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Rapid formation of Cu-Cu joints with high shear strength using multiple-flocculated Ag nanoparticle paste

  • Bo Hu
  • , Fan Yang
  • , Ye Peng
  • , Hongjun Ji*
  • , Shihua Yang
  • , Ming Yang*
  • , Mingyu Li
  • *Corresponding author for this work
  • Harbin Institute of Technology Shenzhen
  • Shanghai Aerospace Equipments Manufacturer
  • Hisilicon Optoelectronics Co., Ltd

Research output: Contribution to journalArticlepeer-review

Abstract

A new type of Ag nanoparticle (NP) paste for rapid sintering was prepared by controlling the thickness of the NP capping agent. The Ag NP paste was combined with a rapid thermo-compression (RTC) method to form a reliable Cu-Cu joint. The shear strengths of the Cu/Ag NP/Cu joints were 46.8 MPa and 90.7 MPa after sintering at 300 °C for only 5 s and 20 s, respectively. The sintering sequence phenomenon was observed, and the differences in microstructure between the pressureassisted and pressureless joints were investigated. Robust bonding at the lattice level between the Ag NPs and Cu substrate was observed by high-resolution transmission electron microscopy, and this bonding contributed to the high shear strength obtained under rapid sintering conditions. A commercially acceptable alternative solution to achieving reliable Cu-Cu joint formation was obtained, especially for thermo-sensitive devices.

Original languageEnglish
Pages (from-to)8071-8079
Number of pages9
JournalJournal of Materials Science: Materials in Electronics
Volume30
Issue number8
DOIs
StatePublished - Apr 2019
Externally publishedYes

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