Regioselective synthesis of α-bromo-α,β-unsaturated carbonyl compounds via photocatalytic α-bromination reactions

Dan Wang; Yating Zhao; Chao Yang; Wujiong Xia

doi:10.1007/s11426-015-5530-7

Regioselective synthesis of α-bromo-α,β-unsaturated carbonyl compounds via photocatalytic α-bromination reactions

Dan Wang
, Yating Zhao
, Chao Yang
, Wujiong Xia^*

^*Corresponding author for this work

School of Sciences

Harbin Institute of Technology
Harbin Institute of Technology Shenzhen

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A visible light-mediated approach for the preparation of α-bromo-α,β-unsaturated ketones and aldehydes was developed. In comparison to traditional methods that generally take two steps to afford the above compounds, this protocol was highlighted by its operational simplicity, avoiding using hazardous bromine and mild reaction conditions.

Original language	English
Pages (from-to)	190-194
Number of pages	5
Journal	Science China Chemistry
Volume	59
Issue number	2
DOIs	https://doi.org/10.1007/s11426-015-5530-7
State	Published - 1 Feb 2016

Keywords

operational simplicity
visible light
α,β-unsaturated ketones and aldehydes
α-bromination

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title = "Regioselective synthesis of α-bromo-α,β-unsaturated carbonyl compounds via photocatalytic α-bromination reactions",

abstract = "A visible light-mediated approach for the preparation of α-bromo-α,β-unsaturated ketones and aldehydes was developed. In comparison to traditional methods that generally take two steps to afford the above compounds, this protocol was highlighted by its operational simplicity, avoiding using hazardous bromine and mild reaction conditions.",

keywords = "operational simplicity, visible light, α,β-unsaturated ketones and aldehydes, α-bromination",

author = "Dan Wang and Yating Zhao and Chao Yang and Wujiong Xia",

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AU - Wang, Dan

AU - Zhao, Yating

AU - Yang, Chao

AU - Xia, Wujiong

PY - 2016/2/1

Y1 - 2016/2/1

N2 - A visible light-mediated approach for the preparation of α-bromo-α,β-unsaturated ketones and aldehydes was developed. In comparison to traditional methods that generally take two steps to afford the above compounds, this protocol was highlighted by its operational simplicity, avoiding using hazardous bromine and mild reaction conditions.

AB - A visible light-mediated approach for the preparation of α-bromo-α,β-unsaturated ketones and aldehydes was developed. In comparison to traditional methods that generally take two steps to afford the above compounds, this protocol was highlighted by its operational simplicity, avoiding using hazardous bromine and mild reaction conditions.

KW - operational simplicity

KW - visible light

KW - α,β-unsaturated ketones and aldehydes

KW - α-bromination

UR - https://www.scopus.com/pages/publications/84957429745

U2 - 10.1007/s11426-015-5530-7

DO - 10.1007/s11426-015-5530-7

M3 - 文章

AN - SCOPUS:84957429745

SN - 1674-7291

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JF - Science China Chemistry

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ER -

Regioselective synthesis of α-bromo-α,β-unsaturated carbonyl compounds via photocatalytic α-bromination reactions

Abstract

Keywords

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