Reversible photoluminescence switching behavior and luminescence thermochromism of copper(I) halide cluster coordination polymers

Guang Zeng; Shanghua Xing; Xu Han; Bingjing Xin; Yulin Yang; Xiuru Wang; Guanghua Li; Zhan Shi; Shouhua Feng

doi:10.1039/c5ra05157f

Reversible photoluminescence switching behavior and luminescence thermochromism of copper(I) halide cluster coordination polymers

Guang Zeng
, Shanghua Xing
, Xu Han
, Bingjing Xin
, Yulin Yang
, Xiuru Wang
, Guanghua Li^*
, Zhan Shi
, Shouhua Feng

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Two novel coordination polymers [Cu₃I₄(C₁₆H₃₂N₄)]·ClO₄ (1) and [Cu₆I₆Br₂(C₁₆H₃₂N₄)(CH₃CN)₂] (2) (C₁₆H₃₂N₄·2Br^- = 4-Aza-1-azoniabicyclo-[2.2.2]octane, 1,1′-(1,4-butanediyl)bis-dibromide) have been synthesized under solvothermal conditions. At room temperature, compounds 1 (Φ = 46.2%) and 2 (Φ = 26.62%) show strong photoluminescence in solid state. At low temperature, compound 1 displays obvious thermochromic luminescence while compound 2 has no obvious change which can be observed by naked eye. However, compound 2 displays a interesting phenomenon. The luminescence of compound 2 is reversible when the coordinated CH₃CN molecules in structure are removed by heat and recovered from acetonitrile solvent.

Original language	English
Pages (from-to)	40792-40797
Number of pages	6
Journal	RSC Advances
Volume	5
Issue number	51
DOIs	https://doi.org/10.1039/c5ra05157f
State	Published - 2015
Externally published	Yes

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@article{f0cbd7b3c8d14609befa3f2e2c627bc5,

title = "Reversible photoluminescence switching behavior and luminescence thermochromism of copper(I) halide cluster coordination polymers",

abstract = "Two novel coordination polymers [Cu3I4(C16H32N4)]·ClO4 (1) and [Cu6I6Br2(C16H32N4)(CH3CN)2] (2) (C16H32N4·2Br- = 4-Aza-1-azoniabicyclo-[2.2.2]octane, 1,1′-(1,4-butanediyl)bis-dibromide) have been synthesized under solvothermal conditions. At room temperature, compounds 1 (Φ = 46.2\%) and 2 (Φ = 26.62\%) show strong photoluminescence in solid state. At low temperature, compound 1 displays obvious thermochromic luminescence while compound 2 has no obvious change which can be observed by naked eye. However, compound 2 displays a interesting phenomenon. The luminescence of compound 2 is reversible when the coordinated CH3CN molecules in structure are removed by heat and recovered from acetonitrile solvent.",

author = "Guang Zeng and Shanghua Xing and Xu Han and Bingjing Xin and Yulin Yang and Xiuru Wang and Guanghua Li and Zhan Shi and Shouhua Feng",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

doi = "10.1039/c5ra05157f",

language = "英语",

volume = "5",

pages = "40792--40797",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "51",

}

TY - JOUR

T1 - Reversible photoluminescence switching behavior and luminescence thermochromism of copper(I) halide cluster coordination polymers

AU - Zeng, Guang

AU - Xing, Shanghua

AU - Han, Xu

AU - Xin, Bingjing

AU - Yang, Yulin

AU - Wang, Xiuru

AU - Li, Guanghua

AU - Shi, Zhan

AU - Feng, Shouhua

PY - 2015

Y1 - 2015

N2 - Two novel coordination polymers [Cu3I4(C16H32N4)]·ClO4 (1) and [Cu6I6Br2(C16H32N4)(CH3CN)2] (2) (C16H32N4·2Br- = 4-Aza-1-azoniabicyclo-[2.2.2]octane, 1,1′-(1,4-butanediyl)bis-dibromide) have been synthesized under solvothermal conditions. At room temperature, compounds 1 (Φ = 46.2%) and 2 (Φ = 26.62%) show strong photoluminescence in solid state. At low temperature, compound 1 displays obvious thermochromic luminescence while compound 2 has no obvious change which can be observed by naked eye. However, compound 2 displays a interesting phenomenon. The luminescence of compound 2 is reversible when the coordinated CH3CN molecules in structure are removed by heat and recovered from acetonitrile solvent.

AB - Two novel coordination polymers [Cu3I4(C16H32N4)]·ClO4 (1) and [Cu6I6Br2(C16H32N4)(CH3CN)2] (2) (C16H32N4·2Br- = 4-Aza-1-azoniabicyclo-[2.2.2]octane, 1,1′-(1,4-butanediyl)bis-dibromide) have been synthesized under solvothermal conditions. At room temperature, compounds 1 (Φ = 46.2%) and 2 (Φ = 26.62%) show strong photoluminescence in solid state. At low temperature, compound 1 displays obvious thermochromic luminescence while compound 2 has no obvious change which can be observed by naked eye. However, compound 2 displays a interesting phenomenon. The luminescence of compound 2 is reversible when the coordinated CH3CN molecules in structure are removed by heat and recovered from acetonitrile solvent.

UR - https://www.scopus.com/pages/publications/84929179571

U2 - 10.1039/c5ra05157f

DO - 10.1039/c5ra05157f

M3 - 文章

AN - SCOPUS:84929179571

SN - 2046-2069

VL - 5

SP - 40792

EP - 40797

JO - RSC Advances

JF - RSC Advances

IS - 51

ER -

Reversible photoluminescence switching behavior and luminescence thermochromism of copper(I) halide cluster coordination polymers

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