Preparation of monodisperse polystyrene particles by radiation-induced dispersion polymerization using waterborne polyurethane as a stabilizer

Guixi Zhang; Zhicheng Zhang; Changqi Xu; Qiang Ye

doi:10.1016/j.colsurfa.2005.10.018

Preparation of monodisperse polystyrene particles by radiation-induced dispersion polymerization using waterborne polyurethane as a stabilizer

Guixi Zhang
, Zhicheng Zhang^*
, Changqi Xu
, Qiang Ye

^*Corresponding author for this work

University of Science and Technology of China

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Novel waterborne polyester polyurethane (WPU) was synthesized and firstly applied to dispersion polymerization of styrene (PSt). Monodisperse PSt particles were successfully prepared by radiation-induced dispersion polymerization, after dispersed in ethanol-water medium and stabilized by WPU at room temperature. The conversion-time curve was investigated, and the grafting reaction between WPU and PSt was investigated via FT-IR, XPS and ¹H NMR spectrum. Furthermore, the grafting efficiency of WPU (G_WPU, ratio of grafted WPU versus the total content of WPU in the system) was calculated via ¹H NMR spectrum. It shows when vinyl groups are attached to WPU molecules, the diameter of PSt particles decrease.

Original language	English
Pages (from-to)	72-77
Number of pages	6
Journal	Colloids and Surfaces A: Physicochemical and Engineering Aspects
Volume	276
Issue number	1-3
DOIs	https://doi.org/10.1016/j.colsurfa.2005.10.018
State	Published - 15 Mar 2006
Externally published	Yes

Keywords

Dispersion polymerization
Grafting reaction
Radiation
Styrene
Waterborne polyurethane

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10.1016/j.colsurfa.2005.10.018

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@article{f05c22d7be944c4facf0555b25c4fc65,

title = "Preparation of monodisperse polystyrene particles by radiation-induced dispersion polymerization using waterborne polyurethane as a stabilizer",

abstract = "Novel waterborne polyester polyurethane (WPU) was synthesized and firstly applied to dispersion polymerization of styrene (PSt). Monodisperse PSt particles were successfully prepared by radiation-induced dispersion polymerization, after dispersed in ethanol-water medium and stabilized by WPU at room temperature. The conversion-time curve was investigated, and the grafting reaction between WPU and PSt was investigated via FT-IR, XPS and 1H NMR spectrum. Furthermore, the grafting efficiency of WPU (GWPU, ratio of grafted WPU versus the total content of WPU in the system) was calculated via 1H NMR spectrum. It shows when vinyl groups are attached to WPU molecules, the diameter of PSt particles decrease.",

keywords = "Dispersion polymerization, Grafting reaction, Radiation, Styrene, Waterborne polyurethane",

author = "Guixi Zhang and Zhicheng Zhang and Changqi Xu and Qiang Ye",

year = "2006",

month = mar,

day = "15",

doi = "10.1016/j.colsurfa.2005.10.018",

language = "英语",

volume = "276",

pages = "72--77",

journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",

issn = "0927-7757",

publisher = "Elsevier B.V.",

number = "1-3",

}

Preparation of monodisperse polystyrene particles by radiation-induced dispersion polymerization using waterborne polyurethane as a stabilizer. / Zhang, Guixi; Zhang, Zhicheng; Xu, Changqi et al.
In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 276, No. 1-3, 15.03.2006, p. 72-77.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation of monodisperse polystyrene particles by radiation-induced dispersion polymerization using waterborne polyurethane as a stabilizer

AU - Zhang, Guixi

AU - Zhang, Zhicheng

AU - Xu, Changqi

AU - Ye, Qiang

PY - 2006/3/15

Y1 - 2006/3/15

N2 - Novel waterborne polyester polyurethane (WPU) was synthesized and firstly applied to dispersion polymerization of styrene (PSt). Monodisperse PSt particles were successfully prepared by radiation-induced dispersion polymerization, after dispersed in ethanol-water medium and stabilized by WPU at room temperature. The conversion-time curve was investigated, and the grafting reaction between WPU and PSt was investigated via FT-IR, XPS and 1H NMR spectrum. Furthermore, the grafting efficiency of WPU (GWPU, ratio of grafted WPU versus the total content of WPU in the system) was calculated via 1H NMR spectrum. It shows when vinyl groups are attached to WPU molecules, the diameter of PSt particles decrease.

AB - Novel waterborne polyester polyurethane (WPU) was synthesized and firstly applied to dispersion polymerization of styrene (PSt). Monodisperse PSt particles were successfully prepared by radiation-induced dispersion polymerization, after dispersed in ethanol-water medium and stabilized by WPU at room temperature. The conversion-time curve was investigated, and the grafting reaction between WPU and PSt was investigated via FT-IR, XPS and 1H NMR spectrum. Furthermore, the grafting efficiency of WPU (GWPU, ratio of grafted WPU versus the total content of WPU in the system) was calculated via 1H NMR spectrum. It shows when vinyl groups are attached to WPU molecules, the diameter of PSt particles decrease.

KW - Dispersion polymerization

KW - Grafting reaction

KW - Radiation

KW - Styrene

KW - Waterborne polyurethane

UR - https://www.scopus.com/pages/publications/33644830440

U2 - 10.1016/j.colsurfa.2005.10.018

DO - 10.1016/j.colsurfa.2005.10.018

M3 - 文章

AN - SCOPUS:33644830440

SN - 0927-7757

VL - 276

SP - 72

EP - 77

JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects

JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects

IS - 1-3

ER -

Preparation of monodisperse polystyrene particles by radiation-induced dispersion polymerization using waterborne polyurethane as a stabilizer

Abstract

Keywords

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