Preparation and optical properties of poly(4-ethynyl-4′-[N,N-diethylamino]azobenzene-co-phenylacetylene)

Shouchun Yin; Hongyao Xu; Wenfang Shi; Liang Bao; Yachen Gao; Yinlin Song; Ben Zhong Tang

doi:10.1016/j.dyepig.2005.08.008

Preparation and optical properties of poly(4-ethynyl-4′-[N,N-diethylamino]azobenzene-co-phenylacetylene)

Shouchun Yin
, Hongyao Xu^*
, Wenfang Shi
, Liang Bao
, Yachen Gao
, Yinlin Song
, Ben Zhong Tang

^*Corresponding author for this work

School of Physics

University of Science and Technology of China
Anhui University
Harbin Institute of Technology
Hong Kong University of Science and Technology

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A novel soluble functional polyacetylene copolymer (poly(EAAB-co-PA)) of 4-ethynyl-4′-[N,N-diethylamino]azobenzene (EAAB) and phenylacetylene (PA) was synthesized. The structures and properties of the polymers were characterized and evaluated by FTIR, UV-vis, ¹H NMR, GPC, optical limiting, and nonlinear optical analyses. The results show that poly(EAAB-co-PA) has the large third-order nonlinear susceptibility, which are two orders of magnitude larger than those of poly(PA) and novel optical limiting property.

Original language	English
Pages (from-to)	119-123
Number of pages	5
Journal	Dyes and Pigments
Volume	72
Issue number	1
DOIs	https://doi.org/10.1016/j.dyepig.2005.08.008
State	Published - 2007

Keywords

Azo dyes
Chromophore
Nonlinear optics
Optical limiting
Substituted polyacetylene
Z-scan

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10.1016/j.dyepig.2005.08.008

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title = "Preparation and optical properties of poly(4-ethynyl-4′-[N,N-diethylamino]azobenzene-co-phenylacetylene)",

abstract = "A novel soluble functional polyacetylene copolymer (poly(EAAB-co-PA)) of 4-ethynyl-4′-[N,N-diethylamino]azobenzene (EAAB) and phenylacetylene (PA) was synthesized. The structures and properties of the polymers were characterized and evaluated by FTIR, UV-vis, 1H NMR, GPC, optical limiting, and nonlinear optical analyses. The results show that poly(EAAB-co-PA) has the large third-order nonlinear susceptibility, which are two orders of magnitude larger than those of poly(PA) and novel optical limiting property.",

keywords = "Azo dyes, Chromophore, Nonlinear optics, Optical limiting, Substituted polyacetylene, Z-scan",

author = "Shouchun Yin and Hongyao Xu and Wenfang Shi and Liang Bao and Yachen Gao and Yinlin Song and Tang, \{Ben Zhong\}",

year = "2007",

doi = "10.1016/j.dyepig.2005.08.008",

language = "英语",

volume = "72",

pages = "119--123",

journal = "Dyes and Pigments",

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TY - JOUR

T1 - Preparation and optical properties of poly(4-ethynyl-4′-[N,N-diethylamino]azobenzene-co-phenylacetylene)

AU - Yin, Shouchun

AU - Xu, Hongyao

AU - Shi, Wenfang

AU - Bao, Liang

AU - Gao, Yachen

AU - Song, Yinlin

AU - Tang, Ben Zhong

PY - 2007

Y1 - 2007

N2 - A novel soluble functional polyacetylene copolymer (poly(EAAB-co-PA)) of 4-ethynyl-4′-[N,N-diethylamino]azobenzene (EAAB) and phenylacetylene (PA) was synthesized. The structures and properties of the polymers were characterized and evaluated by FTIR, UV-vis, 1H NMR, GPC, optical limiting, and nonlinear optical analyses. The results show that poly(EAAB-co-PA) has the large third-order nonlinear susceptibility, which are two orders of magnitude larger than those of poly(PA) and novel optical limiting property.

AB - A novel soluble functional polyacetylene copolymer (poly(EAAB-co-PA)) of 4-ethynyl-4′-[N,N-diethylamino]azobenzene (EAAB) and phenylacetylene (PA) was synthesized. The structures and properties of the polymers were characterized and evaluated by FTIR, UV-vis, 1H NMR, GPC, optical limiting, and nonlinear optical analyses. The results show that poly(EAAB-co-PA) has the large third-order nonlinear susceptibility, which are two orders of magnitude larger than those of poly(PA) and novel optical limiting property.

KW - Azo dyes

KW - Chromophore

KW - Nonlinear optics

KW - Optical limiting

KW - Substituted polyacetylene

KW - Z-scan

UR - https://www.scopus.com/pages/publications/33646546693

U2 - 10.1016/j.dyepig.2005.08.008

DO - 10.1016/j.dyepig.2005.08.008

M3 - 文章

AN - SCOPUS:33646546693

SN - 0143-7208

VL - 72

SP - 119

EP - 123

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 1

ER -

Preparation and optical properties of poly(4-ethynyl-4′-[N,N-diethylamino]azobenzene-co-phenylacetylene)

Abstract

Keywords

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