Recycling of Pd(0) catalysts by magnetic nanocomposites—microbial extracellular polymeric substances@Fe₃O₄

Palladium (Pd) is extremely expensive due to its scarcity and excellent catalytic performance. Thus, the recovery of Pd has become increasingly important. Herein, microbial extracellular polymeric substances (EPS) and magnetic nanocomposite EPS@Fe₃O₄ were applied to recover Pd catalysts from Pd(II) wastewater. Results indicated that Pd(II) was reduced to Pd (0), which was then adsorbed by EPS (101.21 mg/g) and EPS@Fe₃O₄ (126.30 mg/(g EPS)). After adsorbing Pd, EPS@Fe₃O₄ could be collected by magnetic separation. The recovered Pd showed excellent catalytic activity in the reduction of methylene blue (MB). The pseudo-second-order kinetic model and Redlich-Peterson model best fit the adsorption results. According to spectral analysis, Pd(II) was reduced to Pd (0) by chemical groups in EPS and EPS@Fe₃O₄, and the hydroxyl had a chelating effect on adsorbed Pd. Therefore, EPS@Fe₃O₄ is an efficient adsorbent for recovering Pd from Pd(II) wastewater.