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Research of growth kinetics of cu/Sn intermetallic compounds in planar and curved cu/Sn diffusion couples

  • Jiahao Liu
  • , Jixi Huang
  • , Lijin Qiu
  • , Fangzhou Chen
  • , Hongtao Chen*
  • , Yufeng Liu
  • *Corresponding author for this work
  • Harbin Institute of Technology Shenzhen
  • China Electronic Product Reliability and Environmental Testing Research Institute

Research output: Contribution to journalArticlepeer-review

Abstract

As a crucial bridge for heat dissipation, electrical transmission and mechanical interconnection between chips and substrates, interconnection interfaces have a close bearing on the interconnection quality and reliability of the solder joint. With the increasing diversity of electronic packaging configurations, the geometric shape of interconnection interfaces has a growing influence on the growth of Cu-Sn intermetallic compounds (IMCs). However, existing research has predominantly focused on planar Cu/Sn diffusion couples, with insufficient investigation into curved Cu/Sn interfaces. In this study, the growth kinetics of both planar and curved Cu/Sn diffusion couples were systematically examined under various reflow temperatures (250–350 °C) and holding durations (60–960 s). The effects of interface curvature on the diffusion rates, growth mechanisms, and activation energies of Cu3Sn and Cu6Sn5 IMCs were elucidated.

Original languageEnglish
Article number140894
JournalMaterials Letters
Volume419
DOIs
StatePublished - 15 Sep 2026
Externally publishedYes

Keywords

  • Activation energy
  • Cu/Sn diffusion couple
  • Diffusion coefficient
  • Growth mechanism
  • Interface curvature

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