Abstract
The relativistic calculations of the krypton-xenon spectrum in the 68,000 cm-1 region were analyzed to obtain a microscopic understanding of the origin of vuv emission from inert heavy-atom gas mixtures. The calculations were carried out in the ground and in the low-lying spin-orbit excited states of the krypton-xenon dimers. Large-core quasirelastivistic effective core potentials with highly augmented valence basis sets and midbond functions were used for the analysis.
| Original language | English |
|---|---|
| Article number | 042501 |
| Pages (from-to) | 425011-4250110 |
| Number of pages | 3825100 |
| Journal | Physical Review A - Atomic, Molecular, and Optical Physics |
| Volume | 67 |
| Issue number | 4 |
| State | Published - Apr 2003 |
| Externally published | Yes |
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