Rapid and sensitive SERS method for determination of Rhodamine B in chili powder with paper-based substrates

Shuang Lin; Wu Li Ji Hasi; Xiang Lin; Si Qin Gao Wa Han; Xiu Tao Lou; Fang Yang; Dian Yang Lin; Zhi Wei Lu

doi:10.1039/c5ay00028a

Rapid and sensitive SERS method for determination of Rhodamine B in chili powder with paper-based substrates

Shuang Lin
, Wu Li Ji Hasi^*
, Xiang Lin
, Si Qin Gao Wa Han
, Xiu Tao Lou
, Fang Yang
, Dian Yang Lin
, Zhi Wei Lu

^*Corresponding author for this work

Harbin Institute of Technology
Inner Mongolia University for Nationalities

Research output: Contribution to journal › Article › peer-review

133 Scopus citations

Abstract

Surface-enhanced Raman spectroscopy (SERS) was used for detecting Rhodamine B (RB) which is often added illegally to chili powder. Based on density functional theory, the Raman spectrum of RB was calculated and characteristic peaks of RB were assigned to the corresponding vibrational modes. RB was detected utilizing paper-based SERS substrates which were fabricated via a liquid-liquid interface-mediated self-assembly technique. Meanwhile, with simple sample pretreatment, the detection limit could reach 10^-6 g g^-1 for RB in chili powder (5 × 10^-7 g mL^-1 in extraction agent). Within the concentration range from 10^-2 g g^-1 to 10^-6 g g^-1, Raman intensity follows a certain function in relation to the concentration of RB. The recovery of this method ranges from 96.4% to 108.9%, which gives rapid and reliable quantitative detection of RB in chili powder. Therefore, the proposed SERS method is suitable for on-site detection and analysis of RB in chili powder.

Original language	English
Pages (from-to)	5289-5294
Number of pages	6
Journal	Analytical Methods
Volume	7
Issue number	12
DOIs	https://doi.org/10.1039/c5ay00028a
State	Published - 21 Jun 2015

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10.1039/c5ay00028a

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@article{50808a319fa044e8b3ea1cd4914036d0,

title = "Rapid and sensitive SERS method for determination of Rhodamine B in chili powder with paper-based substrates",

abstract = "Surface-enhanced Raman spectroscopy (SERS) was used for detecting Rhodamine B (RB) which is often added illegally to chili powder. Based on density functional theory, the Raman spectrum of RB was calculated and characteristic peaks of RB were assigned to the corresponding vibrational modes. RB was detected utilizing paper-based SERS substrates which were fabricated via a liquid-liquid interface-mediated self-assembly technique. Meanwhile, with simple sample pretreatment, the detection limit could reach 10-6 g g-1 for RB in chili powder (5 \× 10-7 g mL-1 in extraction agent). Within the concentration range from 10-2 g g-1 to 10-6 g g-1, Raman intensity follows a certain function in relation to the concentration of RB. The recovery of this method ranges from 96.4\% to 108.9\%, which gives rapid and reliable quantitative detection of RB in chili powder. Therefore, the proposed SERS method is suitable for on-site detection and analysis of RB in chili powder.",

author = "Shuang Lin and Hasi, \{Wu Li Ji\} and Xiang Lin and Han, \{Si Qin Gao Wa\} and Lou, \{Xiu Tao\} and Fang Yang and Lin, \{Dian Yang\} and Lu, \{Zhi Wei\}",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

month = jun,

day = "21",

doi = "10.1039/c5ay00028a",

language = "英语",

volume = "7",

pages = "5289--5294",

journal = "Analytical Methods",

issn = "1759-9660",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Rapid and sensitive SERS method for determination of Rhodamine B in chili powder with paper-based substrates

AU - Lin, Shuang

AU - Hasi, Wu Li Ji

AU - Lin, Xiang

AU - Han, Si Qin Gao Wa

AU - Lou, Xiu Tao

AU - Yang, Fang

AU - Lin, Dian Yang

AU - Lu, Zhi Wei

PY - 2015/6/21

Y1 - 2015/6/21

N2 - Surface-enhanced Raman spectroscopy (SERS) was used for detecting Rhodamine B (RB) which is often added illegally to chili powder. Based on density functional theory, the Raman spectrum of RB was calculated and characteristic peaks of RB were assigned to the corresponding vibrational modes. RB was detected utilizing paper-based SERS substrates which were fabricated via a liquid-liquid interface-mediated self-assembly technique. Meanwhile, with simple sample pretreatment, the detection limit could reach 10-6 g g-1 for RB in chili powder (5 × 10-7 g mL-1 in extraction agent). Within the concentration range from 10-2 g g-1 to 10-6 g g-1, Raman intensity follows a certain function in relation to the concentration of RB. The recovery of this method ranges from 96.4% to 108.9%, which gives rapid and reliable quantitative detection of RB in chili powder. Therefore, the proposed SERS method is suitable for on-site detection and analysis of RB in chili powder.

AB - Surface-enhanced Raman spectroscopy (SERS) was used for detecting Rhodamine B (RB) which is often added illegally to chili powder. Based on density functional theory, the Raman spectrum of RB was calculated and characteristic peaks of RB were assigned to the corresponding vibrational modes. RB was detected utilizing paper-based SERS substrates which were fabricated via a liquid-liquid interface-mediated self-assembly technique. Meanwhile, with simple sample pretreatment, the detection limit could reach 10-6 g g-1 for RB in chili powder (5 × 10-7 g mL-1 in extraction agent). Within the concentration range from 10-2 g g-1 to 10-6 g g-1, Raman intensity follows a certain function in relation to the concentration of RB. The recovery of this method ranges from 96.4% to 108.9%, which gives rapid and reliable quantitative detection of RB in chili powder. Therefore, the proposed SERS method is suitable for on-site detection and analysis of RB in chili powder.

UR - https://www.scopus.com/pages/publications/84931076191

U2 - 10.1039/c5ay00028a

DO - 10.1039/c5ay00028a

M3 - 文章

AN - SCOPUS:84931076191

SN - 1759-9660

VL - 7

SP - 5289

EP - 5294

JO - Analytical Methods

JF - Analytical Methods

IS - 12

ER -

Rapid and sensitive SERS method for determination of Rhodamine B in chili powder with paper-based substrates

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