to resolve chirality on achiral surfaces has potential applications in heterogeneous stereoselective synthesis and catalysis.

AB - Spontaneous symmetry-breaking of a racemic mixture of supramolecular triginal prisms into chiral domains on a Au(111) surface is observed by scanning tunneling microscopy (STM). High-resolution STM analysis enables the structural aspects of each enantiomeric domain to be elucidated. The ability to resolve chirality on achiral surfaces has potential applications in heterogeneous stereoselective synthesis and catalysis.

UR - https://www.scopus.com/pages/publications/47349112134

U2 - 10.1021/ja801934w

DO - 10.1021/ja801934w

M3 - 文章

C2 - 18549212

AN - SCOPUS:47349112134

SN - 0002-7863

VL - 130

SP - 8878

EP - 8879

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 28

ER -

Scanning tunneling microscopy investigation of a supramolecular self-assembled three-dimensional chiral prism on a Au(111) surface

Abstract

Access to Document

Other files and links

Fingerprint

Cite this