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Room temperature ferromagnetism in ZnO/SnO2 nanotubes by electrospinning

  • Jianguo Zhao*
  • , Mao Yang
  • , Weiying Zhang
  • , Erqing Xie
  • , Xiuyun An
  • , Jiecai Fu
  • , Zhongli Liu
  • *Corresponding author for this work
  • Luoyang Normal University
  • Lanzhou University

Research output: Contribution to journalArticlepeer-review

Abstract

ZnO/SnO2 nanotubes are prepared by electrospinning method with postannealing in air at 500 °C. Field emission scanning electron microscopy (FE-SEM) reveals the formation of porous ZnO/SnO2 nanotubes. The X-ray diffraction (XRD) and Raman spectrum results show that the ZnO/SnO2 nanotubes have mixed of wurtzite (ZnO) and rutile (SnO2) structure. High-resolution transmission electron microscopy (HRTEM) results also assist the products polycrystalline nature with an average outer diameter of ̃300 nm, a wall thickness of ̃20 nm. The magnetic properties of ZnO/SnO2 nanotubes are studied using a superconductor quantum interference device (SQUID) magnetometer, and revealing the room-temperature ferromagnetism. The ferromagnetic origin has been ascribed to intrinsic defects. The coercivity and saturation magnetization of ZnO/SnO2 nanotubes at 5 K are estimated to be 191 Oe, 0.148 emu/g and higher than at 300 K. Such a ferromagnet without the presence of any transition metal could be a very good option for a class of spintronics.

Original languageEnglish
Pages (from-to)985-989
Number of pages5
JournalScience of Advanced Materials
Volume6
Issue number5
DOIs
StatePublished - 2014
Externally publishedYes

Keywords

  • Interface
  • Nanotubes
  • Room temperature ferromagnetism

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