Preparation, Characterization of Cu-MCM-41 and Its Catalysis for Hydroxylation of Aromatic Compounds

Jian Min Sun; Xiang Ju Meng; Run Wei Wang; Wen Yong Lin; Kai Feng Lin; Wen Qin Pang; Da Zhen Jiang; Ru Ren Xu; Feng Shou Xiao

Preparation, Characterization of Cu-MCM-41 and Its Catalysis for Hydroxylation of Aromatic Compounds

Jian Min Sun
, Xiang Ju Meng
, Run Wei Wang
, Wen Yong Lin
, Kai Feng Lin
, Wen Qin Pang
, Da Zhen Jiang
, Ru Ren Xu
, Feng Shou Xiao^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Pure silica MCM-41 with surface grafted Cu²⁺ ions (donated as CuMCM-41) was synthesized via a novel co-assemble route; XRD, ESR and ion-exchange studies revealed that the copper was located on the surface of the pure silica MCM-41 and coordinated with bridged oxygen in the framework. In addition, we also studied its catalysis behavior for hydroxylation of phenol and naphthol with hydrogen peroxide as the oxygen donor. The experimental results show that Cu-MCM-41 possesses an excellent catalytic activity compared with other catalysts Cu-AlMCM-41 and CuO-MCM-41.

Original language	English
Pages (from-to)	1454
Number of pages	1
Journal	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume	21
Issue number	9
State	Published - 10 Sep 2000
Externally published	Yes

Keywords

Cu-MCM-41
Hydrogen peroxide
Mesoporous molecular sieves
Naphthol hydroxylation
Phenol hydroxylation

Cite this

@article{12c96c7d99924ab6a8cf7b847721b070,

title = "Preparation, Characterization of Cu-MCM-41 and Its Catalysis for Hydroxylation of Aromatic Compounds",

abstract = "Pure silica MCM-41 with surface grafted Cu2+ ions (donated as CuMCM-41) was synthesized via a novel co-assemble route; XRD, ESR and ion-exchange studies revealed that the copper was located on the surface of the pure silica MCM-41 and coordinated with bridged oxygen in the framework. In addition, we also studied its catalysis behavior for hydroxylation of phenol and naphthol with hydrogen peroxide as the oxygen donor. The experimental results show that Cu-MCM-41 possesses an excellent catalytic activity compared with other catalysts Cu-AlMCM-41 and CuO-MCM-41.",

keywords = "Cu-MCM-41, Hydrogen peroxide, Mesoporous molecular sieves, Naphthol hydroxylation, Phenol hydroxylation",

author = "Sun, \{Jian Min\} and Meng, \{Xiang Ju\} and Wang, \{Run Wei\} and Lin, \{Wen Yong\} and Lin, \{Kai Feng\} and Pang, \{Wen Qin\} and Jiang, \{Da Zhen\} and Xu, \{Ru Ren\} and Xiao, \{Feng Shou\}",

year = "2000",

month = sep,

day = "10",

language = "英语",

volume = "21",

pages = "1454",

journal = "Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "9",

}

TY - JOUR

T1 - Preparation, Characterization of Cu-MCM-41 and Its Catalysis for Hydroxylation of Aromatic Compounds

AU - Sun, Jian Min

AU - Meng, Xiang Ju

AU - Wang, Run Wei

AU - Lin, Wen Yong

AU - Lin, Kai Feng

AU - Pang, Wen Qin

AU - Jiang, Da Zhen

AU - Xu, Ru Ren

AU - Xiao, Feng Shou

PY - 2000/9/10

Y1 - 2000/9/10

N2 - Pure silica MCM-41 with surface grafted Cu2+ ions (donated as CuMCM-41) was synthesized via a novel co-assemble route; XRD, ESR and ion-exchange studies revealed that the copper was located on the surface of the pure silica MCM-41 and coordinated with bridged oxygen in the framework. In addition, we also studied its catalysis behavior for hydroxylation of phenol and naphthol with hydrogen peroxide as the oxygen donor. The experimental results show that Cu-MCM-41 possesses an excellent catalytic activity compared with other catalysts Cu-AlMCM-41 and CuO-MCM-41.

AB - Pure silica MCM-41 with surface grafted Cu2+ ions (donated as CuMCM-41) was synthesized via a novel co-assemble route; XRD, ESR and ion-exchange studies revealed that the copper was located on the surface of the pure silica MCM-41 and coordinated with bridged oxygen in the framework. In addition, we also studied its catalysis behavior for hydroxylation of phenol and naphthol with hydrogen peroxide as the oxygen donor. The experimental results show that Cu-MCM-41 possesses an excellent catalytic activity compared with other catalysts Cu-AlMCM-41 and CuO-MCM-41.

KW - Cu-MCM-41

KW - Hydrogen peroxide

KW - Mesoporous molecular sieves

KW - Naphthol hydroxylation

KW - Phenol hydroxylation

UR - https://www.scopus.com/pages/publications/0347647705

M3 - 文章

AN - SCOPUS:0347647705

SN - 0251-0790

VL - 21

SP - 1454

JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

IS - 9

ER -

Preparation, Characterization of Cu-MCM-41 and Its Catalysis for Hydroxylation of Aromatic Compounds

Abstract

Keywords

Other files and links

Fingerprint

Cite this